1. Influence of Mg2+ substitution on the strain sensitivity of CoFe2O4 prepared by solid-state method
- Author
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Wang Guijuan, Lu Yongcheng, Chen Daming, Peng Rui, and Li Yuanxun
- Subjects
inorganic chemicals ,010302 applied physics ,Materials science ,Scanning electron microscope ,Analytical chemistry ,Magnetostriction ,Condensed Matter Physics ,Magnetocrystalline anisotropy ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,Crystal ,symbols.namesake ,Lattice constant ,visual_art ,Phase (matter) ,0103 physical sciences ,visual_art.visual_art_medium ,symbols ,Ceramic ,Electrical and Electronic Engineering ,Raman spectroscopy - Abstract
In this study, the traditional solid-phase method was used to synthesize CoMgxFe(2−x)O4 (x = 0–0.1) ceramic, and the effect of replacing Fe3+ with Mg2+ on the structure, crystal phase, and magnetic properties of ceramic crystals was analyzed by X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and vibrating sample magnetometer. Results showed that the lattice constant decreased as Mg2+ content increased. When x 0.05, Mg2+ affected the tetrahedral position and the octahedral position. The substitution of nonmagnetic Mg2+ for magnetic Fe3+ weakened the A-O-B effect of CoFe2O4 and lowered the magnetocrystalline anisotropy constant as well as the magnetostriction coefficient, which led to an enhancement on the strain sensitivity of CoMgxFe(2−x)O4 in a low magnetic field, and a maximum value of 4.6 × 10−9 A−1 m was obtained as x = 0.075.
- Published
- 2021
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