Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2019-12-11T19:31:04Z No. of bitstreams: 1 2012 - J?sus Sampaio J?nior.pdf: 1810130 bytes, checksum: 834e19e522ec02e413e52deda0c29a24 (MD5) Made available in DSpace on 2019-12-11T19:31:04Z (GMT). No. of bitstreams: 1 2012 - J?sus Sampaio J?nior.pdf: 1810130 bytes, checksum: 834e19e522ec02e413e52deda0c29a24 (MD5) Previous issue date: 2012-02-16 CAPES The oil and its derivatives have become not only one of the main primary sources of global energy production nut an input for virtually all industrial sectors, and in the next decades this framework will continue to increase. However, the oil exploration has aggravating factors, such as production of wastes, which have various pollutants mainly due to the used fluid. Among the contaminants, barium and sodium are generally in high concentrations. The storage of such residues in inappropriate locations and without proper treatment enhances the risks of soil, groundwater and living beings contamination. Thus, this study aimed to evaluate the effects of soil application of drilling waste from oil wells in the development and absorption of barium and sodium by sunflower and castor plants, and risks of groundwater contamination. The study was carried out in a greenhouse at Federal Rural University of Rio de Janeiro research area. The soil and waste materials were collected during the drilling of the well 7-MGP-98D-BA. Two experiments were established simultaneously, one with plants and the other in leaching columns. For both tests, the dosages of the residues were determined using guiding values proposed by CONAMA (2009), and they were: control - no application of barium, with natural contents of the element in the soil; and the dosages of 300, 3000 and 6000 mg kg-1 from two residue sources. These dosages are respectively related to an application of 16.6, 165.9 and 331.8 Mg.ha-1 of the dryer residue; and 2.6, 25.7 and 51.3 Mg.ha-1 of the centrifuge residue. In the plants test, two species with potential for biodiesel production were used; sunflower (Catissol 01) and castor bean (Al Guarany 2002). Analyses of growth, dry matter production and elements absorption by plants were carried out. In the column leaching test two redox potential (oxidation and reduction) conditions were tested. The redox potential, pH, the analysis of the pseudo total levels and the soil geochemical fractioning, and the analysis of leachate extracts were monitored. It was observed that in the reduction condition an increase in the barium levels for the most labile fractions, and a decrease in the stable fractions, in both residue sources. There was also more sulfate solubilization, consequently increasing the barium levels in the leachate extracts. In relation to sodium, it was observed that the highest percentages removed in the leachate extracts were found in the centrifuge residue and in the oxidation condition. For the dryer residue, the dosages 2 and 3 affected the growth of plants, whereas in the centrifuge residue, the plants only were affected at the highest concentration, due to high sodium levels. This element showed to be the most critical in the waste. The barium absorption by the sunflower and castor bean plants was not affected by increasing dosages of residue. O petr?leo e seus derivados transformaram-se n?o s? em uma das principais fontes prim?rias da matriz energ?tica mundial, mas tamb?m em insumos para praticamente todos os setores industriais, e nas pr?ximas d?cadas esse quadro deve continuar a aumentar. Por?m, a explora??o de petr?leo apresenta agravante, como a gera??o de res?duos, os quais apresentam diversos poluentes, principalmente, em fun??o do fluido utilizado. Dentre os contaminantes, o b?rio e o s?dio est?o presentes, geralmente, em elevadas concentra??es. A disposi??o desses res?duos em locais inadequados e sem tratamento adequado, potencializa os riscos de contamina??o do solo, das ?guas subterr?neas e dos seres vivos. Desta forma, o presente trabalho teve como objetivo avaliar os efeitos da aplica??o no solo de res?duos de perfura??o de po?os de petr?leo no desenvolvimento e absor??o de b?rio e s?dio por plantas de girassol e mamona, al?m dos riscos de contamina??o das ?guas subterr?neas. O experimento foi conduzido em casa de vegeta??o, em ?rea de pesquisa da Universidade Federal Rural do Rio de Janeiro. O solo e os res?duos utilizados foram coletados durante a perfura??o do po?o 7- MGP-98D-BA. Foram instalados dois ensaios em paralelo, um com plantas e outro com colunas de lixivia??o. Para ambos os ensaios, as doses dos res?duos foram determinadas com base nos valores orientadores propostos pelo CONAMA (2009), sendo estas: Testemunha ? sem aplica??o de b?rio, sendo somente os teores naturais do solo; e doses de 300, 3000 e 6000 mg kg-1, de res?duos de duas fontes. Essas doses s?o respectivamente referentes ? aplica??o de 16,6, 165,9 e 331,8 Mg ha-1, do res?duo do secador, e 2,6, 25,7 e 51,3 Mg ha-1, do res?duo da centr?fuga. No ensaio de plantas, foram utilizadas duas esp?cies promissoras na produ??o de ?leo para biodiesel, o girassol (Catissol 01) e a mamona (Al Guarany 2002). Foram realizadas an?lises de crescimento, produ??o de mat?ria seca e absor??o dos elementos pelas plantas. No ensaio de colunas de lixivia??o foram testadas duas condi??es de potencial redox (oxida??o e redu??o). Foi realizado monitoramento do potencial redox, pH, an?lise dos teores pseudototais e fracionamento geoqu?mico do solo e an?lise dos extratos lixiviados. Foi observado que na condi??o de redu??o ocorreu aumento nos teores de b?rio nas fra??es mais l?beis e diminui??o nas fra??es de maior estabilidade, para ambos os res?duos. Ocorreu tamb?m maior solubiliza??o do sulfato e consequente aumento nos teores de b?rio nos extratos lixiviados. Em rela??o ao s?dio, observou-se que as maiores porcentagens removidas nos extratos lixiviados, foram para o res?duo da centr?fuga e na condi??o de oxida??o. Para o res?duo do secador as doses 2 e 3 afetaram o desenvolvimento das plantas, enquanto que para o res?duo da centr?fuga, as plantas somente foram afetadas na maior dose, devido aos elevados teores de s?dio. Esse elemento mostrou-se o mais cr?tico presente nos res?duos. A absor??o de b?rio pelas plantas de girassol e mamona n?o foi afetada com o aumento das doses de res?duo.