Search

Classifying quantum states usually demands to observe properties such as the amount of correlation at one point in time. Further insight may be gained by inspecting the dynamics in a given evolution scheme. Here we attempt such a classification looking at single-qubit and two-qubit states at the start of thermalisation with a heat bath. The speed with which the evolution starts is influenced by quantum aspects of the state, however, such signatures do not allow for a systematic classification.

Encoding information in the time-frequency domain is demonstrating its potential for quantum information processing. It offers a novel scheme for communications with large alphabets, computing with large quantum systems, and new approaches to metrology. It is then crucial to secure full control on the generation of time-frequency quantum states and their properties. Here, we present an overview of the theoretical background and the technical aspects related to the characterization of time-frequency properties of two-photon states. We provide a detailed account of the methodologies which have been implemented for measuring frequency correlations and for the retrieval of the full spectral wavefunction. This effort has benefited enormously from the adaptation of classical metrology schemes to the needs of operating at the single-photon level.

The emergence of realistic properties is a key problem in understanding the quantum-to-classical transition. In this respect, measurements represent a way to interface quantum systems with the macroscopic world: these can be driven in the weak regime, where a reduced back-action can be imparted by choosing meter states able to extract different amounts of information. Here we explore the implications of such weak measurement for the variation of realistic properties of two-level quantum systems pre- and post-measurement, and extend our investigations to the case of open systems implementing the measurements.

Supplemental Document

Phase estimation is the most investigated protocol in quantum metrology, but its performance is affected by the presence of noise, also in the form of imperfect state preparation. Here we discuss how to address this scenario by using a multiparameter approach, in which noise is associated to a parameter to be measured at the same time as the phase. We present an experiment using two-photon states, and apply our setup to investigating optical activity of fructose solutions. Finally, we illustrate the scaling laws of the attainable precisions with the number of photons in the probe state.

Landauer's principle introduces a symmetry between computational and physical processes: erasure of information, a logically irreversible operation, must be underlain by an irreversible transformation dissipating energy. Monitoring micro- and nano-systems needs to enter into the energetic balance of their control; hence, finding the ultimate limits is instrumental to the development of future thermal machines operating at the quantum level. We report on the experimental investigation of a bound to the irreversible entropy associated to generalized quantum measurements on a quantum bit. We adopted a quantum photonics gate to implement a device interpolating from the weakly disturbing to the fully invasive and maximally informative regime. Our experiment prompted us to introduce a bound taking into account both the classical result of the measurement and the outcoming quantum state; unlike previous investigation, our new entropic bound is based uniquely on measurable quantities. Our results highlight what insights the information-theoretic approach can provide on building blocks of quantum information processors.

Over the last 50 years, the incidence of human thyroid cancer disease has seen a significative increment. This comes along with an even higher increment of surgery, since, according to the international guidelines, patients are sometimes addressed to surgery also when the fine needle aspiration gives undetermined cytological diagnosis. As a matter of fact, only 30% of the thyroid glands removed for diagnostic purpose have a post surgical histological report of malignancy: this implies that about 70% of the patients have suffered an unnecessary thyroid removal. Here we show that Raman spectroscopy investigation of thyroid tissues provides reliable cancer diagnosis. Healthy tissues are consistently distinguished from cancerous ones with an accuracy of $$\sim $$ ∼ 90%, and the three cancer typology with highest incidence are clearly identified. More importantly, Raman investigation has evidenced alterations suggesting an early stage of transition of adenoma tissues into cancerous ones. These results suggest that Raman spectroscopy may overcome the limits of current diagnostic tools.

The concept of ions being either water "structure makers" or water "breakers" seems to be inconsistent with the existence of a critical number of water molecules per ion dictating the properties of an aqueous solution, independent of the ion identity. To investigate this issue, Raman spectra of hydroxide aqueous solutions in the region of the OH stretching mode have been obtained under ambient conditions and at concentrations ranging from extreme dilution to the solubility limit. Spectra have been analyzed with a relatively model-free approach, in terms of a superposition of contributions due to the vibrations of the OH-ions, with two contributions due to the solvent. One of these latter contributions falls at wavenumbers very close to that of the OH-stretching band, sharing with it its concentration dependence of the full width at half maximum (FWHM). The other contribution due to the solvent is very broad, with increasing FWHM with increasing ion concentration. In the light of these observations, an interpretation of the Raman spectra, based on the possibility of distinguishing the self and distinct contributions, is proposed. The present analysis is supported by structural data on the same solutions and puts into evidence relevant structural and dynamical changes occurring when the number of water molecules available per solute is below ∼20, irrespective of the ion identity.

An experimental study of electronic properties, structure and morphology of Copper-phthalocyanine films deposited onto Al(100) and Au(110), as a function of thickness up to tens of nanometers, is presented. The monolayers grown on these two model substrates are already known to exhibit very different behavior for what concerns both the degree of interaction with the substrate and the formation of long range order; in this experiment, by means of low energy electron scattering and Electron Energy Loss Spectroscopy (EELS), remarkable differences are revealed also in the successive growth. Exploiting the link between the crystal structure and the lineshape of HOMO–LUMO transition in EELS spectrum, two different structural phases are identified, compatible with α and β phases, respectively in the case of the film grown on aluminum and on gold. Besides, the evolution of the specular reflection elastic peak indicates the formation of islands on the gold substrate and a more homogeneous growth on the aluminum one.

Quantum photonics has demonstrated its potential for enhanced sensing. Current sources of quantum light states tailored to measuring, allow to monitor phenomena evolving on time scales of the order of the second. These are characteristic of product accumulation in chemical reactions of technologically interest, in particular those involving chiral compounds. Here we adopt a quantum multiparameter approach to investigate the dynamic process of sucrose acid hydrolysis as a test bed for such applications. The estimation is made robust by monitoring different parameters at once.

The superposition of quantum states lies at the heart of physics and has been recently found to serve as a versatile resource for quantum information protocols, defining the notion of quantum coherence. In this contribution, we report on the implementation of its complementary concept, coherence from quantum measurements. By devising an accessible criterion which holds true in any classical statistical theory, we demonstrate that noncommutative quantum measurements violate this constraint, rendering it possible to perform an operational assessment of the measurement-based quantum coherence. In particular, we verify that polarization measurements of a single photonic qubit, an essential carrier of one unit of quantum information, are already incompatible with classical, i.e., incoherent, models of a measurement apparatus. Thus, we realize a method that enables us to quantitatively certify which quantum measurements follow fundamentally different statistical laws than expected from classical theories and, at the same time, quantify their usefulness within the modern framework of resources for quantum information technology., Comment: close to published version

Nonequilibrium quantum thermometry is a central topic for both fundamental and technological purposes. It shows advantages against its equilibrium counterpart by reducing the uncertainty associated to the temperature of the bath, and a negligible invasiveness. Here, we analyze how quantum features influence the dynamical speed of single- and two-qubit nonequilibrium thermometers interacting with a bosonic thermal bath. Our investigations exploit Riemannian geometric tools to show that the Riemannian speed of the nonequilibrium thermometer is only indirectly influenced by its quantum features, thus highlighting how the quantum fingerprint seems to be concealed by the classical aspects of thermalization dynamics.

Encoding information in the time–frequency domain demonstrates its potential for quantum information processing. It offers a novel scheme for communications with large alphabets, computing with large quantum systems, and new approaches to metrology. It is then crucial to secure full control on the generation of time–frequency quantum states and their properties. Here, the authors present an overview of the theoretical background and the technical aspects related to the characterization of time–frequency properties of two-photon states. The authors provide a detailed account of the methodologies that have been implemented for measuring frequency correlations and for the retrieval of the full spectral wavefunction. This effort has benefited enormously from the adaptation of classical metrology schemes to the needs of operating at the single-photon level.Encoding information in the time–frequency domain demonstrates its potential for quantum information processing. It offers a novel scheme for communications with large alphabets, computing with large quantum systems, and new approaches to metrology. It is then crucial to secure full control on the generation of time–frequency quantum states and their properties. Here, the authors present an overview of the theoretical background and the technical aspects related to the characterization of time–frequency properties of two-photon states. The authors provide a detailed account of the methodologies that have been implemented for measuring frequency correlations and for the retrieval of the full spectral wavefunction. This effort has benefited enormously from the adaptation of classical metrology schemes to the needs of operating at the single-photon level.

We present the results of an experiment aimed at studying the archetypal properties of the aluminum bulk plasmon at an organic/metal interface. Electron-electron coincidence spectroscopy is used to determine the contribution of aluminum bulk plasmon decay to the ionization of a thin copper phthalocyanine film. The latter directly depends on the amplitude of the bulk plasmon electric field (generated in the metal substrate) protruding inside the molecular overlayer. The emission of low-energy electrons from the clean substrate is dominated by plasmon-assisted ionization events. These events are not observed when the molecules are adsorbed onto the surface. Our findings suggest that, for the considered system, the bulk plasmon wave is confined within the medium in which it is generated and the interaction of the plasmon field with electrons located in the molecular overlayer does not lead to the emission of low-energy electrons.

The emergence of realistic properties is a key problem in understanding the quantum-to-classical transition. In this respect, measurements represent a way to interface quantum systems with the macroscopic world: these can be driven in the weak regime, where a reduced back-action can be imparted by choosing meter states able to extract different amounts of information. Here we explore the implications of such weak measurement for the variation of realistic properties of two-level quantum systems pre- and post-measurement, and extend our investigations to the case of open systems implementing the measurements.

Landauer’s principle introduces a symmetry between computational and physical processes: erasure of information, a logically irreversible operation, must be underlain by an irreversible transformation dissipating energy. Monitoring micro- and nano-systems needs to enter into the energetic balance of their control; hence, finding the ultimate limits is instrumental to the development of future thermal machines operating at the quantum level. We report on the experimental investigation of a lower bound to the irreversible entropy associated to generalized quantum measurements on a quantum bit. We adopted a quantum photonics gate to implement a device interpolating from the weakly disturbing to the fully invasive and maximally informative regime. Our experiment prompted us to introduce a bound taking into account both the classical result of the measurement and the outcoming quantum state; unlike previous investigation, our entropic bound is based uniquely on measurable quantities. Our results highlight what insights the information-theoretic approach provides on building blocks of quantum information processors. A lower bound for the thermodynamic cost of quantum measurements can be found from non-thermodynamic quantities. Modern classical and quantum devices can be used to explore the fundamental limits of computation, such as the energy required to measure or erase information. Luca Mancino and collaborators in Italy and the United Kingdom have demonstrated the evaluation of a lower limit on irreversible thermodynamic entropy generated during a quantum measurement. In general, thermodynamic quantities are difficult to measure but the authors' bound is calculated using information obtained from standard quantum optical measurements. Mancino et al. find that although their bound does not constrain the entropy tightly it does reflect how the experimental parameters affect the entropic cost of the measurements. This demonstrates the potential for using information-theoretic quantities to gain insight into quantum thermodynamics.

Photons are massless, noninteracting particles, and thermodynamics seems to be completely inappropriate in their description. Here we present two examples of the opposite: connecting thermodynamics with information through Maxwell’s Demon provides interesting insight on properties of light fields. This does not amount to directly applying thermodynamics to photons, but rather helps to obtain tools and concepts from thermodynamics to manipulate and evaluate the information content of light. The examples presented here pinpoint some of the challenges that arise when putting a thought experiment into practice and provide new insights into the relation between thermodynamic work and information.

Careful tailoring the quantum state of probes offers the capability of investigating matter at unprecedented precisions. Rarely, however, the interaction with the sample is fully encompassed by a single parameter, and the information contained in the probe needs to be partitioned on multiple parameters. There exist then practical bounds on the ultimate joint-estimation precision set by the unavailability of a single optimal measurement for all parameters. Here we discuss how these considerations are modified for two-level quantum probes - qubits - by the use of two copies and entangling measurements. We find that the joint estimation of phase and phase diffusion benefits from such collective measurement, while for multiple phases, no enhancement can be observed. We demonstrate this in a proof-of-principle photonics setup.

Single-qubit thermometry presents the simplest tool to measure the temperature of thermal baths with reduced invasivity. At thermal equilibrium, the temperature uncertainty is linked to the heat capacity of the qubit, however the best precision is achieved outside equilibrium condition. Here, we discuss a way to generalize this relation in a non-equilibrium regime, taking into account purely quantum effects such as coherence. We support our findings with an experimental photonic simulation., Comment: 7 pages, 4 figures

Optical sensors based on quantum light need to work even in the presence of imperfections. Here we discuss how to address the presence of noise by measuring multiple parameters at once: those we seek to monitor and those linked to the imperfections. Our method is applied to the investigation of the optical activity of sugary solutions limited by reduced visibility. These studies introduce multiparameter estimation as a viable approach to allow for robust operation of quantum sensors as they are developed from fundamental research to technology.

The Clausius inequality has deep implications for reversibility and the arrow of time. Quantum theory is able to extend this result for closed systems by inspecting the trajectory of the density matrix on its manifold. Here we show that this approach can provide an upper and lower bound to the irreversible entropy production for open quantum systems as well. These provide insights on how the information on the initial state is forgotten through a thermalization process. Limits of the applicability of our bounds are discussed and demonstrated in a quantum photonic simulator.

The simplicity of a question, such as wondering whether or not correlations characterize a certain system, collides with the experimental difficulty of accessing such information. Here we present a low-demanding experimental approach that refers to the use of a metrology scheme to obtain a conservative estimate of the strength of frequency correlations. Our test bed is the widespread case of a photon pair produced per downconversion. The theoretical architecture used to put the correlation degree on a quantitative ground is also described.

The physics that governs quantum monitoring may involve other degrees of freedom than the ones initialised and controlled for probing. In this context we address the simultaneous estimation of phase and dephasing characterizing a dispersive medium, and we explore the role of frequency correlations within a photon pair generated via parametric down-conversion, when used as a probe for the medium. We derive the ultimate quantum limits on the estimation of the two parameters, by calculating the corresponding quantum Cram\'er-Rao bound; we then consider a feasible estimation scheme, based on the measurement of Stokes operators, and address its absolute performances in terms of the correlation parameters, and, more fundamentally, of the role played by correlations in the simultaneous achievability of the quantum Cram\'er-Rao bounds for each of the two parameters., Comment: to appear in Quantum Measurements and Quantum Metrology

The metrological ability of carefully designed probes can be spoilt by the presence of noisy processes occurring during their evolution. The noise is responsible for altering the evolution of the probes in such a way that bear little or no information on the parameter of interest, hence spoiling the signal-to-noise ratio of any possible measurement. Here we show an experiment in which the introduction of an ancilla improves the estimation of an optical phase in the high-noise regime. The advantage is realised by the coherent coupling of the probe and the ancilla at the initialisation and the measurement state, which generate and then select a subset of overall configurations less affected by the noise process.

Not much, in the end. Here we put forward some considerations on how Hong-Ou-Mandel interferometry provides signatures of frequency entanglement in the two-photon state produced by parametric down-conversion. We find that some quantitative information can be inferred in the limit of long-pulse pumping, while the short-pulse limit remains elusive.

Standard thermometry employs the thermalisation of a probe with the system of interest. This approach can be extended by incorporating the possibility of using the non-equilibrium states of the probe, and the presence of coherence. Here, we illustrate how these concepts apply to the single-qubit thermometer introduced by Jevtic et al. by performing a simulation of the qubit-environment interaction in a linear-optical device. We discuss the role of the coherence, and how this affects the usefulness of non-equilibrium conditions. The origin of the observed behaviour is traced back to the propensity to thermalisation, as captured by the Helmholtz free energy., 6 pages, 6 figures