1. Highly Anisotropic Organometal Halide Perovskite Nanowalls Grown by Glancing-Angle Deposition
- Author
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Castillo Seoane, Javier, Contreras Bernal, Lidia, Obrero Pérez, José M., García Casas, Xabier, Lorenzo-Lázaro, Francisco, Aparicio Rebollo, Francisco Javier, López Santos, Carmen, Rojas Ruiz, Teresa Cristina, Anta Montalvo, Juan Antonio, Borrás Martos, Ana Isabel, Barranco Quero, Ángel, Sánchez Valencia, Juan Ramón, Universidad de Sevilla. Departamento de Ingeniería Química, Universidad de Sevilla. Departamento de Física Aplicada I, Universidad de Sevilla. Departamento de Química Inorgánica, Universidad de Sevilla. FQM196: Nanotecnología en Superficies y Plasma, MCIN/AEI/10.13039/501100011033 and by 'ERDF (FEDER) PID2019-110430GB-C21, MCIN/AEI/10.13039/501100011033 and by 'ERDF (FEDER) PID2019-110430GB-C22, MCIN/AEI/10.13039/501100011033 and by 'ERDF (FEDER) PID2019-109603RA-I00, Consejería de Economía, Conocimiento, Empresas y Universidad de la Junta de Andalucía (PAIDI-2020 ) and the EU through cohesion fund and FEDER 2014–2020 programs US-1263142, Consejería de Economía, Conocimiento, Empresas y Universidad de la Junta de Andalucía (PAIDI-2020 ) and the EU through cohesion fund and FEDER 2014–2020 programs US-1381045, Consejería de Economía, Conocimiento, Empresas y Universidad de la Junta de Andalucía (PAIDI-2020 ) and the EU through cohesion fund and FEDER 2014–2020 programs US-1381057, Consejería de Economía, Conocimiento, Empresas y Universidad de la Junta de Andalucía (PAIDI-2020 ) and the EU through cohesion fund and FEDER 2014–2020 programs AT17-6079, Consejería de Economía, Conocimiento, Empresas y Universidad de la Junta de Andalucía (PAIDI-2020 ) and the EU through cohesion fund and FEDER 2014–2020 programs P18-RT-3480, EU H2020 program under the grant agreements 851929 (ERC Starting Grant 3DScavengers), and MCIN/AEI/ 10.13039/501100011033 for SCALEUP SOLAR-ERA.net project PCI2019-111839-2
- Abstract
Polarizers are ubiquitous components in current optoelectronic devices as displays or photographic cameras. Yet, control over light polarization is an unsolved challenge, since the main drawback of the existing display technologies is the significant optical losses. In such a context, organometal halide perovskites (OMHP) can play a decisive role given their flexible synthesis with tunable optical properties such as bandgap and photoluminescence, and excellent light emission with a low non-radiative recombination rate. Therefore, along with their outstanding electrical properties have elevated hybrid perovskites as the material of choice in photovoltaics and optoelectronics. Among the different OMHP nanostructures, nanowires and nanorods have lately arisen as key players in the control of light polarization for lighting or detector applications. Herein, the fabrication of highly aligned and anisotropic methylammonium lead iodide perovskite nanowalls by glancing-angle deposition, which is compatible with most substrates, is presented. Their high alignment degree provides the samples with anisotropic optical properties such as light absorption and photoluminescence. Furthermore, their implementation in photovoltaic devices provides them with a polarization-sensitive response. This facile vacuum-based approach embodies a milestone in the development of last-generation polarization-sensitive perovskite-based optoelectronic devices such as lighting appliances or self-powered photodetectors.
- Published
- 2022