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Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $μ$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission., 31 pages, 18 figures, accepted for publication in ApJ

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI LRS observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000 $\times$ solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities $\leq$300 $\times$ solar due to their large corresponding molecular feature amplitudes, preferring values $\geq$1000 $\times$ solar and column haze production rates $\geq$10$^{-10}$ g cm$^{-2}$ s$^{-1}$. The steam atmosphere scenario with similarly high haze production rates also exhibit sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights $\geq$15 g mol$^{-1}$ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b's atmosphere would likely require multiple transits and eclipses using JWST across the near and mid-infrared, potentially complemented by groundbased high resolution transmission spectroscopy., 21 pages, 10 figures, 4 tables. Accepted for publication by ApJ

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models., Comment: 27 pages, 6 figures, Accepted for publication in Nature, data and models available at https://doi.10.5281/zenodo.6959427

With an increased focus on the observing and modelling of mini-Neptunes, there comes a need to better understand the tools we use to model their atmospheres. In this paper, we present the protocol for the CAMEMBERT (Comparing Atmospheric Models of Extrasolar Mini-neptunes Building and Envisioning Retrievals and Transits) project, an intercomparison of general circulation models (GCMs) used by the exoplanetary science community to simulate the atmospheres of mini-Neptunes. We focus on two targets well studied both observationally and theoretically with planned JWST Cycle 1 observations: the warm GJ~1214b and the cooler K2-18b. For each target, we consider a temperature-forced case, a clear sky dual-grey radiative transfer case, and a clear sky multi band radiative transfer case, covering a range of complexities and configurations where we know differences exist between GCMs in the literature. This paper presents all the details necessary to participate in the intercomparison, with the intention of presenting the results in future papers. Currently, there are eight GCMs participating (ExoCAM, Exo-FMS, FMS PCM, Generic PCM, MITgcm, RM-GCM, THOR, and the UM), and membership in the project remains open. Those interested in participating are invited to contact the authors., Accepted to PSJ

To date, 3D simulations of aerosols in the atmospheres of extrasolar giant planets have almost exclusively focused on condensate clouds. However, for relatively cool hot Jupiters, photochemical hazes are expected to be an important source of opacity. As 1D radiative transfer models show, absorption and scattering from photochemical hazes can change the temperature profile by several hundred Kelvin in these planets. Here, we present 3D simulations of hot Jupiter HD 189733b using SPARC/MITgcm that include radiative feedback from photochemical hazes. We simulated photochemical hazes as radiatively active tracers with a constant particle size of 3 nm. For our nominal simulations, we assumed a soot-like complex refractive index. To explore the dependence on the assumed optical properties, we also performed simulations with a refractive index based on Titan-like hazes. In all simulations with haze radiative feedback, a strong temperature inversion at low pressures forms on the dayside. The response of the atmospheric circulation and the detailed temperature structure strongly depend on the assumed optical properties of the hazes. For soot-like hazes, the equatorial jet slows down and broadens at low pressures. Vertical velocities increase, especially upwelling near the terminator and on the dayside. For Titan-like hazes, the strength of the equatorial jet increases substantially, especially at low pressures. This results in a 3D haze distribution that differs dramatically from simulations without haze feedback or with soot-like hazes. While in simulations with soot-like hazes or without haze feedback, hazes are most concentrated on the nightside and the morning terminator, with lower haze abundances on the dayside and evening terminator, Titan-like hazes are most abundant on the dayside, the evening terminator and in the equatorial region on the nightside. The changed temperature structure affects the model-predicted dayside emission spectrum and phase curve in the near- and mid-infrared, with changes particularly large in the near-infrared water bands and at wavelengths >4 µm for both soot- and Titan-like hazes. In the dayside emission spectrum, the amplitude of the water absorption features is reduced and for the largest haze production rates for soot-like hazes, water is seen in emission rather than in absorption in multiple wavelength regions. The phase curve amplitude increases substantially at most infrared wavelengths when including haze feedback., This research was supported by NASA Headquarters under the NASA Earth and Space Science Fellowship Program - Grant 80NSSC18K1248.