39 results on '"Zan, Bin"'
Search Results
2. Hydrosilylation of ketones catalyzed by novel four-coordinate copper(I) complexes under mild conditions
- Author
-
Zhi-Wen Li, Dong-Li An, Zan-Bin Wei, Yan-Yun Li, and Jing-Xing Gao
- Subjects
Organic Chemistry ,Drug Discovery ,Biochemistry - Published
- 2022
3. Enantioselective Hydrogenation of Ketones Catalyzed by Chiral Cobalt Complexes Containing PNNP Ligand
- Author
-
Dong Zhang, Zhi-Wei Lin, Jing-Xing Gao, Zan-Bin Wei, Yan-Yun Li, and En-Ze Zhu
- Subjects
inorganic chemicals ,010405 organic chemistry ,Ligand ,Organic Chemistry ,Asymmetric hydrogenation ,Enantioselective synthesis ,chemistry.chemical_element ,Noyori asymmetric hydrogenation ,010402 general chemistry ,01 natural sciences ,0104 chemical sciences ,law.invention ,Catalysis ,chemistry ,law ,Yield (chemistry) ,Polymer chemistry ,Organic chemistry ,Electron paramagnetic resonance ,Cobalt - Abstract
Novel chiral cobalt complexes containing a PNNP-type ligand were synthesized using a straightforward method. The structures of the cobalt complexes have been fully characterized by X-ray crystallography, high resolution mass spectrometry (HRMS), and electron paramagnetic resonance (EPR). Using H2 as the hydrogen source, the cobalt-catalyzed asymmetric hydrogenation of various ketones was investigated, and the corresponding chiral alcohols were afforded with up to 99 % yield and 95 % ee. To the best of our knowledge, this is the first example of a cobalt-catalyzed enantioselective hydrogenation of ketones with molecular hydrogen.
- Published
- 2016
4. Synthesis, characterization of novel Nickel(II) complexes with PxNy-Type ligands and their application in reduction of ketones
- Author
-
Zhe Wang, Shenluan Yu, Jing-Xing Gao, Zan-Bin Wei, Yan-Yun Li, and Dong-Li An
- Subjects
Reaction conditions ,010405 organic chemistry ,Chemistry ,Organic Chemistry ,chemistry.chemical_element ,010402 general chemistry ,01 natural sciences ,Biochemistry ,0104 chemical sciences ,Characterization (materials science) ,Inorganic Chemistry ,Nickel ,Polymer chemistry ,Materials Chemistry ,Physical and Theoretical Chemistry - Abstract
Novel nickel(II) complexes 1 and 2 could be conveniently prepared using PxNy-type ligands and easily available NiCl2·6H2O as a starting material. Furthermore, we obtained the single crystals suitable for X-ray diffraction to confirm the structure of these two nickel(II) complexes. With the well-designed nickel(II) complex, the hydrogenation of a wide range of ketones proceeded smoothly under relative mild reaction conditions, affording the corresponding alcohols with high isolated yields.
- Published
- 2019
5. Application of Digital Image Processing Technology in the Process of Ceramic Art Image
- Author
-
Zan Bin Peng
- Subjects
Brightness ,Engineering drawing ,business.product_category ,Computer science ,business.industry ,ComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISION ,Process (computing) ,Image processing ,General Medicine ,law.invention ,law ,visual_art ,Digital image processing ,visual_art.visual_art_medium ,Computer vision ,Ceramic ,Artificial intelligence ,Electron microscope ,business ,Digitization ,ComputingMethodologies_COMPUTERGRAPHICS ,Digital camera ,Microscope image processing - Abstract
With the improvement of computer hardware and software performance, digital multimedia technology has been applied to various fields. The visual effect of ceramic art image is affected mainly by the brightness, texture and color, in which the image defects will affect the visual effect of the ceramic product. This paper designs the digital processing system of a new ceramic art image processing, the system can repair defects in ceramic art image. In order to verify the validity and reliability of digital processing system, the lead-free perovskite structure BZT based ceramics is prepared in this paper, and the use of electron microscope and digital camera take the ceramic products processing image with artistic defects, and then using VB programming digital image processing technology carries out color re coating for the ceramic, the ceramic products electron microscopy images after restoration will be obtained by the image boundary restructuring, which provides a new computer method for the processing art of the ceramic products.
- Published
- 2014
6. Surface Grinding Force Model of Steel 55 Based on Undeformed Chip Thickness with CBN Electroplated Wheels
- Author
-
Ren Zhen Ye, Jun Ming Wang, Hui Peng Chen, and Hong Zan Bin
- Subjects
Grinding process ,Materials science ,Metallurgy ,Surface grinding ,Abrasive ,General Engineering ,Velocity ratio ,Geometric shape ,Electroplating ,Chip ,Grinding - Abstract
Undeformed chip thickness is one of the most important parameters in grinding process, which is related to the entire abrasive grains in grinding simultaneously and changed periodically with time. Simplifying the geometric shape of abrasive grains ,the paper modifies the mathematic models of undeformed chip thickness by analytic method, establishes an universal calculation model of grinding force based on undeformed chip thickness, then optimizes the parameters of the model by restrictive random direction method according to the measuring experiments of the inter-grain spacing about CBN electroplated wheels and the grinding experiments of steel 55 during surface grinding, analyses the influence factors of the friction ratio on the grinding force. The results show that under the same grinding depth, both of the ratio and the grinding force will be decreased with the increase of velocity ratio VS/VW, but the ratio increases and the grinding force decreases with the increase of inter-grain spacing.
- Published
- 2011
7. Research on the technology for outer race elliptical groove grinding with basin-like grinding wheel
- Author
-
Yang Ping Tang, Jun Ming Wang, Hong Zan Bin, Ren Zhen Ye, and Zhen Biao Li
- Subjects
Grinding process ,Engineering ,business.industry ,Mechanical Engineering ,Mechanical engineering ,Constant-velocity joint ,Structural engineering ,Grinding wheel ,Coordinate-measuring machine ,Industrial and Manufacturing Engineering ,Computer Science Applications ,Grinding ,Machining ,Control and Systems Engineering ,Ball (bearing) ,business ,Software - Abstract
A new grinding method that outer race elliptic track in ball basket constant velocity joint is ground by means of basin-like grinding wheel is proposed herein. Aiming at the grinding process with basin-like grinding wheel, the paper establishes the mathematical model, optimizes the parameters by using restrictive random direction method, studies the processing principle in detail, and analyzes the machining errors. The simulation results indicate that the theoretical error of elliptical groove ground by basin-like wheel will be reduced to the level of 0.001 mm. Then, the grinding experiments of elliptical grooves with the basin-like grinding wheel were completed, and the measurements of the grooves by portable arm coordinate measuring machine were carried out, which validates the feasibility of this grinding technology.
- Published
- 2009
8. Syntheses and characterization of elpasolite-type ammonium alkali metal hexafluorometallates(III)
- Author
-
Zan-Bin Wei, Jin-Xiao Mi, Xiao-Xuan Liu, Hua-Yu Sun, and Shu-Ming Luo
- Subjects
Ionic radius ,Absorption spectroscopy ,Hydrogen bond ,Chemistry ,Inorganic chemistry ,Space group ,Crystal structure ,Condensed Matter Physics ,Alkali metal ,Electronic, Optical and Magnetic Materials ,Inorganic Chemistry ,Crystal ,Crystallography ,Lattice constant ,Materials Chemistry ,Ceramics and Composites ,Physical and Theoretical Chemistry - Abstract
Crystal structures of three fluorides (NH 4 ) 2 NaFeF 6 , ( Fe ), (NH 4 ) 2 NaGaF 6 , ( Ga ), and (NH 4 ) 2 NaCrF 6 , ( Cr ), as well as a substituted compound [(NH 4 ) 1− x K x ] 2 KAlF 6 ( x ≈0.17), ( Al ), have been refined using single-crystal and powder X-ray diffraction techniques. All these four ammonium hexafluorides have a cubic elpasolite-type structure and crystallize in the space group Fm 3¯ m with lattice constants a =8.483(3), 8.450 (3), 8.4472(2) and 8.724(3) A for compounds ( Fe) , ( Ga), (Cr) and (Al) , respectively. The effective ionic radius of the ammonium ion calculated from those compounds has a mean value of R =1.729 A for CN=12. An ultraviolet–visible absorption spectrum of (NH 4 ) 2 NaCrF 6 , measured at room temperature, gives a crystal field (Dq=1575 cm −1 ) and Racah parameters ( B =758 cm −1 and C =3374 cm −1 ). Abnormal anisotropic thermal parameters of fluorine atoms have been observed in the compound (Al) , and interpreted to arise from four strong hydrogen bonds (F…H–N) that are distributed in a square form around each fluorine atom.
- Published
- 2008
9. Key techniques of symmetrical machining
- Author
-
Qing-xiu Feng, Hong-zan Bin, Lin-sen Zhu, Cai-hua Xiong, and Yang-ping Tang
- Subjects
Tool path ,Engineering ,Machining ,business.industry ,General Mathematics ,General Engineering ,Mechanical engineering ,Structural engineering ,Mechatronics ,Collision ,business - Abstract
To improve the machining efficiency of large symmetrical freeform surface, this paper proposes a new machining method: symmetrical machining (SM). Based on the concept of collision avoidance plane (CAP), collisions among cutters or headstocks are avoided, and the area of machining residue is controlled effectively. Machining residue is eliminated due to proper design of symmetrical tool in mechanism and control project. Taking 5-axis symmetrical machine with columnar headstocks and flat cutters as example, this paper proposes collision avoidance algorithm. Finally, using a twin-skeg ship model surface as an example, the method is applied to avoiding collisions in original tool path. Simulation and real machining results show that the scheme is practical. Furthermore, the machining efficiency of SM is improved 85% more than that of the traditional single cutter technology.
- Published
- 2008
10. N,N′-Bis(benzamido)thioureas as anion receptors
- Author
-
Zhao Li, Yun-Bao Jiang, Qin-Xian Liao, Zan-Bin Wei, La-Sheng Long, and Zhao Liu
- Subjects
Isosbestic point ,Hydrogen bond ,Stereochemistry ,General Chemical Engineering ,Substituent ,General Chemistry ,Crystallography ,chemistry.chemical_compound ,chemistry ,Thiourea ,Moiety ,Single bond ,Binding site ,Anion binding - Abstract
A series of N,N′-bis(substituted-benzamido)thioureas (3a–e, substituent = p-OEt, p-Me, H, p-Cl, and m-Cl) was designed as anion receptors based on their double hydrogen bonding interaction with anions. NMR and X-ray crystal structural analyses revealed that in these receptor molecules the benzamido moiety serving as a spectral signal reporter and the thiourea moiety as anion binding site were decoupled by the twisted N–N single bond and the two thioureido and amido NH protons experienced differed electronic environment. Yet the absorption spectra of 3a–e in acetonitrile in the presence of anions such as AcO−, F−, and H2PO4− underwent substantial changes by the appearance of a new band at ca. 325 nm, which is red-shifted by ca. 60 nm, and of a clear isosbestic point at 270 nm, suggesting that anion binding led to the communication between thiourea binding site and benzamido signal reporter via probably a conformational change around the N–N bond. The new band energies were found correlating linearly with the Hammett constant of the substituent with a slope of −0.361 eV, indicative of the charge-transfer character of the absorption band. The binding constants for AcO− and F− of 3a–e were obtained at not less than 107 M−1 orders of magnitude, which are much higher than those of the corresponding N,N′-bisarylthioureas. We suggest that anion binding to the thiourea moiety in 3a–e switches on charge transfer in the anion-receptor binding complex, which reinforces anion binding and therefore results in a dramatically enhanced binding affinity of the receptors. The symmetric N,N′-bis(benzamido)thioureas were therefore found better in anion binding and sensing than N-benzamidothioureas.
- Published
- 2008
11. Low‐Temperature Flux Synthesis, Crystal Structure and Ce‐Doped Luminescence of the First Lutetium Diphosphate NH 4 LuP 2 O 7
- Author
-
Dun‐Hua Cao, Mu Gu, Man-Rong Li, Zan‐Bin Wei, Jing-Tai Zhao, Hao‐Hong Chen, Xin‐Xin Yang, and Wei Liu
- Subjects
Inorganic Chemistry ,Crystallography ,Chemistry ,Inorganic chemistry ,Doping ,chemistry.chemical_element ,Crystal structure ,Isostructural ,Ternary operation ,Luminescence ,Lutetium ,Ion ,Monoclinic crystal system - Abstract
The first lutetium diphosphate NH4LuP2O7 has been prepared by a two-step, low-temperature self-flux synthesis in the presence of the F– anion, functioning as a mineralizer, which played a significant role in the synthetic process. The crystal structure has been characterized by single-crystal X-ray diffraction. The title compound crystallizes in a monoclinic system of the space group P21/c (No. 14), a = 7.651(2) A, b = 10.789(2) A, c = 8.577(2) A, β = 105.75(3)°, V = 681.4(2) A3, Z = 4. The three-dimensional framework of NH4LuP2O7, composed of Lu2P4O14 building units formed by vertex-linking LuO6 and P2O7 goups, is isostructural with compounds of the type KAlP2O7 in the ternary diphosphate(AIMIIIP2O7) system. X-ray-excited luminescence measurements of Ce-activated samples show insteresting scintillation properties with a short decay time of 16 ns at room temperature. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
- Published
- 2005
12. Workspace of translation 3-UPU parallel manipulators
- Author
-
Xiang-zkou Zheng, You-go Luo, and Hong-zan Bin
- Subjects
Computer Science::Robotics ,Control theory ,Computer science ,General Mathematics ,General Engineering ,Parallel manipulator ,Workspace ,Mechatronics ,Translation (geometry) ,Performance index ,Condition number - Abstract
To determine workspace and relationship between the workspace and geometry of parallel manipulator is important for optimum design of parallel manipulators. In this paper, the workspace and the relationship between the workspace and the geometry of 3-UPU parallel manipulators with pure translation are investigated. Geometric and non-geometric constraints are denned and taken account of in determining the workspace of the translation 3-UPU manipulators. A direct average condition number is used as the global performance index of the workspace. This research shows that there exists an optimal value of the direct average condition number favorable for a good design of parallel mechanisms. The results presented in this paper are useful for the optimum design of 3-UPU parallel manipulators.
- Published
- 2005
13. Hydrothermal Syntheses, Crystal Structures and Photoluminescent Properties of Three Metal‐Cluster Based Coordination Polymers Containing Mixed Organic Ligands
- Author
-
Rong-Bin Huang, Lan-Sun Zheng, Zan‐Bin Wei, Xin Yin, and Jun Tao
- Subjects
Chemistry ,Stereochemistry ,Infrared spectroscopy ,chemistry.chemical_element ,Zinc ,Crystal structure ,Triclinic crystal system ,Inorganic Chemistry ,Metal ,Crystallography ,visual_art ,visual_art.visual_art_medium ,NIP ,Thermal stability ,Monoclinic crystal system - Abstract
Three novel metal-cluster based coordination polymers (MCCPs) with formulae [Zn4(μ3-OH)2(H2O)2(sip)2(4,4′-bpy)2]·3H2O (MCCP-4), [Cd4(μ3-OH)2(H2O)2(sip)2(4,4′-bpy)4]·H2O (MCCP-5) and [Cd6(μ3-OH)4(μ2-OH2)2(OH2)2 (nip)4(4,4′-bpy)3]·3H2O (MCCP-6) [H2sip = 5-sulfoisophthalic acid, H2nip = 5-nitroisophthalic acid and 4,4′-bpy = 4,4′-bipyridyl] were hydrothermally synthesized and characterized by single-crystal X-ray diffraction studies. MCCP-4 crystallizes in the triclinic space group P with a = 10.106(2), b = 10.851(2), c = 11.125(2) A, α = 105.66(3), β = 112.63(3), γ = 98.18(3)°, V = 1041.8(4) A3, and Z = 2. MCCP-5 crystallizes in the monoclinic space group C2/c with a = 25.602(1), b = 16.571(1), c = 13.322(1) A, β = 92.524(1)°, V = 5646.4(2) A3, and Z = 4. MCCP-4 and -5 consist of similar [M4(μ3-OH)2]6+ tetranuclear building units that are joined through sip and 4,4′-bpy ligands to generate a two-dimensional structure (MCCP-4) and a three-dimensional structure (MCCP-5), respectively. MCCP-6 crystallizes in the triclinic space group P with a = 14.295(2), b = 14.472(2), c = 20.204(3) A, α = 73.362(3), β = 82.200(3), γ = 62.769(2)°, V = 3560.9(10) A3, and Z = 2. MCCP-6 contains unprecedented [Cd6(μ3-OH)4(μ2-OH2)2]8+ hexanuclear building units which are linked through nip and 4,4′-bpy ligands to afford a two-dimensional structure. The infrared spectroscopy, thermal stability and photoluminescence of the three complexes were studied. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
- Published
- 2003
14. Fractal scanning path generation and control system for selective laser sintering (SLS)
- Author
-
Jianzhong Yang, Xiaoyu Zhang, Zuli Liu, and Hong-zan Bin
- Subjects
Rapid prototyping ,Engineering ,business.industry ,Mechanical Engineering ,Topology ,computer.software_genre ,Industrial and Manufacturing Engineering ,law.invention ,Selective laser sintering ,Fractal ,law ,Control system ,Electronic engineering ,Computer Aided Design ,Trimming ,business ,computer ,Stereolithography ,Smoothing - Abstract
A fractal scanning path which is a FASS (space-filling, self-avoiding, simple and self-similar) curve is proposed for selective laser sintering (SLS). The authors’ preliminary research has proved that the samples which are produced by SLS along a fractal scanning path possess improved physical performance. However, the complete FASS fractal curves can only fill a square region, thus a method is developed to realize trimming of the fractal curves suitable for arbitrary boundaries by means of judging intersection points between arbitrary boundaries and the fractal curves as well as to keep the FASS feature. Moreover, a two-lever special control system is built to realize the real-time sintering of samples aiming at the fractal scanning, and the interrupt technology is used for the main-accessory system synchronization.
- Published
- 2003
15. Research on fractal-scanning path for arbitrary boundary layer in Layered Manufacturing
- Author
-
Xiao-Bo Zhang, Hong-zan Bin, and Jia Yang
- Subjects
Boundary layer ,Fractal ,Intersection ,Intersection curve ,General Mathematics ,Fractal derivative ,General Engineering ,Boundary (topology) ,Recursion (computer science) ,Geometry ,Square (algebra) ,Mathematics - Abstract
The fractal curve is proposed as a novel scanning-path used in Layered Manufacturing. Aiming at a limitation that the fractal curve can only fill a square region, a method is developed to realize the trimming of fractal curve in arbitrary boundary layer by means of judging intersection points between parameterized arbitrary boundary and a FASS (space-filling, self-avoiding, simple and self-similar) fractal curve. Accordingly, the related algorithm concerning with determining intersection points has been investigated according to the recursion feature of the fractal curve, and in the process of the fractal curve traversed, the rule of judging intersection points is ascertained as well, so that the laser-scanning beam can “walk” along the fractal curve inside the desired boundary, and arbitrary contour components are fabricated.
- Published
- 2002
16. Crystal structure of potassium indium (monophosphate-hydrogenmonoborate- monophosphate), KIn[BP2O8(OH)]
- Author
-
Rüdiger Kniep, Jing-Tai Zhao, Zan-Bin Wei, J. X. Mi, Man-Rong Li, Shao-Yu Mao, and Ya-Xi Huang
- Subjects
chemistry.chemical_classification ,Crystallography ,Crystal chemistry ,Inorganic chemistry ,Crystal structure ,Triclinic crystal system ,Condensed Matter Physics ,Crystal ,Inorganic Chemistry ,Molecular geometry ,Octahedron ,chemistry ,QD901-999 ,X-ray crystallography ,General Materials Science ,Inorganic compound - Abstract
BHInKO9P2, triclinic, P1 (No. 2), a = 5.2638(4) A, b = 8.4791(5) A, c = 8.1469(9) A, = 91.741(7)°, = 93.061(7)°, = 79.823(5)°, V = 357.3 A, Z = 2, Rgt(F) = 0.052, wRref(F) = 0.113, T = 293 K. Source of material KIn[BP2O8(OH)] was synthesized under mild hydrothermal conditions. The reactions were carried out with mixtures of In metal (0.057 g) dissolved in 1 ml of HCl (18%), H3BO3 (0.062 g) and K2HPO4 (0.522 g) (molar ratio of In:P:B = 1:2:3) in aqueous solution. The mixtures were sealed in glass tubes (after adding 1 ml H2O to achieve a degree of filling of 30%) with subsequent heating at 418 K for 14 days. The starting materials were all of analytical purity grade. Discussion With the increasing interest in microporous materials, the syntheses of compounds like borophosphates with open framework structures have drawn much attention during the past few years and show a rich crystal chemistry [1]. Systems including a p-block metal have not been widely explored up to now besides two compounds with Al and Ga [2,3] reported only recently and two phases with In in the present issue [4,5]. The structure of the title compound is isotypic to the K-Fe [6] and ammonium-In analogues [5]. The structure is characterized by isolated InO5(OH) octahedra sharing common O-corners with phosphate and common O(OH)-corner with hydrogenborate groups from the trinuclear oligomeric units [B2P4O16(OH)2]. The condensation of the borophosphate oligomers with In-coordination octahedra via common corners results in a three-dimensional framework which contains elliptical channels running along the a axis. The cross section of the channels is defined by eight-membered octahedral/tetrahedral rings (two In coordination octahedra, four phosphateand two borate-groups). Potassium ions are distributed within the open channels. The In—O and In—OH bond distances range from 2.110 A to 2.179 A. Both the oligomeric borophosphate and the coordination octahedron of In are similar to its K-Feand NH4-In-analogues [5,6] by considering the bond distances In—O, P—O and B—O and bond angles. Z. Kristallogr. NCS 217 (2002) 3–4 3 © by Oldenbourg Wissenschaftsverlag, Munchen Crystal: colorless prism, size 0.2 × 0.25 × 0.3 mm Wavelength: Mo K radiation (0.71073 A) : 44.09 cm Diffractometer, scan mode: Enraf Nonius CAD4, /2 2 max: 68.04° N(hkl)measured, N(hkl)unique: 3081, 2910 Criterion for Iobs, N(hkl)gt: Iobs > 2 (Iobs), 2126 N(param)refined: 131 Program: SHELXL-97 [7] Table 1. Data collection and handling. H(1) 2i 0.68(2) 0.51(1) 0.64(1) 0.05 Table 2. Atomic coordinates and displacement parameters (in A). Atom Site x y z Uiso
- Published
- 2002
17. Hydrothermal Synthesis and Crystal Structure of the First Ammonium Indium(III) Phosphate NH4In(OH)PO4 with Spiral Chains of InO4(OH)2
- Author
-
Jing-Tai Zhao, H.-H. Chen, Shao-Yu Mao, Ya-Xi Huang, Jin-Xiao Mi, Zan-Bin Wei, and M.-R. Li
- Subjects
Hydrogen bond ,Inorganic chemistry ,chemistry.chemical_element ,Crystal structure ,Condensed Matter Physics ,Alkali metal ,Hydrothermal circulation ,Electronic, Optical and Magnetic Materials ,Inorganic Chemistry ,chemistry.chemical_compound ,Tetragonal crystal system ,Crystallography ,chemistry ,Materials Chemistry ,Ceramics and Composites ,Hydrothermal synthesis ,Ammonium ,Physical and Theoretical Chemistry ,Indium - Abstract
An ammonium indium hydrogen phosphate, NH 4 In(OH)PO 4 , was synthesized under mild hydrothermal conditions, and the crystal structure was characterized by single-crystal X-ray diffraction method. The compound crystallizes with the RbIn(OH)PO 4 type with the following data: M r =244.84, tetragonal, tP 104, P 4 3 2 1 2 (No.96), a =9.416(2) A, c =11.159(3) A, V =989.9(3) A 3 , Z =8, D x =3.288 g cm −3 , λ =0.71073 A, μ =50.34 cm −1 , F (000)=928, T =293 K, R 1=0.0606, wR 2=0.1472 for 91 variables and 1813 contributing unique reflections. The structure is characterized by chiral InO 4 (OH) 2 chains along the c axis formed by sharing OH corners. The chains are isolated by PO 4 tetrahedra leading to a three-dimensional framework structure with channels occupied by NH 4 + ions. The framework structure is similar to that of KIn(OH)PO 4 and γ -NaTiOPO 4 . The hydrogen bonds formed by NH 4 + with the polyhedral oxygen atoms play an important role in the anisotropic changes of the lattice with respect to its alkali metal analogues. The topological construction of the title structure can be considered as an augmented 4,6-net with larger porosity.
- Published
- 2002
18. Hydrothermal Synthesis, Crystal Structure, and Characterization of Tetrasodium Tricobalt(II)-bis-Phosphate-bis-Hydrogenophosphate Octahydrate, Na4Co3H2(PO4)4·8H2O, with a New Structure Type
- Author
-
Jing-Tai Zhao, Shao-Yu Mao, Ya-Xi Huang, Zhong-Le Huang, Jin-Xiao Mi, and Zan-Bin Wei
- Subjects
Valence (chemistry) ,Chemistry ,Inorganic chemistry ,Crystal structure ,Condensed Matter Physics ,Magnetic susceptibility ,Electronic, Optical and Magnetic Materials ,Inorganic Chemistry ,chemistry.chemical_compound ,Crystallography ,Octahedron ,Materials Chemistry ,Ceramics and Composites ,Hydrothermal synthesis ,Physical and Theoretical Chemistry ,Hydrate ,Cobalt phosphate ,Monoclinic crystal system - Abstract
A sodium cobalt hydrogen phosphate hydrate, Na 4 Co 3 H 2 (PO 4 ) 4 ·8H 2 O, was synthesized by the mild hydrothermal method, and the crystal structure was characterized by the single-crystal X-ray diffraction method. The layered structure possesses a new type with the following data: Mr=794.775, monoclinic, mP 106, P 2 1 / c – e 26 d (No. 14), a =7.3547(9) A, b =9.222(1) A, c =15.186(2) A, β =95.18(1)°, V =1025.9(3) A 3 , Z =2, Dx =2.573 g cm −3 , λ =0.71073 A, μ =29.0 cm −1 , F (000)=790, T =293 K, R =0.0346, w R =0.0432 for 198 variables and 2278 contributing unique reflections. The structure is characterized by corner- and edge-sharing deformed CoO 5 trigonal bipyramids with PO 4 tetrahedra forming an infinite ribbon along the [010] direction. The ribbons are connected by bridging CoO 6 octahedra resulting in a novel three-cobalt polymeric coordination unit and a polyhedral sheet. The same sheets are packed along the c -axis by sandwiching Na + cations and hydrogen-bonded water molecules to construct the whole structure. The temperature dependence of the magnetic susceptibility of the compound follows the Curie–Weiss law, and the effective magnetic moment of 4.69 μ B corresponds to high-spin Co 2+ ion, confirmed by bond valence sum calculations.
- Published
- 2000
19. Diammonium sodium hexafluoroaluminate, (NH4)2NaAlF6
- Author
-
Cheng-Xin Wang, Jin-Xiao Mi, Shu-Ming Luo, Zan-Bin Wei, and Xiao-Xuan Liu
- Subjects
chemistry.chemical_compound ,Crystallography ,Chemistry ,Sodium ,Aluminate ,chemistry.chemical_element ,General Materials Science ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,HEXA - Abstract
Diammonium sodium hexafluoroaluminate, (NH4)2NaAlF6, obtained by hydrothermal synthesis, comprises [AlF6]3− octahedra forming a face-centred cubic (fcc) arrangement, with Na+ cations filling all octahedral interstices and NH4+ cations filling all tetrahedral interstices.
- Published
- 2006
20. K2Fe[H(HPO4)2]F2
- Author
-
Fu-Jin Chen, Zan-Bin Wei, Cheng-Xin Wang, Chun-Yan Xu, Shao-Yu Mao, and Jin-Xiao Mi
- Subjects
Diffraction ,Crystallography ,chemistry.chemical_compound ,Hydrogen ,Chemistry ,Difluoride ,chemistry.chemical_element ,General Materials Science ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,Phosphate - Abstract
The crystal structure of dipotassium iron(III) {hydrogen bis[hydrogenphosphate(V)]} difluoride, K2Fe[H(HPO4)2]F2, obtained by hydrothermal synthesis, was determined from single-crystal X-ray diffraction data. The structure is characterized by K+ cations and hydrogen-bonded {[Fe[H(HPO4)2]F2]2−}n chains, which consist of centrosymmetric Fe[F2O4] octahedra linked to their four neighbouring phosphate tetrahedra via common O corners, developing a three-dimensional structure.
- Published
- 2005
21. Ethyl 2-methoxycarbonylamino-3-phenylpropionate
- Author
-
Hua Fang, Bin Tan, Zan-Bin Wei, and Li-Ren Jin
- Subjects
chemistry.chemical_compound ,Malonate ,chemistry ,Hydrogen bond ,Product (mathematics) ,Intermolecular force ,General Materials Science ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,complex mixtures ,Medicinal chemistry - Abstract
The title compound, C13H17NO4, has been obtained as an unexpected product when attempting to prepare diethyl (S)-2-(2-methoxycarbonylamino-3-phenylpropionyl)malonate. The crystal structure involves intermolecular N—H⋯O hydrogen bonds.
- Published
- 2005
22. Renal Protective Role of Xiexin Decoction with Multiple Active Ingredients Involves Inhibition of Inflammation through Downregulation of the Nuclear Factor-κB Pathway in Diabetic Rats
- Author
-
Wu, Jia-sheng, Shi, Rong, Zhong, Jie, Lu, Xiong, Ma, Bing-liang, Wang, Tian-ming, Zan, Bin, Ma, Yue-ming, Cheng, Neng-neng, and Qiu, Fu-rong
- Subjects
Article Subject ,lcsh:Other systems of medicine ,lcsh:RZ201-999 ,Research Article - Abstract
In Chinese medicine, Xiexin decoction (XXD) has been used for the clinical treatment of diabetes for at least 1700 years. The present study was conducted to investigate the effective ingredients of XXD and their molecular mechanisms of antidiabetic nephropathy in rats. Rats with diabetes induced by high-fat diet and streptozotocin were treated with XXD extract for 12 weeks. XXD significantly improved the glucolipid metabolism disorder, attenuated albuminuria and renal pathological changes, reduced renal advanced glycation end-products, inhibited receptor for advanced glycation end-product and inflammation factors expression, suppressed renal nuclear factor- κ B pathway activity, and downregulated renal transforming growth factor- β 1. The concentrations of multiple components in plasma from XXD were determined by liquid chromatography and tandem mass spectrometry. Pharmacokinetic/pharmacodynamic analysis using partial least square regression revealed that 8 ingredients of XXD were responsible for renal protective effects via actions on multiple molecular targets. Our study suggests that the renal protective role of XXD with multiple effective ingredients involves inhibition of inflammation through downregulation of the nuclear factor- κ B pathway, reducing renal advanced glycation end-products and receptor for advanced glycation end-product in diabetic rats.
- Published
- 2013
23. Vehicular sensing networks
- Author
-
Zan, Bin
- Abstract
The increasing integration of sensors and wireless communication devices into highly mobile platforms such as automobiles makes vehicular sensing networks one of the most promising platforms for many applications. The performance of applications such as traffic reporting, environmental monitoring and distributed surveillance can be improved by using the new techniques developed in vehicular sensing networks. Several distinct features such as highly mobile and predictable movement patterns make vehicular sensing networks different from general computer networks. Therefore, unique solutions for vehicular sensing networks are necessary. In this thesis, we show our efforts on three aspects of vehicular sensing networks: efficiency, security and privacy. The efficiency issue is most critical when there is no central infrastructure or when vehicle-to-infrastructure (V2I) communication bandwidth is a precious resource. Keep uploading every piece of sensor data to a remote server is obviously inefficient. Local data aggregation is required to reduce the communication cost and improve the efficiency. However, how and when to perform the aggregation is not trivial. In this work, a GeoCache concept and Boomerang anchoring protocol are proposed to address this issue. Our work in security is focused on building secret keys for both vehicle-to-vehicle (V2V) and the V2I communication modes. Many applications require secure V2V and V2I communications and two sets of secret keys need to be created independently. Based on the special characteristics existing in vehicular sensing networks, we develop two key agreement algorithms to achieve the target. In many of the applications developed within vehicular sensing networks, GPS data has to be submitted to the central server continuously, which results in serious privacy violation. We have three contributions under the privacy domain. First, we develop a privacy preserving algorithm which protects user privacy without filtering too many location traces. Second, we study the possible privacy leakage due to the detailed location information available. At last, we extend the privacy system design under the assumption that there is no location proxy server and the information available is limited.
- Published
- 2013
- Full Text
- View/download PDF
24. Morpholinium dihydrogen citrate hydrate
- Author
-
Zan-Bin Wei, Can-Yu Chen, Seik Weng Ng, and Zhao-Hui Zhou
- Subjects
Crystal ,Crystallography ,Chemistry ,Inorganic chemistry ,General Materials Science ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,Hydrate - Abstract
In the crystal structure of the title compound, [O(CH2CH2)2NH2][C6H7O7]·H2O, the cation interacts with the negatively charged carboxylato group of adjacent anions [N⋯O 2.847 (3) and 2.942 (3) A], forming a linear chain running along the b axis of the crystal. Adjacent chains are linked through the carboxylic —CO2H groups and the water molecule into a layer structure.
- Published
- 2003
25. ChemInform Abstract: Syntheses and Characterization of Elpasolite-Type Ammonium Alkali Metal Hexafluorometallates(III)
- Author
-
Hua-Yu Sun, Shu-Ming Luo, Zan-Bin Wei, Jin-Xiao Mi, and Xiao-Xuan Liu
- Subjects
Crystal ,Crystallography ,chemistry.chemical_compound ,Ionic radius ,Lattice constant ,Absorption spectroscopy ,Chemistry ,Hydrogen bond ,Ammonium ,General Medicine ,Crystal structure ,Alkali metal - Abstract
Crystal structures of three fluorides (NH 4 ) 2 NaFeF 6 , ( Fe ), (NH 4 ) 2 NaGaF 6 , ( Ga ), and (NH 4 ) 2 NaCrF 6 , ( Cr ), as well as a substituted compound [(NH 4 ) 1− x K x ] 2 KAlF 6 ( x ≈0.17), ( Al ), have been refined using single-crystal and powder X-ray diffraction techniques. All these four ammonium hexafluorides have a cubic elpasolite-type structure and crystallize in the space group Fm 3¯ m with lattice constants a =8.483(3), 8.450 (3), 8.4472(2) and 8.724(3) A for compounds ( Fe) , ( Ga), (Cr) and (Al) , respectively. The effective ionic radius of the ammonium ion calculated from those compounds has a mean value of R =1.729 A for CN=12. An ultraviolet–visible absorption spectrum of (NH 4 ) 2 NaCrF 6 , measured at room temperature, gives a crystal field (Dq=1575 cm −1 ) and Racah parameters ( B =758 cm −1 and C =3374 cm −1 ). Abnormal anisotropic thermal parameters of fluorine atoms have been observed in the compound (Al) , and interpreted to arise from four strong hydrogen bonds (F…H–N) that are distributed in a square form around each fluorine atom.
- Published
- 2008
26. Low-Temperature Flux Synthesis, Crystal Structure and Ce-Doped Luminescence of the First Lutetium Diphosphate NH4LuP2O7
- Author
-
Xin‐Xin Yang, Zan‐Bin Wei, Dun‐Hua Cao, Hao‐Hong Chen, Man-Rong Li, Jing-Tai Zhao, Mu Gu, and Wei Liu
- Subjects
Crystallography ,Chemistry ,Doping ,chemistry.chemical_element ,General Medicine ,Crystal structure ,Isostructural ,Luminescence ,Ternary operation ,Lutetium ,Ion ,Monoclinic crystal system - Abstract
The first lutetium diphosphate NH4LuP2O7 has been prepared by a two-step, low-temperature self-flux synthesis in the presence of the F– anion, functioning as a mineralizer, which played a significant role in the synthetic process. The crystal structure has been characterized by single-crystal X-ray diffraction. The title compound crystallizes in a monoclinic system of the space group P21/c (No. 14), a = 7.651(2) A, b = 10.789(2) A, c = 8.577(2) A, β = 105.75(3)°, V = 681.4(2) A3, Z = 4. The three-dimensional framework of NH4LuP2O7, composed of Lu2P4O14 building units formed by vertex-linking LuO6 and P2O7 goups, is isostructural with compounds of the type KAlP2O7 in the ternary diphosphate(AIMIIIP2O7) system. X-ray-excited luminescence measurements of Ce-activated samples show insteresting scintillation properties with a short decay time of 16 ns at room temperature. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
- Published
- 2006
27. Methyl 2-(2-carboxy-3-hydroxy-5-methylphenoxy)-5-hydroxy-3-methoxybenzoate
- Author
-
Zan-Bin Wei, Dan-Qing Pei, Hua Fang, Mei-Juan Fang, and Yufen Zhao
- Subjects
Chemistry ,Stereochemistry ,Hydrogen bond ,General Materials Science ,General Chemistry ,Condensed Matter Physics ,Molecular conformation - Abstract
In the title compound, C17H16O8, intermolecular O—H⋯O hydrogen bonds link adjacent molecules to form a chain. There are also intramolecular hydrogen bonds which stabilize the molecular conformation.
- Published
- 2007
28. (4S)-Benzyl 4-methyl-5-oxo-1,3-oxazolidine-3-carboxylate
- Author
-
Guo Tang, Zan-Bin Wei, Mei-Juan Fang, Yufen Zhao, and Kan Lin
- Subjects
Oxazolidine ,chemistry.chemical_compound ,chemistry ,Stereochemistry ,General Materials Science ,General Chemistry ,Carboxylate ,Dihedral angle ,Condensed Matter Physics ,Ring (chemistry) ,Medicinal chemistry - Abstract
In the title compound, C18H17NO4, the carboxylate group is approximately coplanar with the oxazolidine ring, the largest deviation from the least-squares plane being 0.144 (2) A at the nitrogen atom. The two benzyl rings are located on the same side of this plane, and make dihedral angles with it of 75.23 (4) and 56.97 (7)°.
- Published
- 2006
29. Dimethyl [hydroxy(phenyl)methyl]phosphonate
- Author
-
Hua Fang, Zan-Bin Wei, Zhi-Ping Zeng, Yufen Zhao, and Mei-Juan Fang
- Subjects
Benzaldehyde ,chemistry.chemical_compound ,chemistry ,Hydrogen bond ,General Materials Science ,Dimethyl phosphite ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,Medicinal chemistry ,Phosphonate - Abstract
The title compound, C9H13O4P, has been obtained by the reaction of dimethyl phosphite and benzaldehyde. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules into infinite chains.
- Published
- 2006
30. (3S,4S)-tert-Butyl 4-dibenzylamino-3-hydroxy-5-phenylpentanoate
- Author
-
Rong-Bin Huang, Zan-Bin Wei, Bin Tan, Jian-Feng Zheng, and Li-Ren Jin
- Subjects
Tert butyl ,symbols.namesake ,Stereochemistry ,Chemistry ,Product (mathematics) ,symbols ,General Materials Science ,General Chemistry ,Crystal structure ,van der Waals force ,Condensed Matter Physics ,Medicinal chemistry - Abstract
The title compound, C29H35NO3, was obtained as a major product by reduction of (S)-tert-butyl 4-dibenzylamino-3-oxo-5-phenylpentanoate. The molecular packing in the crystal structure is stabilized by weak intermolecular interactions and van der Waals forces.
- Published
- 2006
31. (3S,4S)-4-Amino-5-phenylpentane-1,3-diol
- Author
-
Zan-Bin Wei, Bin Tan, Li-Ren Jin, Hua Fang, and Rong-Bin Huang
- Subjects
Crystallography ,chemistry.chemical_compound ,Hydrogen bond ,Stereochemistry ,Plane (geometry) ,Chemistry ,Diol ,General Materials Science ,General Chemistry ,Crystal structure ,Link (geometry) ,Condensed Matter Physics - Abstract
The title compound, C11H17NO2, was obtained by hydrogenolysis of (3S,4S)-4-(dibenzylamino)-5-phenylpentane-1,3-diol. In the crystal structure, intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the molecules into a sheet parallel to the ab plane.
- Published
- 2005
32. Diamminediaquabis(4-pyridylthioacetato)copper(II)
- Author
-
Jian-Gu Chen, Wei Zou, Li Li, Seik Weng Ng, Hui Zhang, Yong-Qing Huang, and Zan-Bin Wei
- Subjects
Crystallography ,Octahedron ,Chemistry ,Atom ,chemistry.chemical_element ,General Materials Science ,General Chemistry ,Condensed Matter Physics ,Copper ,Special position - Abstract
The Cu atom in the title compound, [Cu(C7H6NO2S)2(H2O)2(NH3)2], lies on a special position at a crystallographic inversion centre and has a tetragonally distorted octahedral coordination involving the N atoms of two ammine ligands [Cu—N = 2.010 (2) A], the N atoms of two pyridylthioacetate ligands [Cu—N = 2.033 (2) A] and the O atoms of two water molecules [Cu—O = 2.472 (2) A].
- Published
- 2004
33. 7,8-Dihydroxy-3-methyl-10-oxo-1H,10H-pyrano[4,3-b]chromene-9-carboxylic acid
- Author
-
Mei-Juan Fang, Yong-Jie Zhang, Yufen Zhao, Zan-Bin Wei, Jian-Feng Wang, Yaojian Huang, Zhonghui Zheng, and Wenjin Su
- Subjects
chemistry.chemical_classification ,chemistry.chemical_compound ,Paecilomyces sp ,Chemistry ,Stereochemistry ,Carboxylic acid ,Metabolite ,Chromone ,General Materials Science ,General Chemistry ,Acid group ,Condensed Matter Physics ,Ring (chemistry) - Abstract
The structure of the title compound, anhydrofulvic acid, C14H10O7, a yellow acidic metabolite isolated from Paecilomyces sp. was determined by X-ray analysis. The chromone ring system is essentially planar, with the carboxylic acid group coplanar with the ring.
- Published
- 2003
34. Measurement of the deformation on a joint of combined precision ball screw
- Author
-
Hong-Zan Bin, Hongguan Wu, and Fu-Run Zhang
- Subjects
Computer Science::Robotics ,Condensed Matter::Materials Science ,Materials science ,business.industry ,Ball (bearing) ,Structural engineering ,Ball screw ,business ,Finite element method - Abstract
Based on the finite element method the deformation of the joint of linked ball screws is analyzed in detail Meanwhile the calculation results are testified with the strain gauging method. The conclusions of this paper are important to design and manufacture of the joint structure of linked ball screws.
- Published
- 1993
35. Crystal structure of sodium gallium [monohydrogenmonophosphatedihydrogenmonoborate- monophosphate], NaGa[BP2O7(OH)3]
- Author
-
Ya-Xi Huang, Shao-Yu Mao, Rüdiger Kniep, Zan-Bin Wei, Jing-Tai Zhao, and Jin-Xiao Mi
- Subjects
Crystallography ,Aqueous solution ,Crystal chemistry ,Chemistry ,Stereochemistry ,Crystal structure ,Condensed Matter Physics ,Inorganic Chemistry ,Crystal ,Metal ,Octahedron ,QD901-999 ,visual_art ,visual_art.visual_art_medium ,General Materials Science ,Diffractometer ,Monoclinic crystal system - Abstract
BGaH3NaO10P2, monoclinic, C12/c1 (No. 15), a = 10.408(3) A, b = 8.094(2) A, c = 9.099(2) A, = 116.64(2)°, V = 685.2 A, Z = 4, Rgt(F) = 0.025, wRref(F ) = 0.068, T = 293 K. Source of material NaGa[BP2O7(OH)3] was synthesized under mild hydrothermal conditions. The reaction was carried out with mixtures of Ga metal (0.139 g) dissolved in 1ml of HCl (18%) with Na2HPO4·12H2O (1.075 g) and Na2B4O7·10H2O (0.4767 g) (molar ratio of Ga:P:B = 2:3:6) in aqueous solution. The mixture was sealed in glass tubes (after adding 1 ml H2O to achieve a degree of filling of 30%) with subsequent heating at 408 K for 60 days. The starting materials are all of analytical grade. Discussion With the increasing interest in microporous materials, synthesis of compounds like borophosphates with open framework structure have drawn much attention during the past few years and show a rich crystal chemistry [1]. Systems including a p-block metal have not been widely explored up to now besides one Al compound [2] reported only recently. The structure of the title compound is isotypic to the Fe [3] and Al analogues [2] and is characterized by isolated GaO4(OH)2 octahedra sharing common O-corners with phosphate and common O(OH)-corners with hydrogenborate groups from the ol igomeric uni ts [B2P2O7(OH)3]. The condensation of the borophosphate oligomers with Ga-coordination octahedra via common corners results in an overall three-dimensional framework which contains elliptical channels running along the [001] direction. The cross section of the channels is defined by eight-membered octahedral/tetrahedral rings (four Ga coordination octahedra, two phosphateand two borate-groups). Sodium ions are distributed within the open channels. The Ga—O bond distances are 1.925 and 1.965 A, while the Ga—OH value is increased to 1.995 A. The bond distances P—O and B—O in the oligomeric borophosphate groups correspond to respective values in the Feand Al-analogues [2,3]. Z. Kristallogr. NCS 216 (2001) 15–16 15 © by Oldenbourg Wissenschaftsverlag, Munchen Crystal: colorless, prism, size 0.15 × 0.2 × 0.3 mm Wavelength: Mo K radiation (0.71073 A) : 45.94 cm Diffractometer, scan mode: Enraf Nonius CAD4, non-profiled scans 2 max: 69.86° N(hkl)measured, N(hkl)unique: 850, 737 Criterion for Iobs, N(hkl)gt: Iobs > 2 (Iobs), 676 N(param)refined: 75 Program: SHELXS-97 [4] Table 1. Data collection and handling. H(1) 4c 1/4 –1/4 1/2 0.05 H(2) 8f 0.485(7) 0.163(6) 0.591(7) 0.05 Table 2. Atomic coordinates and displacement parameters (in A). Atom Site x y z Uiso
- Published
- 2001
36. 4-Bromo-2-chloroaniline
- Author
-
Zan-Bin Wei, Zhi-Hong Liu, Jian-Liang Ye, and Hong-Kui Zhang
- Subjects
Crystal ,Crystallography ,chemistry.chemical_compound ,Information retrieval ,Aniline ,Chemistry ,Hydrogen bond ,QD901-999 ,General Materials Science ,General Chemistry ,Condensed Matter Physics ,Organic Papers - Abstract
The title compound, C6H5BrClN, is almost planar (r.m.s. deviation = 0.018 Å). In the crystal, molecules are linked by intermolecular N—H...N and weak N—H...Br hydrogen bonds, generating sheets.
- Published
- 2009
37. A Microprocessor-Based Control Scheme for the Improvement of Contouring Accuracy
- Author
-
Hong Zan Bin, M.F. DeVries, K. Yamazaki, and John G. Bollinger
- Subjects
Scheme (programming language) ,Engineering ,Contouring ,business.product_category ,business.industry ,Mechanical Engineering ,Feed drive ,Control (management) ,Kinematics ,Industrial and Manufacturing Engineering ,law.invention ,Machine tool ,Microprocessor ,Control theory ,law ,business ,computer ,ComputingMethodologies_COMPUTERGRAPHICS ,computer.programming_language - Abstract
The kinematic accuracy between axes is very important when an NC machine tool performs a contouring cut. This paper describes a theoretical and experimental investigation in which undesired kinematic errors were reduced by means of a microprocessor-based control scheme. A theoretical model representing the relationship between the dynamic behavior and the controller performance in one axis was first developed and then extended to two-axis contouring operations. Based on these relationships, either a closed-loop proportional (P) or proportional-integral (PI) controller can be optimally designed to manipulate the machine tool feed drive system to achieve high precision. Experiments were performed on an existing three-axis NC milling machine that verified the concepts introduced in this paper. The analytical controller design and implementation procedure are also detailed in this paper.
- Published
- 1983
38. A Stochastic Approach to the Measurement and Analysis of Leadscrew Drive Kinematic Errors
- Author
-
K. Yamazaki, M. F. DeVries, and Hong Zan Bin
- Subjects
Patient diagnosis ,Engineering ,Control theory ,law ,business.industry ,Kinematics ,Mechanical drive ,Servomechanism ,business ,Position control ,law.invention ,Leadscrew ,Transmission errors - Abstract
A practical way to achieve machine tool drive system accuracy is through compensation in the position control loop. Various strategies have been developed in which the compensation data are stored either in a computer or by alternative techniques. The approach described in this paper demonstrates how the dominant causes of the inaccuracies in machine tool drive systems can be determined in a simple and straightforward manner and how the compensation data can be generated using a microprocessor-based calibration technique. The proposed method was demonstrated on a Giddings & Lewis Model 10V Numericenter and consists of three major steps: 1) accuracy measurement, 2) error-map representation, and 3) error-map analysis and error cause diagnosis. Accuracy measurement was accomplished by reading both the resolver counts and the output of a laser interferometer which served as a reference (master) scale. The procedure is based on a strategy in which small 0.5 mm (0.020 in.), highly accurate ±2.5 μm ( ± 0.0001 in.) linear displacements of the machine tool table motion are taken as the measurement reference. An ARMA (Autoregressive Moving Average) model of order (16, 15) is the statistically adequate model that fit the data of the angular displacement of the resolver. The Dynamic Data System technique was used for this purpose and it can also be used to represent the error-map function. A spectral analysis of the ARMA model revealed the sources of the kinematic errors.
- Published
- 1984
39. Microprocessor-Based Compensation of Leadscrew Drive Kinematic Errors by a Forecasting Technique
- Author
-
Hong Zan Bin and Marvin F. DeVries
- Subjects
Microprocessor ,Control theory ,Computer science ,law ,Microcomputer ,Dynamic data ,Control engineering ,Autoregressive–moving-average model ,Kinematics ,Leadscrew ,Compensation (engineering) ,law.invention - Abstract
A microcomputer-based forecasting technique for compensating leadscrew drive kinematic errors by the DDS (Dynamic Data Systems) approach is proposed in this paper. The kinematic error of a particular leadscrew drive system was described by an ARMA(16,15) model. In order to facilitate on-line compensation, an AR(9) model was fit instead of the ARMA model. Both models revealed the same dominate error components and have similar spectral plots.
- Published
- 1984
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.