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The Early Cretaceous Yellow Cat Member of the terrestrial Cedar Mountain Formation in Utah, USA. has been interpreted as a “time-rich” unit because of its dinosaur fossils, prominent paleosols, and the results of preliminary chemostratigraphic and geochronologic studies. Herein, we refine prior interpretations with: (1) a new composite C-isotope chemostratigraphic profile from the well-known Utahraptor Ridge dinosaur site, which exhibits δ13C features tentatively interpreted as the Valanginian double-peak carbon isotope excursion (the so-called “Weissert Event”) and some unnamed Berriasian features; and (2) a new cryptotephra zircon eruption age of 135.10 ± 0.30/0.31/0.34 Ma (2σ) derived from the CA-ID-TIMS U-Pb analyses of zircons from a paleosol cryptotephra. Our interpretations of δ13C features on our chemostratigraphic profile, in the context of our new radiometric age, are compatible with at least one prior age model for the “Weissert Event” and the most recent revision of the Cretaceous time scale. Our results also support the interpretation that the Yellow Cat Member records a significant part of Early Cretaceous time.

Chongqing is a mountain city in western China with a complex geological environment, which brings many difficulties to the construction of large sections of underground projects. In order to avoid serious problems in the construction of Guobo Station with large sections, intensive coring and laboratory tests were carried out to obtain the rock mass properties in detail. The boreholes reveal that the lithology of the rock mass in the project area consists mainly of mudstone and a small area of sandstone. The uniaxial compressive strength (UCS) and the Brazilian tensile strength (BTS) of mudstone are highly scattered, which are 4.43~42.43 MPa and 0.66~4.30 Mpa, respectively, but they all show a lognormal distribution. The average UCS of sandstone is 65.31 MPa, and the BTS is 3.06 MPa. Meanwhile, the softening coefficients of mudstone and sandstone are 0.33 and 0.73, which indicate that the water content has a great influence on the mechanical properties of the rock. For the in situ stress field, the relationship between the three principal stresses is as follows: the maximum horizontal principal stress > minimum horizontal principal stress > vertical principal stress, and the lateral pressure coefficient is 2.11~5.71. Based on the present experimental results, it is proposed that the potential risks of excavation include: (1) bias pressure (2) high in situ stress; (3) surrounding rock deterioration.

In geological engineering, a series of safety problems caused by expansive mudstone are common, such as slope instability and roadbed up-arch. In this paper, the mineral composition of mudstones in the Xining area was analyzed by X-ray diffraction (XRD), and the microstructural and morphological changes of mudstones after water absorption were observed by scanning electron microscopy (SEM) test to analyze the internal factors and microstructural evolution patterns of water absorption and swelling of mudstones. Based on the microstructural units, the mudstones were defined into two categories, one is N-type mudstone with flat sheet-like stromatolite units, and the other is SN-type mudstone with more clastic particle units. Water absorption experiments were conducted on the rock samples to study the microstructure of these two types of mudstones under different water absorption conditions. The pore characteristics of the mudstones were analyzed by using Image-Pro Plus to reveal the water absorption mechanism. The results show that the pore area of N-type mudstone is smaller, as well as the distribution of pore diameter. The pore area of N-type mudstone develops rapidly, in the early stage of water absorption, lots of pores are produced, and the pore area of SN-type mudstone shows an overall decreasing trend. The pore area and the number of SN-type mudstones are at a low level after full water absorption. Under the condition of full immersion, water enters the pores rapidly and soluble salts are dissolved in large quantities. The change of water absorption rate of mudstone with time can be divided into the stage of sudden increase, decrease and stability of water absorption rate. Then, based on the stress theory, the relationship between the macroscopic expansion process and the microstructure of mudstone was analyzed. Finally, the energy basis of mudstone water absorption is discussed. In the swelling of mudstone, the energy gradually turns into swelling strain energy.

The mechanical characteristics of rocks, such as their strength, elastic modulus, porosity and permeability, have been found to be reduced in the presence of water. Researches have been contacted in a range of rock types, mostly in sedimentary rocks; igneous and metamorphic rocks have been lesser investigated. From all of the available literature, it has been found that indeed water has a negative effect on such properties However, the magnitude of it is not well defined, since the range of the reduction is great through different rock types, or even into the same rock type. In the present thesis, the role of clay minerals in the unconfined compressive strength reduction of rocks is investigated. The survey starts with providing the basic background of clay mineral structure and behavior, after hydration. The basic aspects investigated, are the mechanisms related to clay minerals, the unconfined compressive strength loss magnitude at different saturation degrees, as well as at wetting and drying cycles, the saturation time influence, and how the strength loss behavior changes when saturated with cationic solutions. For that, two rock groups investigated, with the first group being rocks with high clay content (mudstones, siltstones and marls), and the second one being sandstones alone, in order to compare the different behavior presented by the two groups, concerning their mineral content. After that, it is suggested that for rocks with high clay content, the wet behavior of clay is the basic reason for the strength loss. Such statements cannot be made for sandstones; however, clay seems to have an impact in sandstone strength as well. After statistical analysis, no clear relation was found between clay content and strength loss, for both groups. After discussion, author suggested that the clay mineral itself is not sufficient enough to indicate a strong correlation, instead, the clay content should be studied in addition to the pore space, for both groups. Other mechanisms affecting the strength reduction are presented in Appendixes. These mechanisms concern the presence of quartz and calcite, as well as the pore water itself

Ancient salt deposits preserve a record of highly specific environmental, climatic and biological conditions, including past surface water chemistry and water depths, local air temperatures, atmospheric composition and halophilic microorganisms. This paper presents the first sedimentological study of the mid‐Late Permian Belfast Harbour Evaporite Formation of Northern Ireland. This formation is dominated by bedded halite, contains some siliciclastic mudstone and bedded anhydrite, and is cross‐cut by intrusive igneous rocks. The bedded halite lithology contains bottom‐growth chevron and cornet crystals, efflorescent crusts and dissolution pipes, which are evidence of a saline surface brine that underwent periods of evapoconcentration, desiccation and flooding. The mudstone lithology contains dewatering structures, intraclasts and mudcracks, which indicate flooding and desiccation in dry mudflats. Bedded anhydrite was deposited as beds of gypsum cumulate crystals in saline surface waters. The Belfast Harbour Evaporite Formation was formed by saline lakes with associated mudflats, based on sedimentary characteristics and supported by mineralogical, geochemical and stratigraphic context. Diagenetic features reflect dissolution and cementation at the surface and shallow subsurface in the depositional environment and limited late‐stage alterations. Syndepositional dissolution pipes in bedded halite were formed by flooding events. Early halite cement is present in dissolution pipes and mudstones. Gypsum/anhydrite repeatedly dehydrated and rehydrated to form an interlocking crystal mosaic. Later features include fluid migration and the intrusion of mafic rocks. The Belfast Harbour Evaporite Formation was deposited by an ephemeral saline lake and dry mudflat system in an arid climate. This study, when compared to age‐equivalent continental deposits elsewhere, suggests that arid settings with saline lakes existed across much of Pangea during the Permo‐Triassic. The Belfast Harbour Evaporite Formation stratigraphically underlies the extremely low pH saline lakes of the Mercia Mudstone Group, implying that it aids in understanding the formation of Pangean acid brine lakes.

Understanding how mud moves and deposits is essential for conceptualizing the dynamic nature of surface environments and their ancient counterparts. Experimental study has largely been pursued by civil engineers, using kaolinite as an active ingredient. Yet, applying their data to the physical comprehension of mudstone sedimentology is hampered by multiple flume configurations between labs, and data sets tailored to specific engineering needs. The need for a better grasp of underlying processes is acute, given recent flume studies that show that moving suspensions form large bedload floccules, migrating floccule ripples and bed accretion under currents capable of moving sand grains. To advance mudstone sedimentology, integrated study of suspended sediment concentration, salinity and bed shear stress on the deposition of floccules is crucial. Described here is a set of tightly controlled experiments that explored suspended sediment concentrations from 70 to 900 mg/l, freshwater, brackish and marine salinities, flow velocities in the 5 to 50 cm/s range (equivalent to 0.01 to 0.58 Pa bed shear), measured the size of in-flow and bedload floccules, and the critical velocity of sedimentation that marks the onset of sustained bedload accumulation. The critical velocity of sedimentation of kaolinite clays is in the 26 to 28 cm/s flow velocity range (0.22 to 0.25 Pa), appears insensitive to a wide range of suspended sediment concentrations and salinities, and coincides with the formation of sand-size bedload floccules. Further decrease of flow velocity/bed shear stress is accompanied by a steady increase in the size of bedload floccules. Large bedload floccules appear to form in the high-shear basal part of the flow, a phenomenon requiring further investigation. Better understanding of the mechanisms that facilitate mud deposition from moving suspensions is critical for more realistic assessments of the depositional conditions of mud and mudstones, as well as for refining predictive models for the flux of fine-grained sediments across the Earth's surface. Chevron; ConocoPhillips; ExxonMobil; Shell; Statoil; Marathon; National Science Foundation [EAR-0318769]; Whiting; Wintershall; Anadarko Published version Funding for this research was provided by the sponsors of the IU Shale Research Consortium (Anadarko, Chevron, ConocoPhillips, ExxonMobil, Shell, Statoil, Marathon, Whiting, and Wintershall). A National Science Foundation equipment grant to J. Schieber (EAR-0318769) provided funds for the purchase of the analytical SEM that was used to acquire SEM images for this article. The paper also benefited from constructive suggestions by Drs Jo~ao TrabuchoAlexandre, Aubry DeReuil, Lauren Birgenheier, Peir Pufahl, Chris Paola and an anonymous reviewer. Dr David Bish of the Indiana University Department of Chemistry kindly provided the quantitative analysis of the kaolinite clay used in these experiments, as well as his insights into the peculiarities of industrially sourced kaolinite. We also thank Dr Juan Fedele from the ExxonMobil Research Labs for computing bed shear stress values from provided velocity profiles.

Sedimentary rocks record the ancient climate of Mars through changes between subaqueous and eolian depositional environments, recognized by their stratal geometries and suites of sedimentary structures. Orbiter- and rover-image-based geologic mapping show a dynamic evolution of the 5-km-thick sedimentary sequence exposed along the flanks of Aeolis Mons (informally, Mt. Sharp) in Gale crater, Mars, by deposition of subaqueous strata followed by exhumation via eolian erosion and then deposition of overlying, onlapping strata of inferred eolian origin. This interpretation suggests that a significant unconformity should occur at the base of the onlapping strata, thus predicting lateral variations in elevation along the contact between the underlying Mt. Sharp group and overlying Stimson formation. Curiosity rover and high-resolution orbital image data quantify paleotopographic variability associated with the contact; similar to 140 m of net elevation change and a slope closely aligned with the modern topography is expressed along the regional contact. These results support the interpretation of an erosional unconformity between these strata and that it was likely formed as a result of eolian erosion within the crater, indicative of a transition from wet to dry climate and providing insight into the stratigraphic context, geologic history, and habitability within Gale crater.

Mudstone is a widely occurring type of rock in deep mining, and it is crucial to understand its failure mechanisms and strength characteristics under the interaction of water and high stress to ensure the stability of deeply buried engineered mudstone. In this study, the composition and the structure of mudstone were obtained, and triaxial tests were conducted on mudstone under five different water contents and four different confining pressures using a triaxial servo press. The variation rules for the peak strength and residual strength were obtained, and the applicability of the strength criteria was analyzed through fitting. The results showed that both the peak strength and the residual strength decreased linearly with increasing water content, with the peak strength decreasing more rapidly. Both the peak strength and the residual strength increased with increasing confining pressure, with the residual strength increasing more rapidly. The decrease in strength was primarily due to the decrease in cohesion, with the cohesion of the peak strength decreasing from 8.40 MPa to 0.94 MPa and the cohesion of the residual strength decreasing from 1.75 MPa to 0.82 MPa. The internal friction angle did not change much, with the internal friction angle of the peak strength decreasing from 41.57° to 37.29° and the internal friction angle of the post-peak strength increasing from 32.35° to 33.28°. For dry and low-water-content mudstone, the peak strength conformed to the Mohr–Coulomb criterion, while for mudstone with a higher water content, the peak strength conformed to the Hoek–Brown criterion. The residual strength conformed to the Hoek–Brown criterion. Under low and medium confining pressures, water played a dominant role in the damage pattern for the fractures produced by the initial damage to the mudstone. Under a high perimeter pressure, water played a guiding role for the fractures produced by the initial damage to the mudstone.

The elastic modulus is a key parameter in the constitutive equation of rock material, which changes with exterior conditions, including temperature. To study the evolution of the elastic modulus of the surrounding rock in some high‐temperature underground engineering works (eg, underground coal gasification, in situ pyrolysis of oil shale), a servo‐controlled rock testing machine was used in a study of the variation in elastic modulus of Jimsar mudstone (the roof stratum of Jimsar oil shale) when subjected to triaxial compression at high temperatures. The elastic modulus exhibited nonmonotonal variation when heated to 400°C while subjected to triaxial compression. This occurred in three stages. An empirical model involving piecewise linear function was used to quantitatively describe the relationship between elastic modulus and temperature. Elasticity increased between room temperature and 265°C, then weakened between 265 and 341°C, then increased at 341‐400°C, in accordance with the calculated result from the empirical model. Thermal expansion, thermal cracking, water loss, and structure reconstruction had a combined effect on the elastic modulus of the mudstone. The results will be helpful for understanding the mechanism of strata movement in some underground high‐temperature engineering operations.

The swelling and softening of mudstones caused by water often lead to serious geological disasters. In petroleum exploration and development, the hydration expansion of mudstone can also lead to serious wellbore instability hazards. The swelling of smectite clays is the main reason for this hydration expansion in mudstones. It is generally recognized that illite and illite–smectite mixed layer clays are both poor swellable and has a low effect on rock strength of smectite-poor mudstone. Furthermore, weakening law and degree of smectite-poor mudstone in water is not clear. This study conducted swelling tests and rock mechanics experiments on a smectite-poor mudstone from the Sichuan basin. The results show that both water content and swelling capacity tend to remain steady after soaking the samples for 24 h. The mudstone water content reached 5.36%, and the swelling rate was 2% after soaking in water for 72 h, and the rock had a lower unconfined compressive strength (UCS) value of 1.41 MPa. Adding KCl inhibited these processes, and elevated KCl concentrations drastically reduced the mudstone water content and swelling rate. Compared to water, the water content and swelling rate of mudstone soaked in a 6% KCl solution both decreased by 50%. The UCS and the elastic modulus also increased for a half-dry mudstone, although the inhibitor was important. At elevated KCl inhibitor concentrations, the UCS and elastic modulus of the hydrated mudstone were lower than those of the dry mudstone. The findings of this study can help for better understanding of the application of KCl inhibitor in water-based fluid for drilling engineering.

In this contribution we report measurements and interpretations of aeolian abrasion features observed along the Mars Science Laboratory rover traverse at Gale Crater on Mars. Aeolian abrasion of surface rocks has been documented by most missions that have landed on Mars, but attention has largely focused on relatively resistant rocks that display ventifact morphologies well‐known from Earth. The current study instead emphasizes abrasion features developed on mudstone surfaces, because aeolian abrasion textures are very common in the mudstone‐dominated Murray Formation at Gale Crater. These abrasion textures have been observed over a wide area, and they allow deductions about dominant past wind regimes that differ from those observed at present. On Earth, aeolian abrasion features in mudstone outcrops have minimal preservation potential because of the susceptibility of mudstones to moisture and aqueous erosion, even in dominantly arid surface environments. Because of this there is no literature on potential terrestrial analogs. In order to better understand aeolian abrasion morphologies in mudstones on Mars, laboratory experiments were conducted that exposed a range of mudstone samples and rock simulant samples to wind‐driven sand for periods of up to four months. These experiments produced a range of aeolian abrasion textures (‘wind tails’, fluting, differential ‘etching’ of laminae, stalks and pedestals) that can serve as analogs for features in the Murray Formation, increasing our confidence regarding aeolian origins for these and the deductions of formative, sand‐driving wind azimuths. Orientations of aeolian abrasion textures along the Mars Science Laboratory traverse were compared with active ripple orientations in rover images, and with previous analyses of orbital images of the study area, in order to evaluate whether the current, complex wind environment can explain the abrasion orientations observed in rover images, or if the abrasion record might also contain signatures of past wind regimes that differed from those of the present. Results show relatively coherent patterns of airflow and sand movement that vary in accordance with factors like local topography and upwind availability of sand for abrasion. Wind events blowing southwest that are primarily responsible for southwest migration of the Bagnold Dunes have also caused bedrock abrasion of similar orientation between these dunes. Less effective wind events (from an abrasion standpoint) blowing south‐southeast have broadly affected bedrock exposures elsewhere across the Mars Science Laboratory landing site away from the Bagnold Dunes. A notable exception are northeast abrasion textures on the more erosion‐resistant sandstones of the Naukluft Plateau. The latter are consistent with one of two abrasion directions measured in previous studies, prior to the rover's arrival at the Murray Formation mudstones, and probably reflect the preservation of an ancient sand‐driving wind regime that differs from that of the present.

International audience; The Hides anticline in the Papua New Guinea fold belt is the core part of the Papua New Guinea liquified natural gas project that commenced production in 2014, yet little is known about its internal structure, particularly at depth. The structure of the upper 3 km (9843 ft) is relatively well constrained from surface data, recent development wells, and poor-quality two-dimensional seismic data, but the deep structure has been obscure. Seismic data and gravity modeling suggest an underlying large normal fault in basement. Forward geometrical modeling using MoveTM and four-dimensional analog sandbox modeling under an x-ray tomography scanner have greatly constrained the structural interpretation. The modeling confirms the presence of the underlying basement normal fault and suggests that it was mildly inverted prior to the onset of pure compression deformation in the sedimentary section. The main detachment level was just above basement approximately 8–10 km (∼5–6 mi) beneath the surface, but this ramped up at the basement fault creating an array of triangle-zone faults through the overlying sedimentary section, building the Hides anticline. The early inversion was instrumental in initiating a back thrust and hinterland-verging tight fold in the Mesozoic section, including the source, reservoir, and seal. Deformation in the thick Miocene carbonates at the surface was detached from that in the underlying reservoir along an Upper Cretaceous mudstone horizon that varies strongly in thickness such that the 2–4-km (6562–13,123-ft)-high Mesozoic structure verges northeast and the overlying Miocene structure verges southwest. Analog modeling shows that a ductile stratigraphy is required with slow strain rates of approximately 1–3 km/m.y. (∼3281–9843 ft/m.y.).

Understanding mudstone depositional processes, including both traction transport and dynamic mechanisms, requires a re‐assessment of how these processes relate to the accumulation and preservation of organic carbon in fine‐grained successions. This relationship was addressed using facies described in detail from a Cenomanian–Turonian aged, organic‐rich, marine mudstone‐dominated succession from the Albertan Western Interior Seaway. All facies exhibit a high degree of heterogeneity at the millimetre‐to‐decimetre scale, contain evidence of bioturbation and display similar ranges of sedimentary structures including wave ripples and current ripples, sharp‐based graded beds and starved ripples. Described facies vary in grain size as well as relative abundances of biogenic versus siliciclastic grains. Siliciclastic grains are dominantly composed of quartz silt as well as silt‐sized to sand‐sized clay mineral–rich aggregates while the biogenic grains are dominantly composed of silt‐sized to sand‐sized calcareous pellets, bivalve fragments and foraminifera. Although the succession is relatively clay mineral‐rich, the majority of clay minerals occur as mud aggregates that were transported by traction processes. The sedimentary structures present are diagnostic of sea floor reworking by waves and currents, indicating that the basin was relatively shallow (i.e. not hundreds of metres deep) with frequent reworking of the sea floor sediment with suspension settling deposits being rare. The abundance of bioturbation and in situ bivalves indicates that there was sufficient oxygen at the sea floor and that widespread bottom water anoxia was not persistent at the time of deposition of the organic‐rich interval of interest. The accumulation of organic‐rich sediment appears to be a preservational phenomenon caused by sediment being buried more rapidly than the organic carbon can oxidize in the surficial layers due to episodic inputs of siliciclastic material during large storm events.

Clogging constitutes a significant obstacle to shield tunneling in mudstone soils. Previous research has focused on investigating the influence of soils and slurry properties on clogging, although little attention has been paid to the impact of tunneling parameters on clogging, and particularly early clogging warning during tunneling. This paper contributes to developing a real-time clogging early-warning approach, based on a self-updating machine learning method. The clogging judgment criteria are based on the statistical characteristics of whole-ring tunneling parameters. The paper proposes the use of random forest (RF) for a real-time self-updating early warning strategy for clogging. The performance of this approach is illustrated through its application to a slurry-pressure-balanced shield tunneling construction of Nanning metro line 1. Results show that the RF-based approach can predict clogging during a ring construction with only four minutes of tunneling data, with an accuracy of 95%. The RF model provided the best performance compared with the other machine learning methods. Furthermore, the RF model can realize an accurate clogging prediction in one ring, using less tunneling data with the self-updating mechanism.

Fractures can provide valuable information on the tectonic evolution of the Earth’s crust. Our field observation data, rock core data, and thin section observations reveal several horizontal fractures in the Cenozoic mudstone strata in the western Qaidam Basin, Qinghai Province, China. These horizontal fractures have rough surfaces and are filled by gypsum. The fractures are mainly curved; however, some straight fractures are also found. There are many intersections between adjacent curved fractures, which often adjoin to form “T” shape fractures. Fracture apertures are mainly between 1 mm and 1 cm, with a maximum of 3 cm. Both the size and density of fractures decrease as strata denudation thickness decreases and depth of burial increases. Horizontal fractures are only found in a core area of anticlines with severe strata denudation. Accordingly, these fractures are related to vertical extension due to residual stress in the process of rapid uplift and denudation. The horizontal fractures cut earlier vertical tectonic fractures, indicating their formation after tectonic extrusion. Electron spin resonance (ESR) dating of fracture-filling materials revealed that horizontal fractures appeared in two stages. The first stage was approximately 1.8 Ma ago, while the second stage was approximately 0.3 Ma ago. The size and density of the later-stage horizontal fractures are markedly greater than the earlier-stage fractures. Based on the driving stress when fractures are formed, which is obtained from fracture parameters, the denudation rate in the later stage was approximately 2∼3-fold greater than that in the earlier stage. According to the evidence, during the Quaternary, the western Qaidam Basin experienced pulsating tectonic extrusion, producing uplift and denudation and an increase in tectonic activity. Such findings suggest a gradual increase in episodic tectonic activity in the entire Tibetan Plateau region during the Quaternary.

The mechanical response characteristics of mudstone from the ingate roadway of the west ventilation shaft in Yuandian No. 2 coal mine, Huaibei City, Anhui Province, China to dynamic loads were quantified in single- and cyclic-impact compression tests, using the split-Hopkinson pressure bar test device. The dynamic stress–strain relationships and the failure characteristics of mudstone samples under different impact loads were analyzed systematically. Considering the “rate effect” of the mudstone dynamic strength, the dynamic strength criterion of mudstone was proposed, and the dynamic damage constitutive model of mudstone was established, based on the statistical damage theory. In response to single-impact loads, with increasing impact pressure, the mudstone peak stress and strain gradually increased, and the peak stress and average strain rate increased nonlinearly. In response to cyclic-impact loads, with an increasing number of impacts, the mudstone peak stress first increased and then decreased, and the peak strain increased gradually. With increasing impact pressure, the number of impacts to the samples’ failure decreased gradually. By parameter identification and comparative analysis of the test results, the proposed dynamic damage constitutive model of mudstone was validated. The model can be used for stability analysis of roadway-surrounding rock under dynamic loads.

In order to investigate the difference of pore structure characteristics between mudstone and coal under different particle size conditions, samples acquired from Henan province were smashed and screened into three different particle sizes (20–40, 80–100, and >200 mesh) to conduct the experiments, using the high-pressure mercury intrusion porosimetry (MIP) and low-temperature N2 adsorption (LT-N2A) techniques. The results demonstrated that the proportion of open pores or semi-enclosed pores increased, and the pores became preferable contacted each other for both mudstone and coal during the crushing process. These variations of pore structure characteristics in the coal were beneficial to methane storage and migration. The total specific surface areas and pore volumes all showed a tendency of increasing continually for both mudstone and coal, as the particle sizes decreased from the LT-N2A test. The mudstone and coal were non-rigid aggregates with micropores, plate-shaped pores, and slit-shaped pores developed inside. The effect of the crushing process on the pore shape for the mudstone and coal was inappreciable. Moreover, the influence of the particle sizes on the mesopore was the most significant, followed by the macropore; and on the micropore, the influence was negligible for both mudstone and coal. The crushing process only had a significant impact on the pore structure of mudstone with a particle size of less than 100 mesh, while it could still alter the pore structure of coal with a particle size of larger than 100 mesh. It is believed that this work has a significant meaning to explore the diffusion and migration rules of coal-bed methane in coal.

The variation in mineral composition will affect the rock brittleness, thus the change of mineral assemblages during diagenesis has a potential control on the brittleness of mudstones. In this study, thin section, X-ray diffraction (XRD), and Scanning Electron Microscope (SEM) analyses were used to investigate compositional and microscopic features of mudstones. With the enhancement of diagenesis, three mineral assemblages were divided due to the diagenetic evolution of minerals. Quartz, feldspar, dolomite, chlorite, and illite were regarded as brittle minerals and (quartz + feldspar + dolomite + illite + chlorite)/(detrital mineral + carbonate + clay mineral) was defined as the brittleness evaluation index The mudstone brittleness changed slightly during early diagenesis but increased gradually with enhancement of diagenesis in the late diagenesis stage. Quartz and feldspar were scattered above the clay matrix and the contact of grains was limited, therefore, the contribution of detrital minerals to the brittleness was affected by the properties of clay minerals. The diagenetic transformation of clay minerals resulted in the reduction of ductile components (smectite/I-Sm and kaolinite) and increase of brittle components (illite and chlorite), leading to the enhancement of integral rigidity of the mudstones. Meanwhile, the improved crystallization of carbonate in late diagenesis stage enlarged the carbonate grains which resulted in rigid contact between grains. These results highlighted the influence of diagenesis on mudstone brittleness. Therefore, for evaluation of mudstone brittleness, attention should be paid to the diagenesis process besides mineral composition.

The Yinggehai Basin is an important Cenozoic gas bearing basin in the South China Sea. With the gradual improvement of gas exploration and over-development in shallow layers, deep overpressured layers have become the main target for natural gas exploration. There are no large-scale faults in the strata above the Meishan Formation in the central depression, and hydraulic fracturing caused by overpressure in mudstone cap rocks is the key factor for the vertical differential distribution of gas. In this paper, based on the leak-off data, pore fluid pressure, and rock mechanics parameters, the Fault Analysis Seal Technology (FAST) method is used to analyze the hydraulic fracture risk of the main mudstones in the central depression. The results show that the blocks in the diapir zone have been subjected to hydraulic fracturing in the Huangliu cap rocks during the whole geological history, and the blocks in the slope zone which is a little distant from the diapirs has a lower overall risk of hydraulic fracture than the diapir zone. In geological history, the cap rocks in slope zone remained closed for a longer time than in diapir zone and being characterized by the hydraulic fracture risk decreases with the distance from the diapirs. These evaluation results are consistent with enrichment of natural gas, which accumulated in both the Yinggehai Formation and Huangliu Formation of the diapir zone, but it only accumulated in the the Huangliu Formations of the slope zone. The most reasonable explanation for the difference of the gas reservoir distribution is that the diapirs promote the development of hydraulic fractures: (1) diapirism transfers deep overpressure to shallow layers; (2) the small fault and fractures induced by diapir activities weakened the cap rock and reduced the critical condition for the natural hydraulic fractures. These effects make the diapir zone more prone to hydraulic fracturing, which are the fundamental reasons for the difference in gas enrichment between the diapir zone and the slope zone.

The reduction in the conventional resources and insistent request for hydrocarbons and energy lead us to look forward for the increasing interest in unconventional resources by exploring new technologies for the national economy and local utilization in Malaysia. Upper Mesozoic-Cenozoic is considered the age of Central Sarawak Formations. This paper attempts to evaluate the clay mineralogy, depositional environment, gamma ray evaluation and the relationship between total organic carbon and uranium concentration of the Nyalau, Tatau, Begrih, Liang and Belaga Formation which eventually comprise black shales and mudstones using spectral gamma ray (SGR), field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), XRD clay separation and total organic content (TOC%). The results from SGR indicate that the formations composed mainly of kaolinite, smectite and chlorite. These results are confirmed by XRD, XRD clay separation and FESEM with the presence of illite as a dominant clay mineral component. Based on Th/U ratios which vary between 0.42 and 3.95, the formations are expected to be deposited in the reduced marine environment. Results from calculated API (90.76–233.32 API) reveal the ability of the clay minerals to absorb uranium and thorium through cation exchange capacity. The relationship between TOC% and U cross plots also show a significant positive correlation. The presence of high U concentrations in the formations is possible because of their relatively higher clay contents and the existence of organic matter.

Nowadays, the Iran country with considering huge reserves of building stone, is one of the important countries in world. But, unfortunately when building stones are processed in factories, significant part of material changed to waste. In final of processing, simultaneous national treasures are spoiled and environment is damaged too. Therefore, propose new methodologies and reuse of waste materials due to building stone is necessary. In this research, main idea is study of mudstone due to travertine and granite on geotechnical properties of dune sand. In present research, some factors such as optimum water content, dry density, bearing capacity, internal friction angle and cohesive by using laboratory tests including compaction, California Bearing Ratio (CBR) and direct shear tests were evaluated.

The location of mudstone rock formations as a repository of radioactive materials has attracted great attention from the international rock mechanics community. In this paper, the strain and thermal expansion coefficient of mudstone during the heating and constant temperature stages are studied through experiments. The results can provide a scientific basis for the design and safety protection of related projects.

The deposition of the Lower Cambrian argillaceous rocks on the Kongquehe slope provides a good opportunity to reconstruct the paleoenvironmental conditions of the Tarim Basin. To explore the paleoredox conditions, paleoclimate, and provenance of this deposit, 21 samples were collected from Well A, and the concentrations of major and trace elements were analyzed. The V/(V + Ni), V/Cr, Ni/Co, U/Th, Uau, and V/Sc ratios indicated that the sediments in the water body from the Lower Cambrian were in a reducing environment, and the degree of reduction weakened from the bottom to the top. The Sr/Cu, Mg/Ca, and Fe/Mn ratios in the sediments revealed that the Lower Cambrian was mainly characterized by a warm and humid paleoclimate, and there may be a paleoclimatic transition toward drought conditions as recorded by the sediments of Xidashan Formation. The chemical alteration index, compositional variation index, plagioclase alteration index values, and Th/U and K/Rb ratios of the Lower Cambrian mudstone all reflected that the parent rock in the study area was mainly subject to low- to medium-degree chemical weathering. Longitudinally, the Lower Cambrian gradually increased and then weakened from Xishanbulake Formation to Xidashan Formation. The ratios of trace elements and rare earth elements as well as Th–Sc–Zr/10, Th–Co–Zr/10, and ∑REE–La/Yb diagrams all showed that the mudstones of Xishanbulake and Xidashan Formations of the Lower Cambrian in the study area have a common parent rock type, mainly sedimentary rocks rich in felsic minerals. Additionally, the structural setting discrimination diagrams of SiO2–K2O/Na2O, Th–Sc–Zr/10, Th–Co–Zr/10, and La–Th–Sc showed that the structural setting of the Lower Cambrian mudstone deposition is mainly a continental island arc environment and has the characteristics of an active continental margin.

The Opalinus Clay is notable in Switzerland as being the selected host rock for deep geological disposal of radioactive waste. Since the early 1990’s, this argillaceous mudstone formation of Jurassic age has been intensively studied within the framework of national and international projects to characterize its geological, hydrological, mechanical, thermal, chemical, and biological properties. While there is no formal stratigraphic subdivision, the Opalinus Clay lithology is classically divided into several, dam- to m-scale sub-units (or facies), depending on location. Recent multi-proxy studies (combining petrographic, petrophysical, geochemical, and mineralogical analyses) have however demonstrated that high, intra-facies, lithological heterogeneity occurs at the dm- to cm-scale. To constrain this small-scale heterogeneity into distinct lithological units (subfacies), the present study aims at defining and presenting a convenient subfacies classification scheme covering the overall Opalinus Clay lithology across northern Switzerland. Petrographic (macro- and microfacies), mineralogical (X-ray diffraction) and textural (image analysis, machine learning and 3D X-ray computed tomography) analyses are performed on diverse drill cores from the Mont Terri rock laboratory (northwestern Switzerland), and results are extended further to the east (Riniken, Weiach, and Benken). Most of the investigated Opalinus Clay can be described by the use of five distinctive subfacies types (SF1 to SF5), which are visually and quantitatively distinguishable by texture (grain size, bedding, fabric, and color) and composition (nature and mineralogy of components). The five subfacies types can be further refined by additional attributes and sedimentary characteristics (biogenic, diagenetic, and structural). Eventually, the widespread and consistent use of standardized Opalinus Clay subfacies types provides the means to harmonize petrographic descriptions within multidisciplinary research projects, enhance reproducibility of in situ experiments, and further evidence the tight relations between lithology and various rock properties., Frontiers in Earth Science, 9, ISSN:2296-6463

The deformation and failure of rock materials are closely related to the strain energy characteristics during the loading process. These strain energy characteristics and rock properties are greatly affected when the rock is subjected to the acidic solution. To study the effects of chemical solutions with different pH on the mechanical properties and strain energy mechanism of mudstone, the chemical corrosion mudstone samples are subjected to a uniaxial loading testing machine (CN64 electro-hydraulic servo). The corrosive effects of the acidic solution on the porosity, strain energy characteristics, and failure mode of mudstone samples were thoroughly investigated. The findings of this research indicate that: (1) The rate of change in the porosity and chemical damage coefficient of rock samples after chemical corrosion decreases, which is closely linear with the increase of solution pH, (2) The total strain energy, elastic strain energy, and dissipative strain energy decrease with the increase of pH, and, as a result, it is proposed that the observed turning point of the proportion curve of dissipated strain energy from decline to rise is used as a precursor point of the rock failure, (3) The stress value of the failure precursor point increases and the strain value decreases with the increase in pH value. However, the ratio of the stress value of the failure precursor point to the peak stress hardly changes with pH value, and its value is about 0.883, and (4) Rock samples soaked in a weak acidic chemical solution (pH 7.3 and 5.3) are damaged by tensile crack, while rock samples soaked in a strong acidic chemical solution (pH 3.3 and 1.3) are mainly damaged by the combination of tensile and shear. The findings of this study can be used to provide an experimental and theoretical foundation for monitoring rock engineering disasters such as slope, tunnel, and coal mine failures.

Equivalent to the Lower Siwalik Group, the Late Miocene Chinji Formation in Pakistan consists of interbedded in-channel sandstone (SSt) and overbank mudstone (MSt) sequences. Twelve sandstone and sixteen mudstone samples from three different sections of the formation in southwestern Kohat, NW Pakistan were analyzed for major elements and selected trace elements. The Chinji sandstones are feldspathic and lithic arenites. They are mostly matrix-supported, moderately to well sorted, and contain angular to rounded framework grains. Authigenic carbonate makes up most of the matrix. The framework grains consist of abundant monocrystalline quartz, alkali feldspar, and lithic fragments with subordinate mica and trace to accessory amounts of heavy minerals including epidote, monazite, apatite, garnet, rutile, and brown hornblende. The lithic fragments consist of sedimentary, volcanic, and low-grade metamorphic rocks.The average concentration of Zr, Nb and Y, and the Ba/Sc and Ba/Co ratios in the studied samples are lower than the corresponding values for the upper continental crust (UCC) and Post-Archean Australian Shale (PAAS) indicating the presence of mafic phases in the source area(s). The high average Cr/Zr and Cr/V ratios of the investigated samples relative to UCC and PASS also support the presence of mafic lihtologies, possibly chromite and ultramafic rocks in the source region. The La/Sc and Th/Sc ratios of the Chingi samples are more like the UCC while the Th/Co and Cr/Th ratios suggest a major contribution from mafic rocks. The average percent differences of the Chinji samples from both the UCC and PAAS in terms of critical silicic to basic trace element ratios (Ba/Co, Ba/Sc, La/Co, La/Sc, Th/Co, Th/Sc, Zr/Cr, and Zr/Sc) suggest a mafic contribution of 23 to 47% (mudstone) and 56 to 69% (sandstone). The lower Th/U, Rb/Sr and Zr/Sc ratios in the studied samples than the corresponding values of the UCC and PAAS suggest negligible recycling for the sediments of the Chinji Formation. Petrographic point count data on the Chinji sandstone indicate sediment derivation from a dissected arc, suture belt, and recycled orogen corresponding to the Kohistan-Ladakh Arc, the Indus Suture Zone, and the Himalayan Tectonic units, respectively. The different source rocks identified on the basis of various petrographic and geochemical parameters occur as part of the mentioned tectonic domains.

The Eocene Huitrera Formation of northwestern Patagonia, Argentina, is renowned for its diverse, informative, and outstandingly preserved fossil biotas. In northwest Chubut Province, at the Laguna del Hunco locality, this unit includes one of the most diverse fossil floras known from the Eocene, as well as significant fossil insects and vertebrates. It also includes rich fossil vertebrate faunas at the Laguna Fría and La Barda localities. Previous studies of these important occurrences have provided relatively little sedimentological detail, and radioisotopic age constraints are relatively sparse and in some cases obsolete. Here, we describe five fossiliferous lithofacies deposited in four terrestrial depositional environments: lacustrine basin floor, subaerial pyroclastic plain, vegetated, waterlogged pyroclastic lake margin, and extracaldera incised valley. We also report several new 40Ar/39Ar age determinations. Among these, the uppermost unit of the caldera-forming Ignimbrita Barda Colorada yielded a 40Ar/39Ar age of 52.54 ± 0.17 Ma, ∼6 m.y. younger than previous estimates, which demonstrates that deposition of overlying fossiliferous lacustrine strata (previously constrained to older than 52.22 ± 0.22 Ma) must have begun almost immediately on the subsiding ignimbrite surface. A minimum age for Laguna del Hunco fossils is established by an overlying ignimbrite with an age of 49.19 ± 0.24 Ma, confirming that deposition took place during the early Eocene climatic optimum. The Laguna Fría mammalian fauna is younger, constrained between a valley-filling ignimbrite and a capping basalt with 40Ar/39Ar ages of 49.26 ± 0.30 Ma and 43.50 ± 1.14 Ma, respectively. The latter age is ∼4 m.y. younger than previously reported. These new ages more precisely define the age range of the Laguna Fría and La Barda faunas, allowing greatly improved understanding of their positions with respect to South American mammal evolution, climate change, and geographic isolation., Centro de Investigaciones Geológicas

The Opalinus Clay is an argillaceous to silty mudstone formation, notable in Switzerland as the selected host rock for deep geological disposal of radioactive waste. Its upper bounding unit (Passwang Formation and eastern equivalents) is composed of successions of mudstone, sandy bioclastic marl and limestone separated by ooidal ironstone beds. The lithostratigraphic transition is diachronous across northern Switzerland and shows high vertical and lateral lithological variability. To constrain this variability into predictive models, and to identify horizons with properties that could potentially influence radionuclide mobility, the sedimentological and diagenetic processes involved in the genesis of this transition have to be investigated. The present study aims at testing the applicability of X-ray fluorescence chemostratigraphy to characterise the mixed carbonate-siliciclastic units and understand the complex genesis of the lithostratigraphic transition from the Opalinus Clay towards its upper bounding unit. Sediment drill cores from four locations across northern Switzerland (Mont Terri, Riniken, Weiach and Benken) are analysed using high-resolution X-ray fluorescence core scanning. Data are compared to petrographic and additional geochemical data sets (inductively coupled plasma mass spectrometry, scanning electron microscopy with energy dispersive X-ray analysis, micro-X-ray fluorescence mapping) obtained from powdered samples, thin section analyses and drill core slabs. The results demonstrate that the combination of these rapid and non-destructive measurements along with multivariate data analysis allows the fast and objective classification of lithofacies along complex sedimentary successions. Moreover, it provides quantitative means for differentiating between prominent depositional and post-depositional processes. The lithostratigraphic transition has been traced by the use of specific elemental proxies as a discontinuity, and its genesis linked to sediment bypassing., The Depositional Record, 7 (1), ISSN:2055-4877

International audience; Fine-grained sedimentary successions contain the most detailed record of past environmental conditions. High-resolution analyses of these successions yield important insights into sedimentary composition and depositional processes and are, therefore, required to contextualise and interpret geochemical data which are commonly used as palaeoclimate proxies. The Kimmeridge Clay Formation (KCF) is a 500 m-thick mudstone succession deposited throughout the North Sea in the Late Jurassic and records environmental conditions through this time. Here, we present petrographic analyses (on 36 thin sections) on a 50 m section of a KCF core from the Cleveland Basin (Yorkshire, UK) to investigate controls on sedimentation in this region during the Tithonian, Late Jurassic. Facies descriptions demonstrate that deposition took place in a hydrodynamically variable environment in which the sediment origins, sediment dispersal mechanisms, and redox conditions fluctuated on the scale of thousands of years. Petrographic analyses show that the sediment comprises marine (algal macerals, calcareous fossils), detrital (quartz, clay, feldspar), and diagenetic (dolomite and authigenic kaolinite) components and that several sediment dispersal mechanisms influenced deposition and facilitated both the supply and preservation of terrestrial and marine organic material. This work provides a framework for the interpretation of geochemical palaeoclimate proxies and reinforces the importance of looking at the rock when interpreting whole-rock geochemical data.

International audience; This study aims to better understand the evolution of the organic matter (OM) ultrafine structure (designating the nanoscopic structure of the OM/macerals) and porosity with increasing thermal maturity of mudstones source-rocks. To this end, the particulate fractions of kerogen from organic-rich Kimmeridge clay mudstones were isolated by acidic treatment before and after laboratory thermal maturation. The evolution of the composition, the chemical structure and the porosity of kerogen from the immature stage (Ro = 0.42%) to the dry gas zone (Ro = 2.12%) were documented using a combination of elemental analysis, vitrinite reflectance measurements, Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), Raman spectroscopy and Small Angle X-Ray Scattering (SAXS). The evolution of the porosity of OM was then compared to the evolution of the pore volume of the total rock measured by nitrogen adsorption. The results show that the progressive densification, reorganization and aromatization of the amorphous kerogen particles into a more ordered, but heterogeneous carbon-rich residue is responsible for significant variations in the kerogen porosity with increasing maturity. Contrary to the previous observations on these Kimmeridge clay mudstones, the variations that occur during the peak of oil generation (Ro of ca. 0.90%) mark the onset of the OM-hosted pores development. There appears to be a natural close relationship between the evolution of OM porosity and total pore volume of organic-rich mudstones during gas generation. Indeed, a similar alternation of pore collapse and pore development is observed in response to gas generation. The development and the evolution of pores in these organic-rich mudstones seems thus mainly driven by the evolution of the chemical structure and the composition of OM during thermal maturation. In the dry gas zone, the porosity and the specific surface area of the kerogen are significant (19% and 57.1 m2.g−2 respectively). This highlights the importance of the OM content, type and composition in the porosity and gas storage capacities of mudstone reservoirs, increasingly discussed in the available literature in recent years.

Deep-water contourite muds are an important component of many continental margin systems and are currently the focus of much interest amongst deep-water researchers. One outstanding gap in our knowledge of these systems is to understand and quantify a contourite budget, both at the small (facies) scale and at the larger drift scale. A second problem concerns the establishing of robust criteria for discriminating between contourites and associated deepwater facies&mdash, turbidites and hemipelagites. This paper contributes to these topics by detailed examination of sediment composition, with a particular focus on potentially diagnostic components, within contourites and hemipelagites from the same depositional basin. Samples were selected from Pliocene to Quaternary muddy contourites from the Gulf of Cadiz (IODP 339) and examined by scanning electron microscopy. The presence of tunicate spicules, micro-bored shell fragments, and a particular species of coccolithophore, Braarudosphaera biglowii, all indicate derivation from shallow waters and hence lateral off-shelf supply. In contrast, micro-mudclasts and fragmented bioclasts are indicative of alongslope transport in bottom currents. A normal planktic component of the contourite muds shows a significant vertical input from pelagic settling. Such diagnostic components can also help in the discrimination between contourites, turbidites and hemipelagites.

This study focuses on Early Cretaceous mudstones from the Shahai and Fuxin formations in the Fuxin continental basin. We analyse chemical weathering, land surface temperatures and palaeoclimates based on chemical weathering indices, and emphasize the implications of continental chemical weathering on nutrient fluxes into lakes and oceans. According to Cr and Ni abundance, Al2O3-TiO2, La/Sc-Th/Co and V-Ni-Th×10 plots, as well as rare earth element (REE) analysis, mudstone samples from the Shahai and Fuxin formations were derived from the same type of provenance comprising mainly felsic igneous rocks. Chemical weathering trends reflected by the Chemical Index of Alteration (CIA), Weathering Index of Parker (WIP) and the Mafic Index of Alteration for Oxidative weathering environments (MIA(O)) are consistent with each other and allow the geological succession to be divided into four stages. Land surface temperatures of the Shahai and Fuxin formations are estimated based on the linear relationship of CIA to temperature, and also can be divided into four stages consistent with those determined from chemical weathering trends. During Stage A (early part of the late Aptian) chemical weathering and land surface temperatures were relatively low and showed characteristic high fluctuations, while Stage B (latest Aptian) represented a transitional period where weathering rates and temperatures increased, and high amplitude fluctuations continued. Conditions changed markedly in Stage C (early Albian) with very high and stable weathering, and warm, humid climates, while in Stage D (middle and late Albian) conditions returned to low chemical weathering and land surface temperatures. These stages of chemical weathering and land surface temperature fluctuations represent responses to global climate fluctuations during the Early Cretaceous, with the early Albian high weathering intensities and warm, humid climates combining to create high nutrient levels that would have flushed through rivers into lakes and ultimately oceans. This correlates stratigraphically with the development of Early Cretaceous black shales during Ocean Anoxic Event 1b, showing the importance of continental weathering regimes as a causal mechanism for lake and ocean anoxia.

This report presents the results of scanning electron microscopy (SEM) analyses on 2 core samples from the GSWA Waukarlycarly 1 stratigraphic well drilled in the Canning Basin. The well was drilled as part of a co-funded collaboration between Geoscience Australia (GA) and the Geological Survey of Western Australia (GSWA) aimed at gathering new subsurface data on the potential mineral, energy and groundwater resources in the southern Canning Basin. The collaboration resulted in the acquisition of the Kidson Deep Crustal Seismic Reflection Survey in 2018; and the drilling of deep stratigraphic well GSWA Waukarlycarly 1, located along the Kidson Sub-basin seismic line within the Waukarlycarly Embayment in 2019 (Figure 1). GSWA Waukarlycarly 1 reached a total depth of 2680.53 m at the end of November 2019 and was continuously cored through the entire Canning Basin stratigraphy. Coring was complemented by the acquisition of a standard suite of wireline logs and a vertical seismic profile. The work presented in this report constitutes part of the post well data acquisition. The purpose of the SEM analysis was to determine mineralogy and textural relationships between grains, verify the presence of organic material at the micro-scale, document i) the presence of diagenetic alterations to the detrital mineral assemblage and ii) eventual distribution of visible pores.

Целью работы является оценка потенциала нефте-битумопродуктивности анализируемых отложений. Были проведены исследования 13 образцов керна из различных интервалов 4 скважин. В данной работе представлены результаты анализа состава и свойств углеводородов, выделенных из керна карбонатных и прилегающих к ним отложений с интервала 1631,2-1774,8 м. Анализ выполнен на основе результатов термогравиметрических, хроматографических и оптических исследований. Произведена обработка результатов с применением расчёта линейной и ранговой корреляции. Отмечается значимая взаимосвязь между значениями параметров, полученных в результате хроматографических исследований и лабораторных исследований по определению состава нефти и процессов, протекающих в них при нагревании по заданной программе, а также между результатами хроматографических и оптических исследований. Анализ показал значимый вклад легких фракций изоалканов и лёгких фракций нормальных алканов при термических преобразованиях, то есть в процессе хранения, доставки в лабораторию и при пробоподготовке не произошло существенной потери лёгких компонентов углеводородов кернового материала. Не обнаружена корреляционная связь между оптическими и термическими методами, так как эти методы направлены на выявление различных запасов органического материала, которые также требуют применения различных методов воздействия при их разработке. Детальный анализ образцов с выявлением заметной потерей массы при термовоздействии и низкими величинами коэффициента светопоглощения позволяет выявить образцы горной породы с не преобразованным в битумоиды органическим веществом. Полученные результаты позволяют оценить применимость как методов исследований, так и систем разработки с теми или иными технологиями воздействия на призабойную зону и межскважинный объём пласта., The aim of the work is to assess the potential of oil and bitumen productivity of the analyzed deposits. Research was conducted on 13 core samples from various intervals of 4 wells. This paper presents the results of an analysis of the composition and properties of hydrocarbons extracted from the core of carbonate and adjoining deposits from an interval of 1631.2-1774.8 m. The analysis is based on the results of thermogravimetric, chromatographic and optical studies. The results were processed using the calculation of linear and rank correlation. A significant relationship is noted between the values of the parameters obtained as a result of chromatographic studies and laboratory studies to determine the composition of oil and the processes that occur in them when heated according to a given program, as well as between the results of chromatographic and optical studies. The analysis showed a significant contribution of light fractions of isoalkanes and light fractions of normal alkanes during thermal transformations, i.e. during storage, delivery to the laboratory and sample preparation, there was no significant loss of light components of the core material hydrocarbons. No correlation was found between optical and thermal methods, since these methods are aimed at identifying various stocks of organic material, which also require the application of various methods of exposure in their development. A detailed analysis of the samples revealing a noticeable mass loss during thermal exposure and low values of the light absorption coefficient makes it possible to identify rock samples with organic matter that is not converted to bitumoids. The results obtained make it possible to assess the applicability of both research methods and development systems with various technologies for influencing the bottom-hole zone and inter-well volume of the formation., Нефтяная провинция, Выпуск 2 (22) 2020

The quality of hydrocarbon source rocks is affected by the sedimentary paleoenvironment. A paleoenvironment with anoxia and a high paleoproductivity is beneficial to source rocks. The paleoenvironment of the Lower Ordovician Meitan Formation of the Sichuan Basin and its adjacent areas is lacking, restricting the oil and gas exploration of the Ordovician in the Sichuan Basin and its adjacent areas. In this paper, the content of major and trace elements of 50 samples was tested to clarify the paleoenvironment of the Meitan Formation. The paleoclimate, paleosalinity, paleoredox, and paleoproductivity during the deposition of the Meitan Formation were analyzed. The control effect of the paleoenvironment on the development of source rocks was clarified, and the favorable paleoenvironment for source rock development was pointed out. The results show that the paleoenvironment of the Meitan Formation has the following characteristics: humidity, brackish water, oxygen depletion, anoxia environment, and high paleoproductivity. These characteristics are conducive to the development of poor and moderate source rocks. The source rocks of the Meitan Formation were developed in the north, west, and south of the Sichuan Basin and its adjacent areas. The organic matter of the source rocks is mainly typed II1 kerogen, and the quality is evaluated as poor-medium source rocks having the potential of generating oil and gas. This study can provide fundamental parameters for the further exploration of Ordovician petroleum.

The Upper Ordovician–Lower Silurian mudstones (including the Wufeng, Guanyinqiao and Longmaxi Formations) in the Sichuan Basin are some of the most important shale gas plays in China. In order to enhance our understanding of the process of formation of organic carbon up to 10%, optical, microscopy and geochemical methods have been used to investigate the petrographic and geochemical characteristics of the formation. Firstly, three mudstone lithofacies were identified based on a wide variety of mudstone laminations. These are: (a) indistinctly laminated mudstone; (b) parallel-laminated mudstone; and (c) nonparallel-laminated mudstone. Then, combining with the evidence from depocenter migration, Th/U ratios and total organic carbon, the abundant organo-minerallic fabrics suggest that organic carbon was preferentially deposited and preserved in anoxic, low energy and stagnant water conditions during deposition of the Wufeng and Longmaxi Formations. On the contrary, the Guanyinqiao Formation with poor organic carbon was deposited in oxic and high-energy water conditions.

Pore characterization in shales is challenging owing to the wide range of pore sizes and types present. Haynesville-Bossier shale (USA) was sampled as a typical clay-bearing siliceous, organic-rich, gas-mature shale and characterized over pore diameters ranging 2 nm to 3000 nm. Three advanced imaging techniques were utilized correlatively, including the application of Xe+ plasma focused ion beam scanning electron microscopy (plasma FIB or PFIB), complemented by the Ga+ FIB method which is now frequently used to characterise porosity and organic/inorganic phases, together with transmission electron microscope tomography of the nano-scale pores (voxel size 0.6 nm; resolution 1–2 nm). The three pore-size scales each contribute differently to the pore network. Those 100 nm (greatest total volume hence determines fluid storativity). Four distinct pore types were found: intra-organic, organic-mineral interface, inter-mineral and intra-mineral pores were recognized, with characteristic geometries. The whole pore network comprises a globally-connected system between phyllosilicate mineral grains (diameter: 6–50 nm), and locally-clustered connected pores within porous organic matter (diameter: 200–800 nm). Integrated predictions of pore geometry, connectivity, and roles in controlling petrophysical properties were verified through experimental permeability measurements.

Chemical and mineralogical signatures of mudstones from the Agnone Flysch turbidite successions (late Tortonian to early Messinian) deposited in the Lagonegro-Molise foredeep basin reveal new insight for the sedimentary evolution of the southern Apennines during late Miocene. Geochemical and mineralogical signatures of the Verrino and Poggio Villanelle members of the Agnone Flysch mark a complex sedimentation history testifying to a multi-source area probably due to structural changes and depositional basin physiography. The studied mudstones show chemical variations in term of Ca vs. Si and Al. Mineralogical analyses confirm a decrease of carbonate minerals and an increase of silicate phases passing from Verrino Member to Poggio Villanelle Member samples. Compositional data of the mudstone samples of both members mainly record a derivation from felsic rocks due to the Calabrian terranes unroofing. Poggio Villanelle Member samples further show an enrichment in Cr, Ni, Fe e Mg in accordance with higher chlorite content suggesting a mafic supply probably related to an ophiolitic source successively exposed. Thus, those trends based on chemical and mineralogical data suggest a change in relative abundance of a detritus characterized by different compositions through time and space. Whole rock geochemistry of the studied mudstones indicate that they are from the first-cycle sediments. Palaeoweathering processes in source areas were moderate as shown by CIA (Chemical Index of Alteration) and CIA’ (modified Chemical Index of Alteration) values of the mudstones of both members (Verrino and Poggio Villanelle members). The trends observed in the paleoweathering diagrams suggest source areas characterized by moderate weathering in non-steady-state conditions which have changed toward the upper portion of the sedimentary succession. Those changes are mainly related to the geodynamic conditions of the source areas where active tectonism allows erosion of all zones within weathering profiles developed on source rocks. The paleocurrent data and the compositional analysis of the mudstones and sandstones indicate a provenance (supply) from the western, north-western, and south-western sectors of the basin where carbonate platforms and magmatic, metamorphic and sedimentary rocks cropped out.

The construction of a repository for geological disposal of radioactive waste will include the use of cement-based materials. Following closure, groundwater will saturate the repository and the extensive use of cement will result in the development of a highly alkaline porewater, pH &gt, 12.5, this fluid will migrate into and react with the host rock. The chemistry of the fluid will evolve over time, initially high [Na] and [K], evolving to a Ca-rich fluid, and finally returning to the groundwater composition. This evolving chemistry will affect the long-term performance of the repository, altering the physical and chemical properties, including radionuclide behaviour. Understanding these changes forms the basis for predicting the long-term evolution of the repository. This study focused on the determination of the nature and extent of the chemical reaction, as well as the formation and persistence of secondary mineral phases within a mudstone, comparing data from sequential flow experiments with the results of reactive transport modelling. The reaction of the mudstone with the cement leachates resulted in small changes in pH with the precipitation of calcium aluminium silicate hydrate (C-(A-)S-H) phases of varying compositions. As the system evolves, secondary C-(A-)S-H phases re-dissolve and are replaced by secondary carbonates. This general sequence was successfully simulated using reactive transport modelling.

Jersovec chert deposit is a part of the transitional zone between the internal and the external Dinarides. Tethyan cherts are often interlaid with fie-grained material, as is also the case in Jersovec, where chert beds interchange with several thin, up to 10 cm thick layers of fie-grained sedimentary rocks. The source of this material is often questionable and interpreted to be terrigenous, volcanogenic or even combination of both. In order to determine origin and depositional environment of fie-grained material, detailed mineralogical and geochemical analyses were performed. Fine-grained sedimentary rocks were characterised by X-ray diffraction (XRD), scanning electron microscopy/ energy dispersive X-ray spectroscopy (SEM/EDS) and inductively coupled plasma emission spectroscopy (ICPES) and mass spectroscopy (ICP-MS). All samples are mineralogically very similar but differ in mineral ratios. They contain quartz and clay minerals, predominantly illite/muscovite and chlorite group minerals. SEM/EDS analysis additionally revealed zircon, monazite, Ti-oxide (probably rutile) and iron oxides/hydroxides in all samples, whereas chromite, ilmenite, xenotime, apatite and baryte were found only in some of them. The average sizes of accessory minerals range from 3–20 μm. Two samples differ from the others by their brown colour and higher Fe2O3 and lower SiO2 contents. All other samples are green. Chemical analysis showed that they consist mostly of SiO2 (46.3–69.3 %), Al2O3 (15–24.1 %) and minor contents of K2O (2.8–3.4 %), Fe2O3 (2.1–8.4 %), MgO (1.6–2.3 %), TiO2 (0.5–0.7 %), CaO (0.3–1.4 %), Na2O (0.1 %) and P2O5 (up to 0.5 %). Position of all samples in the Zr/TiO2 vs. (V+Ni+Cr)/Al2O3 diagram points to terrigenous origin and sedimentation on the continental margin. According to the chemical weathering indices (CIA and CIW) material has been subjected to the intense and long weathering, supported also by the index of compositional variability (ICV), which corresponds to the compositionally mature material, and by rounded zircon and ilmenite grains.

The Palaeogene Isparta Basin of southwestern Anatolia formed between two convergent arms of the Isparta Bend orocline of the Tauride orogen. The origin of this tightening orocline is hypothetically explained in plate-tectonic terms. Basin sedimentation commenced on a down-warped Mesozoic carbonate platform of a crustal block accreted at the end of Cretaceous to the southern margin of the Anatolian plate. The basin earliest deposits are Palaeocene reddish mudstones with a fossil-barren condensed basal part and increasingly interspersed with thin calcarenitic turbidites towards the top. The supply of turbiditic sediment to the basin plain subsequently increased, as the upper-bathyal basin plain became surrounded from both sides by a narrow littoral shelf with an advancing turbiditic slope ramp. A major forced regression occurred at the end of Bartonian, causing incision of subaerial to submarine valleys up 600 m deep, filled in with gravelly to sandy turbidites and debrisflow deposits during the subsequent rise of relative sea level. The half-filled valleys were re-incised due to a Rupelian forced regression and were fully filled with fluvio-deltaic bayhead deposits during a final marine transgression that re-established the basin-margin biocalcarenitic shelf. The littoral environment then expanded across the shallowing basin, as the basin axial zone was up-domed and eroded to bedrock level at the end of Oligocene and the basin was tectonically inverted in Miocene. The pattern of intra-orocline foreland sedimentation documented by this case study provides tentative criteria for the recognition of synorogenic oroclines and for their distinction from post-orogenic oroclines. © 2017 The Authors. Basin Research © 2017 John Wiley & Sons Ltd, European Association of Geoscientists & Engineers and International Association of Sedimentologists

In order to study the properties of high-temperature creep for mudstone, MTS810 electro-hydraulic servo material test system and MTS652.02 high temperature furnace are utilized for the creep test of mudstone at 700?C. Considering the visco-elastic-plastic characteristics and the damage effect, the variable-order fractional creep model is established to research the creep character, and it is found that the proposed model can be well fitting of our experimental results. Especially, variable-order function can be used to analyze and study the viscoelastic property evolution of mudstone in process of high-temperature creep. Compositions of mudstone are distinguished by X-ray diffraction technology. The presence of the illite under high temperatures can be used for explaining the viscous feature prevails over the elastic ones in viscoelastic properties.

In order to develop an improved pore pressure prediction model for the overburden mudstones in the Rovuma Basin, offshore Mozambique, we apply Eaton's method to example well data from three exploration wells, which intersect Quaternary, Tertiary and Cretaceous sediments over depth intervals down to ∼3 km below seafloor. The predictive method only included the effects of mechanical compaction, which is a reasonable assumption for the low-temperature shallow sections. We found that Eaton's method applied to resistivity and acoustic log attributes works well and can be used to identify the mudstones that display over-pressured or normally pressured sections. The predicted pore pressures showed a good match to pore pressures in permeable formations. Using this calibration, we derived an improved pore-pressure prediction method for these wells and for the Rovuma Basin in general. The resulting model should give a good basis for future analysis of compaction processes and pore pressure in this basin., Geology; Geophysics; Petroleum engineering; Petrology; Lithology; Mineralogy; Mudstone; Rovuma basin; Sonic transit time; Pore pressure; Effective stress; Resistivity

It is of paramount importance to understand the hydration swelling and weakening properties of clay minerals, such as montmorillonite, to determine their mechanical responses during deep underground argillaceous engineering. In this study, the mineral components and microscopic structure of mudstone were characterised using X-ray powder diffraction and field-emission scanning electron microscopy. Experimental schemes were devised to determine the properties of mudstone under the influence of underground water and stress, these involved compacting montmorillonite particles with various water contents and conducting uniaxial compression tests. Experimental results demonstrated that compaction stress changes the microscopic structure of the montmorillonite matrix and affects its properties, and stress independency was found at particular water and stress conditions. Two equations were then obtained to describe the swelling and weakening properties of the montmorillonite matrix based on the discrete element method, further, the hydration swelling equation represents the linear decrease in the density of the montmorillonite matrix with an increase in the water content. It was also determined that the water dependency of uniaxial compressive strength can be described by negative quartic equations, and the uniaxial compressive strength of the montmorillonite matrix is just 0.04 MPa with a water content of 0.6. The experimental results are in good agreement with the calculated solutions and provide an important experimental basis to the understanding of the mechanical properties of montmorillonite-rich mudstones under the influence of underground water and stress.

Despite recent advances, diagenetic processes in fine-grained sediments are still relatively poorly understood. Key questions still to be resolved include the types of diagenetic minerals present in mudstones and the extent of element mobility in these low permeability systems. This study utilizes data from the Haynesville-Bossier Shale, USA, to analyze lithologies, discriminate authigenic phase, and identify mobile elements during diagenesis. It has implications for understanding how authigenic minerals develop and the sources of those authigenic minerals in fine-grained sediments.On the basis of grain-size and mineralogy five lithologies are designated: (i) silica-rich argillaceous mudstones; (ii) argillaceous siliceous mudstones; (iii) mixed siliceous mudstones; (iv) mixed mudstones; and (v) authigenically-dominated mudstones. The diagenetic development of the Haynesville-Bossier Shale can be divided in to early and late diagenesis. Ferroan and non-ferroan dolomite, framboidal pyrite and bioclast pore-filling kaolinite and calcite grain replacements and cements all formed during early diagenesis. Late diagenetic minerals phases include illite formed by the illitisation of smectite, replacive and displacive chlorite, calcite-replacive albite, quartz-replacive calcite and replacive and/or displacive quartz.The presence of extensive late diagenetic mineral precipitates indicates that there was a degree of element mobility on at least the local scale. Aluminium present in albite is most likely to have resulted from the illitization of smectite. Quartz overgrowths probably resulted from illitization and the pressure dissolution at quartz silt grain boundaries. Externally, hydrothermal fluids resulting from regional-scale igneous activity appear to have played a role in the formation of chlorite and possibly albite. The work indicates that extensive mineral development and element mobility occurred during late diagenesis.

The detection of chlorinated hydrocarbons by Curiosity on Mars has been attributed to the presence of unidentified indigenous organic matter. Similarly, oxychlorines on Earth have been proposed to be responsible for the apparent lack of organics in the Atacama Desert. The presence of perchlorate (ClO4-) poses a unique challenge to the measurement of organic matter due to the oxidizing power of oxychlorines during commonly used pyrolysis-gas chromatography-mass spectrometry (py-GC-MS) methods. Here, we show that perchlorates and other oxyanion salts inhibit the detection of organic compounds but that removing these problematic species prior to pyrolysis by using an optimal sample extraction duration and suitable ratios of water to sample mass enables analysis. We have characterized leached and unleached samples containing perchlorates from the Atacama Desert and have found that after leaching, the py-GC-MS chromatograms of the dried mineral residues show identifiable biomarkers associated with indigenous cyanobacteria. Samples which were pyrolyzed without leaching showed no detectable organic matter other than background siloxane and very weak or no trace of detectable polychlorinated benzenes. Dried sample residues remaining after leaching, the mineral matrix and water-insoluble organic matter, showed a strong organic response in all cases when analyzed by py-GC-MS. These residues are most likely the product of the pyrolysis of water-insoluble organics originally present in the samples. In addition, our results imply that previous soil analyses which contained high levels of oxyanions and concluded that organics were either not present or were present at extremely low levels should be reexamined.

The Paleogene &ldquo, megabeds&rdquo, of the Julian-Slovenian Basin are regional, basin-wide deposits, produced by catastrophic carbonate platform collapses. They record the emplacement of a bipartite slide mass behaving as a cohesive blocky/debris flow in the lower part, and as a grain to turbulent flow in the upper part. Several types of primary (sedimentary) soft sediment deformation structures testify fluid overpressure conditions during emplacement. Such structures are identified within a brecciated, fine grained matrix that encloses and intrudes slide blocks and clasts, characterized by NE-, NW- and SW-directed paleo-transport directions, indicating a depositional setting close to the basin margins. Here we present an updated review of some representative megabeds, exposed in the open-pit quarry outcrops of Anhovo (SW Slovenia). In particular, we here discuss new interpretations based on X-ray fluorescence spectrometry (XRF), thermo-gravimetry (TG) and electric resistivity tomography (ERT). Our results indicate that basal marly clasts of the megabeds are markedly different from the uppermost draping marls, suggesting two different coeval sources. The relationships with the underlying successions are strongly erosive, with deep localized scouring of the substrate and amalgamations between different megabeds, and the depositional units inside individual megabeds, supporting the geochemical differences.

Mudstone samples from the Moreno (Upper Cretaceous-Paleocene) and Kreyenhagen (Eocene) formations are analysed using X-ray diffraction (XRD) and X-ray fluorescence (XRF) to determine their mineralogy. Smectite (Reichweite R0) is the predominant phyllosilicate present, 48% to 71.7% bulk rock mineralogy (excluding carbonate cemented and highly bio siliceous samples) and 70% to 98% of the &lt, 2 &mu, m clay fraction. Opal CT and less so cristobalite concentrations cause the main deviations from smectite dominance. Opal A is common only in the Upper Kreyenhagen. In the &lt, m fraction, the Moreno Fm is significantly more smectite-rich than the Kreyenhagen Fm. Smectite in the Moreno Fm was derived from the alteration of volcaniclastic debris from contemporaneous rhyolitic-dacitic magmatic arc volcanism. No tuff is preserved. Smectite in the Kreyenhagen Fm was derived from intense sub-tropical weathering of granitoid-dioritic terrane during the hypothermal period in the early to mid-Eocene, the derivation from local volcanism is unlikely. All samples had chemical indices of alteration (CIA) indicative of intense weathering of source terrane. Ferriferous enrichment and the occurrence of locally common kaolinite are contributory evidence for the intensity of weathering. Low concentration (max. 7.5%) of clinoptilolite in the Lower Kreyenhagen is possibly indicative of more open marine conditions than in the Upper Kreyenhagen. There is no evidence of volumetrically significant silicate diagenesis. The main diagenetic mineralisation is restricted to low-temperature silica phase transitions.

Silica cementation exerts a key control on the compaction and geotechnical properties of mudstones, and byextension, the style of hydrocarbon and/or mineral systems present in a given sedimentary basin. Integratedmicroscopic and bulk geochemical observations demonstrate that siliceous mudstones in the Bowland ShaleFormation, a target for UK shale gas extraction, exhibit abundant dispersed, discrete, μm-scale quartz cements,and exhibit silica enrichment (‘excess’) above a local detrital Si/Al threshold of 2.5. Dissolution of siliceousradiolarian tests during early diagenesis is identified as the main source of silica (opal A) required for quartzprecipitation, either via opal CT or directly to quartz, and potentially generated as a product of anoxic marine‘weathering’ (dissolution) of reactive silicates during early diagenesis. Excess silica correlates with free hydrocarbons(S1) normalised to total organic carbon (oil saturation index; OSI); we propose early diagenetic quartzprecipitation suppressed pore collapse (‘buttress effect’), retaining the pore space capacity to host oil. Quartzprecipitation was likely catalysed, for example via low porewater pH, elevated Al and/or Fe oxide content, and/or abundant labile organic matter. Juxtaposition of siliceous mudstones and mudstones lacking quartz cementindicates silica was immobile beyond the bed scale. Thus metre-scale siliceous packages likely represent moreprospective units within the Bowland Shale (in terms of unconventional hydrocarbons), on the basis of earlydiagenetic biogenic-derived quartz cementation leading to improved hydrocarbon storage capacity coupled toenhanced brittleness. These findings are relevant for shale oil and shale gas systems, specifically where oilretained in pores subsequently cracks to generate gas. These findings also suggest the Bowland Shale is a subclassof black shale, defined by the potential to host a relatively large volume of early diagenetic fluids,derived from anoxic bottom waters, which were potentially S- and/or metal-bearing. This is potentially relevantfor understanding the genesis of adjacent and related Pb-Zn mineral deposits.