Search

Increasing the water flux of nanofiltration membrane is of great significance for expanding the application field of nanofiltration membrane, reducing energy consumption and building a conservation-oriented society. Polyamide nanofiltration membrane prepared by traditional interfacial polymerization has many problems, such as dense internal structure and poor water permeability. In this study, polyacrylic acid (PAA) was introduced into the interfacial polymerization. There are electrostatic and hydrogen bond interactions between PAA and piperazine (PIP). At the same time, the polymer properties of PAA increase the viscosity of aqueous solution. Under the joint action of two factors, the diffusion of PIP to the organic phase was effectively restricted. A thin (~62 nm) separation layer was prepared to improve the water flux of the nanofiltration membrane. In addition, the introduction of PAA also enhanced the hydrophilicity and electronegativity of the membrane surface. The results showed that the optimum addition of PAA was 0.15 wt.%, and under the working condition of 25°C and 0.5 MPa, the pure water flux of the PAA_0.15@PA membrane is 80.18 L·m–2·h–1, which is nearly 25% higher than that of pristine PA membrane. The salt rejection order is Na2SO4> MgSO4> NaCl > MgCl2, which is a typical negatively charged nanofiltration membrane. The PAA_0.15@PA membrane has a narrow pore-size distribution, has a high rejection rate for small molecule (180–400 Da) organics while maintaining a high flux, and has good separation stability.

The Shapinggou porphyry molybdenum (Mo) deposit, located in Jinzhai County, Anhui Province, China, is the largest in the Qinling-Dabie Mo Metallogenic Belt. The intrusive rocks in the Shapinggou Mo ore district formed in the Yanshanian can be divided into two stages based on zircon U-Pb dating and geochemical features. This study focuses on the late stage intrusions (quartz syenite and granite porphyry), which are closely genetically related to molybdenum mineralization. Petrographic observations identified two quartz polymorphs in the quartz syenite and granite porphyry, which were derived from the same magmatic sources and similar evolutionary processes. The quartzes were identified as a xenomorphic α-quartz within quartz syenite, while the quartz phenocrysts within the granite porphyry were pseudomorphous β-quartz, characterized by a hexagonal bipyramid crystallography. The pseudomorphous β-quartz phenocrysts within the granite porphyry were altered from β-quartz through phase transformation. These crystals retained β-quartz pseudomorph. Combined with titaniumin- zircon thermometry, quartz phase diagrams, and granitic Q-Ab-Or-H2O phase diagrams, it is suggested that the quartz syenite and granite porphyry were formed under similar magmatic origins, including similar depths and magmatic crystallization temperatures. However, the α-quartz within quartz syenite indicated that the crystallization pressure was greater than 0.7 GPa, while the original β-quartz within the granite porphyry was formed under pressures between 0.4 and 0.7 GPa. The groundmass of the granite porphyry which formed after the phenocryst indicated a crystallizing pressure below 0.05 GPa. This indicates that the granite porphyry was formed under repetitive and rapid decompression. The decompression was significant as it caused the exsolution of the ore-forming fluids, and boiling and material precipitation during the magmatic-fluid process. The volumetric difference during the phase transformation from β-quartz to α-quartz caused extensive fracturing on the granite porphyry body and the wall rocks. As the main ore-transmitting and ore-depositing structures, these fractures benefit the hydrothermal alteration and stockwork-disseminated mineralization of the porphyry deposit. It is considered that the pseudomorphous β-quartz phenocrysts of the porphyritic body are metallogenic indicators within the porphyry deposits. The pseudomorphous β-quartzes therefore provide evidence for the formation of the porphyry deposit within a decompression tectonic setting.