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Abstract: The chromatographic behavior of adamantane derivatives as sorbates and sorbents was studied. The retention characteristics of adamantane derivatives and some organic compounds on an adamantylsilicone stationary phase were determined. The effect of various substituents on the chromatographic behavior of the compounds was examined. Correlations between the sorption and structural characteristics of adamantane derivatives were found.

Correlations between physicochemical properties and chromatographic retention parameters of adamantane derivatives were studied. The Kovats indices and contributions of hydrocarbon radicals and functional groups to the chromatographic retention were calculated from the experimental data.