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Coastal protection is of paramount importance because erosion and flooding affect millions of people living along the coast and can largely influence countries' economy. The implementation of nature‐based solutions for coastal protection, such as sand engines, has become more popular due to these interventions' adaptability to climate change. This study explores synergies between Artificial Intelligence (AI) and hydro‐morphodynamic models for the creation of efficient decision‐making tools for the choice of optimal sand engines configurations. Specifically, we investigate the use of long‐short‐term memory (LSTM) models as predictive tools for the morphological evolution of sand engines. We developed different LSTM models to predict time series of bathymetric changes across the sand engine as well as the time‐decline in the sand engine volume as a function of external forces and intervention size. Finally, a MATLAB framework was developed to return LSTM model results based on users' inputs about sand engine size and external forcings. Sand engines are a type of coastal protection where a large volume of sand is added to the coastline to protect low‐lying areas from erosion and flooding. Sand engines, like other Nature‐based solutions, are gaining popularity due to their potentially lower maintenance costs compared to other concrete‐based coastal protection strategies and a number of co‐benefits. However, there are currently no design guidelines or decision‐making tools for sand engines. Here we address this gap in the state of knowledge and use Artificial Intelligence (AI) techniques to analyze the evolution of sand engines under different waves and external forcings. AI models are also used to predict the volume of sand being transferred by the waves from the location of deposition to the surrounding areas. To facilitate the use of AI models, this study proposes a computer software, sand engine surface, which includes all the AI models developed in this study, predicting the evolution of sand engine and volume of sand being transported. This study presents models to predicts the evolution of Sand Engine over time in terms of Volumetric changes and Morphological changesAll our Long Short Term Memory models' results are accessible through Sand Engine SurfaceApplicationSand Engine Surfaceis MATLAB framework providing results about time‐dependent morphological changes of sand engines based on users' inputs This study presents models to predicts the evolution of Sand Engine over time in terms of Volumetric changes and Morphological changes All our Long Short Term Memory models' results are accessible through Sand Engine SurfaceApplication Sand Engine Surfaceis MATLAB framework providing results about time‐dependent morphological changes of sand engines based on users' inputs

Coastal flood warning and design of coastal protection schemes rely on accurate estimations of water level and waves during hurricanes and violent storms. These estimations frequently use numerical models, which, for computational reasons, neglect the interaction between the hydrodynamic and wave fields. Here, we show that neglecting such interactions, or local effects of atmospheric forcing, causes large uncertainties, which could have financial and operational consequences because flood warnings are potentially missed or protection schemes underdesigned. Using the Severn Estuary, SW England, we show that exclusion of locally generated winds underestimates high water significant wave height by up to 90.1%, high water level by 1.5%, and hazard proxy (water level + 1/2 significant wave height) by 9.1%. The uncertainty in water level and waves is quantified using a system to model tide‐surge‐wave conditions, Delft3D‐FLOW‐WAVE in a series of eight model simulations for four historic storm events. Coastal zones worldwide are subject to combined effects of astronomical tides, meteorological storms surges, waves, and wind during storms and hurricanes, which can lead to flooding, property damage, and casualties. Coastal communities and critical infrastructure rely on accurate water level and wave forecasts to mitigate these combined hazards. Forecasts utilize hydrodynamic numerical models, which need to accurately represent these hazards and how they interact with, and feedback to, each other. This study uses a model, Delft3D‐FLOW‐WAVE, to calculate how tides and waves from four historic storm events combine to contribute to water level, wave height, and hazard proxy (water level + 1/2 wave height) in the Severn Estuary, southwest England. Additional simulations are run to show how local winds can further contribute to the hazard. Results show that including locally generating winds in simulations of water level, wave height, and hazard proxy is most important for accurate representation of physical processes that contribute to coastal hazards. Excluding locally generated winds from numerical model predictions could mean that flood alerts, warnings, and evacuation orders are missed, or coastal protection schemes are underdesigned, potentially leading to more flooding. Delft3D‐FLOW‐WAVE is used to quantify uncertainty in water level and waves in a hypertidal estuary due to coupling and forcing processesExclusion of locally generated winds underestimates significant wave height at high water by up to 90.1% in the outer estuaryLocal atmospheric forcing is vital in coastal hazard predictions for timely flood warnings and to avoid underdesigning protection schemes

A numerical tool integrating hydrodynamics, vegetation growth, stochastic selection, and Monte‐Carlo simulation is developed to predict channel network evolution in a newly inundated back‐barrier wetland. Focusing on the formation and evolution of tidal channels, model simulations suggest a clear tendency towards specific creek topologies with high probability despite creek evolution being subject to random perturbations. These creek topologies are primarily determined by wetland topography while the influence of vegetation is secondary. Ensemble results of Monte‐Carlo simulations identify threshold points leading to bimodal separation of the emergent creek networks characterized by different complexity and efficiency. This, in turn, assists the recognition of necessary human interventions to encourage the formation of complex and far‐reaching creek networks that can promote exchange of materials between estuaries and salt marshes and, hence, maintain salt marsh ecosystem structure and function. A large part of the world's low‐lying areas is heavily managed to protect lives, assets, and landscapes from marine‐derived natural hazards. However, climate change is putting unprecedented pressure on these managed environments, forcing the adoption of “no active intervention” or “managed realignment” strategies in areas where “hold the line” options cannot be justified due to financial constraints. This leads to the very likely possibility that unmaintained coastal defenses will begin to fail, raising questions as to the potential impacts on low‐lying regions as well as the options available to mitigate impacts through targeted interventions. Of particular interest is the question of whether it is possible to facilitate the shift of managed coastal wetlands towards intertidal environments in which tidal creeks form and evolve to support salt marshes. Combining the use of a numerical model and multiple model runs, we find that although the evolution of tidal creeks is subject to random disturbances, creek networks are likely to form with a clear tendency towards specific types. Grouped results of multiple, random simulations are useful in identifying interventions that are necessary for developing far‐reaching tidal creek networks. Influence of vegetation is found to be secondary compared to the wetland topography in terms of influencing tidal creek evolution. A reduced complexity model is developed based on simple rules for projecting tidal creek network developmentThe influence of vegetation in determining probabilities of creek formation is secondary compared to wetland topographyEnsemble prediction of tidal creek evolution is effective for identifying threshold points and targeted interventions

Tidal deltas are fragile systems whose morphology can be easily impacted by variations in water and sediment fluxes caused by natural and human processes. Here we explore the relation between tidal prism and sediment dynamics in tidal deltas using the recent evolution of the Yangtze River estuary, China, as an example. Using the numerical model Delft3D, we examine how changes in delta morphology can trigger variations in tidal signal, suspended and bed load transport, and how these could ultimately cause additional morphological changes. Our results show that a positive feedback between sediment deposition and tidal prism dominates the morphodynamic evolution of the delta. Accretion of the shoals in the delta front increases the dissipation of tides and decreases the tidal prism leading to weaker tidal flows. This reduction in tidal currents lowers the sediment flushing capacity of the system, promoting deposition on the shoals and tidal dissipation. This positive feedback potentially traps more sediment in the delta topset and possibly offsets the decrease in sediment load triggered by the construction of upstream dams, often present in tidal deltas. Reduced tidal prism diminishes tidal discharges and peak velocities, preventing sediment flushing and favoring sediment trappingPositive feedback has mitigated the drastic reduction in sediment load triggered in the last decade by the construction of the TGDPositive feedback between deposition and tidal prism highlights the importance of the shoals for the stability of the entire delta

The current paradigm is that salt marshes and their important ecosystem services are threatened by global climate change; indeed, large marsh losses have been documented worldwide. Morphological changes associated with salt marsh erosion are expected to influence the hydrodynamics and sediment dynamics of coastal systems. Here the influence of salt marsh erosion on the tidal hydrodynamics and sediment storage capability of shallow bays is investigated. Hydrodynamics, sediment transport, and vegetation dynamics are simulated using the numerical framework Coupled Ocean‐Atmosphere‐Wave‐Sediment Transport in the Barnegat Bay‐Little Egg Harbor system, USA. We show that salt marsh erosion influences the propagation of tides into back‐barrier basins, reducing the periodic inundation and sediment delivery to marsh platforms. As salt marshes erode, the sediment trapping potential of marsh platforms decreases exponentially. In this test case, up to 50% of the sediment mass trapped by vegetation is lost once a quarter of the marsh area is eroded. Similarly, without salt marshes the sediment budget of the entire bay significantly declines. Therefore, a positive feedback might be triggered such that as the salt marsh retreats the sediment storage capacity of the system declines, which could in turn further exacerbate marsh degradation. Morphological changes induced by marsh lateral erosion affect tidal dynamics in estuarine systemsPositive feedback between marsh loss and reduction in sediment trapping capacity of estuarine systemsEffects of marsh loss on sediment budget destinations

Seagrasses are marine flowering plants that strongly impact their physical and biological surroundings and are therefore frequently referred to as ecological engineers. The effect of seagrasses on coastal bay resilience and sediment transport dynamics is understudied. Here we use six historical maps of seagrass distribution in Barnegat Bay, USA, to investigate the role of these vegetated surfaces on the sediment storage capacity of shallow bays. Analyses are carried out by means of the Coupled‐Ocean‐Atmosphere‐Wave‐Sediment Transport (COAWST) numerical modeling framework. Results show that a decline in the extent of seagrass meadows reduces the sediment mass potentially stored within bay systems. The presence of seagrass reduces shear stress values across the entire bay, including unvegetated areas, and promotes sediment deposition on tidal flats. On the other hand, the presence of seagrasses decreases suspended sediment concentrations, which in turn reduces the delivery of sediment to marsh platforms. Results highlight the relevance of seagrasses for the long‐term survival of coastal ecosystems, and the complex dynamics regulating the interaction between subtidal and intertidal landscapes. Seagrasses influence the resilience of coastal wetlands to external agents, such as sea level rise, by altering the velocity field and sediment transport dynamics of coastal environments. In many areas worldwide seagrass habitats are declining. This paper studies how seagrasses influence the sediment budget of shallow bays using a computer model, and Barnegat Bay, New Jersey, as test case. Specifically, we used computer models to simulate velocity and sediment transport dynamics in Barnegat Bay with historical seagrass maps for the period 1968–2009. These maps show that for Barnegat Bay seagrasses have decreased in time. We found that seagrasses are important for the retention of sediments within bay systems, and when seagrasses are present less sediments are lost in the ocean, which is relevant for the long‐term survival of coastal wetlands as an abundance of sediments generally corresponds to more resilient wetlands. The presence of seagrasses mainly increases the storage of sediments on tidal flats, while it decreases the delivery of sediments to the marsh platforms during high tide. Our results highlight the importance of seagrasses and are relevant for coastal communities and coastal managers worldwide as they could aid the design of coastal protection schemes. Seagrass loss increases bay‐wide sediment concentrationsInfluence of seagrass decline on sediment budget in shallow baysSeagrass impact on sediment exchange between tidal flats and salt marsh

Herein, we investigate the relationship between wind waves, salt marsh erosion rates, and the planar shape of marsh boundaries by using aerial images and the numerical model Coupled‐Ocean‐Atmosphere‐Wave‐Sediment‐Transport Modeling System (COAWST). Using Barnegat Bay, New Jersey, as a test site, we found that salt marsh erosion rates maintain a similar trend in time. We also found a significant relationship between salt marsh erosion rates and the shape of marsh boundaries which could be used as a geomorphic indicator of the degradation level of the marsh. Slowly eroding salt marshes are irregularly shaped with fractal dimension higher than rapidly deteriorating marshes. Moreover, for low‐wave energy conditions, there is a high probability of isolated and significantly larger than average failures of marsh portions causing a long‐tailed distribution of localized erosion rates. Finally, we confirm the existence of a significant relationship between salt marsh erosion rate and wind waves exposure. Results suggest that variations in time in the morphology of salt marsh boundaries could be used to infer changes in frequency and magnitude of external agents. Shorelines fractality is an indicator of salt marsh vulnerabilitySalt marsh erosion rates maintain similar trend in timeSalt marsh erosion depends on wave energy

Storm surge barriers can protect against coastal flooding. Observations from the Venice Lagoon in Italy show that the operation of these types of barriers must be carefully tuned to avoid inhibiting sedimentation and compromising marsh resilience to sea-level rise.

We use field data and a cellular automata model to investigate salt marsh response to wave action under different wave energy conditions and frequency of extreme events. Our results suggest that salt marsh response to wind waves is tied to their local properties. In case of low‐wave‐energy conditions, local variability in marsh resistance might lead to the unpredictable failure of large marsh portions with respect to average erosion rates. High‐wave‐energy conditions, while overall leading to faster marsh deterioration, produce constant and predictable erosion rates. A high occurrence of extreme events leads to smoother and more uniformly deteriorating marsh boundary profiles. Salt marshes subject to weak wave energy conditions are the most susceptible to variations in the frequency of extreme events. This suggests that variations in time in the morphology of salt marsh boundaries could be used to infer changes in frequency and magnitude of external agents. Small‐scale ecogeomorphic heterogeneities affect salt marsh evolutionMarshes subject to weak waves are the most susceptible to changes in extreme eventsHigh‐wave‐energy and frequent extreme events lead to smooth marsh boundary

There are still numerous uncertainties over the influence of anthropogenic interventions on salt marsh dynamics. This study uses the Ribble Estuary as a test case and an integrated approach of numerical modeling and paleoenvironmental analysis to investigate the contribution of embankment construction to long‐term marsh accretion. Accretion rates derived using optically stimulated luminescence dating (OSL) were combined with a multi‐proxy paleoenvironmental investigation on sediment cores extracted from the salt marsh, the mobile seafloor of the central Irish Sea and the river catchment area. These analyses provided a first evolutionary perspective on the Ribble Estuary preceding any management interventions. The paleoenvironmental analyses were then compared to simulations conducted using the hydrodynamic model Delft3D to investigate the effects of embankment construction on estuarine hydrodynamics and morphodynamics of the salt marsh over the period constrained by the OSL. The numerical simulations showed that embankments were responsible for an overall intensification of the ebb currents in the system which promoted sediment export. The paleoenvironmental analyses showed that the marsh has been accreting at a rate of 4.61 to 0.86 cm yr−1over the last ca. 190 years and that the high sedimentation rate was caused by a naturally high rate of sediment supply. The model‐data integration showed that the effects of the embankment construction on sediment transport did not compromise the long‐term resilience of the salt marsh because of the high rates of sediment supply and the river dredging which enhanced the flood dominance of the tide near the tidal flat. Salt marshes are important ecosystems and can help protect the coastline from flooding. Sediment availability is important to help the establishment and maintenance of salt marshes. Large quantities of sediments can help salt marshes to expand and grow in elevation. Instead, the removal of sediments can cause marsh erosion. Management interventions along a coastline can influence the movement of sediments and determine how much sediments can reach (or not reach) the marsh platform. This study found that in the Ribble Estuary, a site renowned for its high rate of sediment supply, the construction of embankments promoted sediment export out of the estuary, but the high sedimentation rates caused by a natural high rate of sediment supply from the ocean, aided by river dredging, allowed long‐term marsh accretion despite the embankments presence, meaning that the marsh continued to grow in elevation over time. The construction of embankments along an estuary can reduce salt marsh accretion by promoting sediment exportEmbankments do not necessarily compromise the long‐term resilience of salt marshes when high rates of sediment supply are presentChannel dredging can promote sediment import and reduce the effects of embankment construction on sediment transport The construction of embankments along an estuary can reduce salt marsh accretion by promoting sediment export Embankments do not necessarily compromise the long‐term resilience of salt marshes when high rates of sediment supply are present Channel dredging can promote sediment import and reduce the effects of embankment construction on sediment transport

The synthesis and fluorescence properties of novel bis(salicylaldiminato)zinc(II) Schiff-base complexes is reported. Selfassembled monolayers (SAMs) of these complexes are obtained by reaction of coupling layers, functionalized quartz substrates and a derivatized precursor complex. A comparison between the integrated emission intensity of the SAM films and that of a suitable model compound in solution indicates molecular fluorescence retention of the ZnII Schiff bases on going from the solution phase to the monolayer. This is consistent with the absence of significant self-quenching processes, as expected on the basis of the relatively high estimated surface coverage. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

The synthesis and characterization of a new, amino-derivatized functional bis(salicylaldiminato)NiII complex is reported. It is a useful and reactive precursor in the synthesis of polyimide thermosets. Thus, the first synthesis of a polyimide containing a nonlinear optical NiII Schiff base complex in the main chain is achieved by thermally controlled film polymerization. Polymerization was monitored on silicon substrates by FT-IR spectroscopy. The polymer film possesses characteristics analogous to those of the insoluble polymer obtained by polymerization in solution, as evidenced by FT-IR spectroscopy and TGA analysis. The present approach might represent a general strategy for achieving thin films of insoluble, functional polymers. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

A series of poly(ether sulfone)s and poly(ether ketone)s were synthesized from combinations of 1,5- and 2,6-bis(4-fluorosulfonyl)naphthalene, 2,6-bis(4-fluorobenzoyl)naphthalene, and 2,6-bis(4-fluorobenzoyl)quinoline with 3,3',5,5'-tetramethylbiphenyl-4,4'-diol and 2,2',3,3',5,5'-hexamethylbiphenyl-4,4'-diol. The polycondensations proceeded quantitatively in diphenylsulfone in the presence of anhydrous potassium carbonate to afford polymers with inherent viscosities between 0.40 and 1.28 dL/g measured in N-methyl-2-pyrrolidone or concentrated sulfuric acid. The tetramethyl- and hexamethyl-substituted aromatic polyethers exhibited good thermal stability, did not decompose below 330°C in both air and nitrogen atmospheres, and had higher glass transition temperatures than the corresponding unsubstituted polymers. The methylsubstituted poly(ether sulfone)s and poly(ether ketone)s showed good solubility in such common organic solvents as N-methyl-2-pyrrolidone, N,N-dimethylacetamide, tetrahydrofuran, chloroform, and 1,4-dioxane.

Salt marshes are valuable ecosystems that must trap sediments and accrete in order to counteract the deleterious effect of sea level rise. Previous studies have shown that the capacity of marshes to build up vertically depends on both autogenous and exogenous processes including ecogeomorphic feedbacks and sediment supply from in‐land and coastal ocean. There have been numerous efforts to quantify the role played by the sediments coming from marsh edge erosion on the resistance of salt marshes to sea level rise. However, the majority of existing studies investigating the interplay between lateral and vertical dynamics use simplified modeling approaches, and they do not consider that marsh retreat can affect the regional‐scale hydrodynamics and sediment retention in back‐barrier basins. In this study, we evaluated the fate of the sediments originating from marsh lateral loss by using high‐resolution numerical model simulations of Jamaica Bay, a small lagoonal estuary located in New York City. Our findings show that up to 42% of the sediment released during marsh edge erosion deposits on the shallow areas of the basin and over the vegetated marsh platforms, contributing positively to the sediment budget of the remaining salt marshes. Furthermore, we demonstrate that with the present‐day sediment supply from the ocean, the system cannot keep pace with sea level rise even accounting for the sediment liberated in the bay through marsh degradation. Our study highlights the relevance of multiple sediment sources for the maintenance of the marsh complex. The sediment eroded from marsh edges helps to build the remaining marshesMarsh erosion has a twofold effect: more sediment available for the remaining marshes but decrease in the trapping capacity of the lagoonManagement actions should consider the effects associated with wetland edge erosion at basin scale

Salt marshes are dynamic systems able to laterally expand, contract, and vertically accrete in response to sea level rise. Here, we present the grand challenges that need to be addressed to fully characterize marsh morphodynamics. The review focuses on physical processes and quantitative models. Without predictive models, it is impossible to determine the future marsh evolution under accelerated sea level rise. In these models, one of the challenges is to resolve both horizontal and vertical dynamics within the same framework. Vertically, the marsh has to accumulate enough material to contrast rising water levels. Horizontally, marsh erosion at the ocean side must be compensated by landward expansion in forests, lawns, and agricultural fields. The dynamics of the marsh‐upland boundary are still not fully understood and will require more research in the upcoming years. The complexity of marsh vegetation is seldom captured in predictive models of marsh evolution. More research is needed to understand the effects of each species or species assemblages on hydrodynamics and sediment transport. Here, we further advocate that a sediment budget resolving all sediment fluxes in a marsh complex is the most important metric of marsh resilience. Characterization of these fluxes will enable to connect salt marshes to other landforms and to unravel feedbacks controlling the evolution of the entire coastal system. Current models of marsh evolution rely on sparse data sets collected at few locations. Novel remote sensing techniques will provide high‐resolution spatial data that will inform a new generation of computer models. Vertical and horizontal dynamics must be combined to understand salt marsh evolutionA sediment budget is the key variable to measure marsh resilience to sea level riseRemote sensing will provide spatial data sets to inform a new generation of numerical models of salt marsh evolution

Sediment budget and sediment availability are direct metrics for evaluating the resilience of coastal bays to sea‐level rise (SLR). Here we use a high‐resolution numerical model of a tidally dominated marsh‐lagoon system to explore feedbacks between SLR and sediment dynamics. SLR augments tidal prism and inundation depth, facilitating sediment deposition on the marsh platform. At the same time, our results indicate that SLR enhances ebb‐dominated currents and increases sediment resuspension, reducing the sediment‐trapping capacity of tidal flats and bays and leading to a negative sediment budget for the entire system. This bimodal distribution of sediments budget trajectories will have a profound impact on the morphology of coastal bays, increasing the difference in elevation between salt marshes and tidal flats and potentially affecting intertidal ecosystems. Our results also clearly indicate that landforms lower with respect to the tidal frame are more affected by SLR than salt marshes. SLR increases sediment deposition on the marsh platform but reduces the sediment‐trapping capacity of tidal flats and baysFor a given SLR the increase of bottom sediments resuspended and exported out of the system is more significant for sand than mud fractionLandforms lower with respect to the tidal frame are more affected by SLR than salt marshes