1. Amine modification over activated carbon for an effective removal of phosphate ions in water
- Author
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Samir, B., Bouazizi, N., Fotsing, P.N., Cosme, J., Marquis, V., Dotto, G.L., Le Derf, F., Pakade, V., and Vieillard, J.
- Abstract
AC-PEI(H) was prepared by chemically grafting polyethyleneimine (PEI) onto activated carbon (AC), followed by acidification and protonation of the amino groups, resulting in positively charged ammonium moieties. The resulting materials are used for the adsorption of phosphate ions (H2PO4−) from water. The effects of temperature, contact time, and concentration on phosphate ions removal from wastewater were investigated. The structure, surface morphology and chemistry of AC-PEI(H) were characterized by SEM, XPS, FTIR, DSC, and ZP. The optimum adsorption conditions of phosphates were the temperature (285 K), the time (4 h), the mass of the adsorbent (0.40 g), and the initial pH of 5. Results showed that the removal efficiency of phosphate in simulated wastewater was estimated at 63.9 %. In addition, the utilization of NaOH as a regenerant for the H2PO4−-laden AC-PEI(H) can still reach more than 47 %. The chemical adsorption mechanism was proposed, suggesting the key role of the interaction between the terminal amine at the adsorbent surface and the phosphate. Reportedly, our prepared green adsorbent AC-PEI(H) could be regarded as an efficient candidate for high removal of phosphate in water, which could be promoted to treat other anionic salts in sewage.
- Published
- 2024
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