1. Removal of Gold Particles from Chromium Oxynitride Surface with Dilute Sulfuric Acid Solutions
- Author
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Pandit, Viraj S., Keswani, Manish, Raghavan, Srini, Muralidharan, Krishna, Deymier, Pierre, Eshbach, Florence, Sengupta, Archita, and Yun, Henry
- Abstract
Removal of gold particles (100 nm) from chromium oxynitride surface (CrON) has been investigated using dilute sulfuric acid solutions. Two types of gold nano-particles, one with a negative surface charge and the other with a positive charge achieved by adsorption of poly diallyl-dimethyl ammonium chloride (PDAC), were used. Particle removal efficiency (PRE) increases with sulfuric acid concentration and bath temperature. In 1:10 H2SO4:DI solution, increasing the bath temperature from 25 to 100 {degree sign}C increases the PRE from 21 to 99 %. Introduction of megasonic energy at 0.43 W/cm2 in a 1:10 H2SO4:DI bath at 35 {degree sign}C increases the PRE to 88 %. PDAC coated gold particles are difficult to remove as compared to uncoated particles due to their electrostatic interaction with the surface leading to stronger adhesion.
- Published
- 2007