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Seven seawater polychlorinated biphenyls (PCBs) were measured in water (DAP), suspended particulate matter (SPM), and blue mussels (Mytilus edulis) collected from four beaches in northwest Portugal. PCBs were extracted using solid-phase-extraction, ultrasound-extraction and QuEChERS before GC–MS analysis. The two-year annual average concentrations of PCBs in DAP, SPM and the four-year analysis in mussels were ∼ 4.4 ng/L, ∼15.9 μg/kg, and ∼ 56.0 μg/kg. The results suggest higher concentrations of PCBs in summer for SPM and in spring for mussels, mainly those collected close to the Ave River estuary. The origins of PCBs remain uncertain. Risk assessment shows that PCBs in water are unlikely to harm local biota due to their low thyroid hormone toxicity equivalents (TEQ-TH; ∼1.4E-04 ng/L and ∼ 4.1E-04 μg/kg) and on WHO toxicity equivalents (TEQ-WHO; ∼2.1E-05 ng/L and ∼ 4.9E-05 μg/kg). However, the lifetime carcinogenic risk (LCR) for humans consuming local bivalves is concerning, as it exceeds 1.0E-06. [Display omitted] • 7 PCBs were quantified in water, particulate matter (2 years) and mussels (4 years) from the North Iberian seacoast. • All analysed matrices contained significant amounts of PCBs. • Toxic equivalents for PCBs in water point to low risks for local biota. • The Lifetime Carcinogenic Risk indicates that intake of local mussels poses cancer risks. [ABSTRACT FROM AUTHOR]

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As a case study, the estuary of the international Douro River (Iberian Peninsula) was sampled over a year (2010) at six sampling sites to determine the presence of 56 pesticides of different categories (insecticides, herbicides, and fungicides). 96% of measured pesticides were detected in 79% of the quantified samples. Individual average pesticide concentrations ranged from 39 to 1 265 ng/L, indicating a ubiquitous presence of the selected compounds; moreover, twelve pesticides were above the 2013/39/EU Directive limits. Due to its highly impacted profile, a theoretical hazard assessment was done considering the average and maximum environmental mixtures of all measured pesticides to identify the most sensitive trophic level. For both environmental mixtures, the theoretical approach suggested that invertebrates were the most sensitive group. Therefore, short-time exposure assays using both invertebrates Artemia salina and Daphnia magna, were done using the referred mixtures. Data demonstrated significant toxic effects ─ high mortality rate and abnormal swimming behaviour ─ of the exposed animals. Both approaches (theoretical and experimental) support the analytical results, alerting for an intervention on this estuarine environment and of other comparable. [ABSTRACT FROM AUTHOR]

The Ave basin (North Atlantic Ocean Ecoregion) is highly disturbed by anthropogenic activities. The amounts and distribution patterns of 56 priority pesticides (fungicides, herbicides, and insecticides) dissolved in the aqueous phase (DAP) and suspended particle matter (SPM) were evaluated seasonally along the river, estuary and coastline. Over 83 % of the GC–MS/MS-identified pesticides were quantified in DAP and 91 % in SPM. Pesticides' average annual amounts were ≅316 ng/L and 1.3 μg/g (fungicides), ≅272 ng/L and 2.2 μg/g (herbicides) and ≅1344 ng/L and 6.6 μg/g (insecticides). Invertebrates were the most vulnerable trophic level in the theoretical assessment of pesticide mixture hazards. This hypothesis was strengthened by acute in vivo assays using Artemia salina and Daphnia magna. These data, and the fact that 38 % of pesticides showed concentrations above the maximum established by the European legislation, plus the high concentrations of nitrates, nitrites, ammonia and phosphates, request further depollution actions in this region. [Display omitted] • More than 83% of the pesticides were quantified in water (≅2.0 µg/L) and suspended particles (≅10 µg/g). • 38% of the measured pesticides infringe the European Directives (98/83/EC and 2013/39/EU). • A two-tiered approach reflected a potential danger to aquatic life, particularly invertebrates. • Short-term in vivo assays point to insecticides as the primary hazardous pollutants of this habitat. [ABSTRACT FROM AUTHOR]

The Mondego River estuary, located on the North Atlantic Ocean Ecoregion, is a basin affected by agricultural run-off with increasing signs of eutrophication. We evaluated the amounts and distribution of 56 priority pesticides belonging to distinct categories (insecticides, herbicides and fungicides). Temporal trends were considered and a total of 42 surface water samples were collected between 2010 and 2011. More than 55% of the GC–MS/MS-quantified pesticides were above the maximum amounts established by the European Directives (98/83/EC and 2013/39/EU). Based on the concentration addition (CA) and independent action (IA) models, we used a two-tiered approach to assess the hazard of the pesticide mixture, at the maximum concentration found, reflecting a potential risk. Short-term exposure using Artemia salina indicated a significant toxic effect where the locomotion of the animals was clearly affected. [ABSTRACT FROM AUTHOR]

Anthropogenic activities can introduce polycyclic aromatic hydrocarbons (PAHs) in coastal waters. Here, 16 priority PAHs were quantified by gas chromatography-mass spectroscopy (GC–MS) in seawater samples from three Iberian Atlantic habitats. Results showed global concentrations of ≅9 ng/L in the aqueous phase (DAP) and ≅94 ng/g, dw in suspended particulate matter (SPM). The identified sources were both petrogenic and pyrogenic. Nonetheless, the application of several quantitative approaches, including Principal Component Analysis, point to distinct PAHs inputs amongst the sampling areas and demonstrate that sources in S 1 (fire forests/sea harbor) are different from those at S 2 and S 3 (oil refinery/sea harbor). The calculated carcinogenicity potential in both DAP and SPM was low for humans (high percentage of Group 3 PAHs). However, both toxic equivalent factors (TEQs) and environmental risks coefficients (RQs) reveal that the evaluated areas are not risk-free, as confirmed by the practical Artemia salina acute-test assay. [Display omitted] • Water from three Iberian Atlantic beaches were assessed as to 16 priority PAHs. • Dissolved aqueous phase (DAP) and suspended particulate matter (SPM) were studied. • Inputs varied amongst sampling sites, suggesting pyrogenic and petrogenic sources. • Toxic equivalents backed low PAHs carcinogenic risk for humans in both DAP and SPM. • Toxic Equivalent Factors and Risk Quotients reveal "low-risk" for the ecosystems. • Exposures to environmental levels of PAHs caused higher mortality of Artemia salina. [ABSTRACT FROM AUTHOR]