1. Tracing mercury pathways in Augusta Bay (southern Italy) by total concentration and isotope determination.
- Author
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Bonsignore, M., Tamburrino, S., Oliveri, E., Marchetti, A., Durante, C., Berni, A., Quinci, E., and Sprovieri, M.
- Subjects
MERCURY poisoning ,SEDIMENTS ,MERCURY isotopes ,PHOTOCHEMISTRY ,CHEMICAL reduction - Abstract
The mercury (Hg) pollution of sediments is the main carrier of Hg for the biota and, subsequently, for the local fish consumers in Augusta Bay area (SE Sicily, Italy), a coastal marine system affected by relevant sewage from an important chlor-alkali factory. This relationship was revealed by the determination of Mass Dependent (MDF) and Mass Independent Fractionation (MIF) of Hg isotopes in sediment, fish and human hair samples. Sediments showed MDF but no MIF, while fish showed MIF, possibly due to photochemical reduction in the water column and depending on the feeding habitat of the species. Benthic and demersal fish exhibited MDF similar to that of sediments in which anthropogenic Hg was deposited, while pelagic organisms evidenced higher MDF and MIF due to photoreduction. Human hair showed high values of δ 202 Hg (offset of +2.2‰ with respect to the consumed fish) and Δ 199 Hg, both associated to fish consumption. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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