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1. Solvent-mediated Tuning of the Regioselectivity of Intramolecular Diaryl Ether Formation: Total Synthesis of (+)-Aspercyclide C.

Author

Tatsuya Yoshino, Shuji Yamashita, Itaru Sato, Yujiro Hayashi, and Masahiro Hirama

Abstract

A concise total synthesis of the 11-membered cyclic (+)-aspercyclide C is reported. Key to success was the finetuning of the reaction media to realize an oxidative, macrocyclic diaryl C-O bond formation in a regioselective and direct fashion. [ABSTRACT FROM AUTHOR]

Published
2014
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