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Constructing composite structures is the key to breaking the dilemma of slow reaction kinetics and easy oxidation on the surface of lightly doped p-type silicon nanowire (SiNW) array photocathodes. Electrodeposition is a convenient and fast technique to prepare composite photocathodes. However, the low conductivity of SiNWs limits the application of the electrodeposition technique in constructing composite structures. Herein, SiNWs were loaded with Au nanoparticles by chemical deposition to decrease the interfacial charge transfer resistance and increase active sites for the electrodeposition. Subsequently, co-catalysts CoS, MoS2, and Ni3S2with excellent hydrogen evolution activity were successfully composited by electrodeposition on the surface of SiNWs/Au. The obtained core–shell structures exhibited excellent photoelectrochemical hydrogen evolution activity, which was contributed by the plasma property of Au and the abundant hydrogen evolution active sites of the co-catalysts. This work provided a simple and efficient solution for the preparation of lightly doped SiNW-based composite structures by electrodeposition.

The rhizosphere microbiome forms a first line of defense against soilborne pathogens. To date, most microbiome enhancement strategies have relied on bioaugmentation with antagonistic microorganisms that directly inhibit pathogens. Previous studies have shown that some root-associated bacteria are able to facilitate pathogen growth. We therefore hypothesized that inhibiting such pathogen helpers may help reduce pathogen densities. We examined tripartite interactions between a model pathogen, Ralstonia solanacearum, two model helper strains and a collection of 46 bacterial isolates recovered from the tomato rhizosphere. This system allowed us to examine the importance of direct (effects of rhizobacteria on pathogen growth) and indirect (effects of rhizobacteria on helper growth) pathways affecting pathogen growth. We found that the interaction between rhizosphere isolates and the helper strains was the major determinant of pathogen suppression both in vitro and in vivo. We therefore propose that controlling microbiome composition to prevent the growth of pathogen helpers may become part of sustainable strategies for pathogen control.

The rhizosphere microbiome forms a first line of defense against soilborne pathogens. To date, most microbiome enhancement strategies have relied on bioaugmentation with antagonistic microorganisms that directly inhibit pathogens. Previous studies have shown that some root-associated bacteria are able to facilitate pathogen growth. We therefore hypothesized that inhibiting such pathogen helpers may help reduce pathogen densities. We examined tripartite interactions between a model pathogen, Ralstonia solanacearum, two model helper strains and a collection of 46 bacterial isolates recovered from the tomato rhizosphere. This system allowed us to examine the importance of direct (effects of rhizobacteria on pathogen growth) and indirect (effects of rhizobacteria on helper growth) pathways affecting pathogen growth. We found that the interaction between rhizosphere isolates and the helper strains was the major determinant of pathogen suppression both in vitro and in vivo. We therefore propose that controlling microbiome composition to prevent the growth of pathogen helpers may become part of sustainable strategies for pathogen control.

In recent years, increasing attention has been paid to photoelectrochemical (PEC) hydrogen production owing to the utilization of sustainable solar energy and its promising performance. Silicon-based composites are generally considered ideal materials for PEC hydrogen production. However, slow reaction kinetics and poor stability are still key factors hindering the development of silicon-based photoelectrocatalysts. Herein, we present an n+-p Si pyramidal photocathode assembly method to load reduced graphene oxide (rGO) onto the surface of the n+-p Si pyramid by covalently linking (Si/rGO). rGO is utilized as a conductive layer to reduce the interfacial charge-transfer resistance. Then, MoS2can be successfully electrodeposited on the surface of Si/rGO to form the Si/rGO/MoS2composite, which possesses excellent PEC hydrogen evolution performance with a high and stable photocurrent of −41.6 mA cm–2and a hydrogen evolution rate of about 18.1 μmol min–1cm–2under 0 V (vs RHE). The covalently linking rGO layer effectively enhances the transfer of photogenerated carriers between the Si substrate and MoS2. MoS2provides abundant hydrogen evolution active sites, which accelerate the surface reaction kinetics, as well as a protective layer for the Si pyramidal array structure. This work provides a low-cost, convenient, and efficient way of preparing silicon-based photocathodes.

•Straw cellulose (SC) decorated CeO2nanocomposite was prepared via a hydrothermal method.•TEM images display carbon nanotube-like SC has grown on the surface of CeO2.•The SC-CeO2nanocomposite has good visible light photocatalytic activity on reduction of aqueous Cr(VI).