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In the development of on-line monitoring technique for transformer aging status, detecting concentration of methanol dissolved in transformer oil by the method of surface enhanced Raman spectroscopy (SERS) is a novel and promising technique. By use of Raman spectroscopy technique, we can improve various shortcomings of traditional detection technology. In this paper, the concentration of methanol dissolved in 2 mL/L methanol-oil solution was effectively detected by surface enhanced Raman spectroscopy. In the first, Raman spectra of single methanol molecule and its SERS were simulated to analyze the Raman peaks of methanol. A SERS substrate was prepared with selective enhancement. Based on prepared SERS substrate, concentration of methanol dissolved in transformer oil with content of 2 mL/L have been effectively detected. This helped us to further study the lower concentration of methanol in oil and make quantitative analysis.

How to accurately detect the concentration of furfural in transformer oil plays an important role in the analysis of the aging state of the transformer. As a fast and non-destructive detection method, Raman spectroscopy is the key to improving the sensitivity of Raman detection. In this paper, based on the extraction technique, the deionized water and methanol are used as extractants to carry out the comparative experiment of furfural Raman spectroscopy in oil. Firstly, the deionized water and methanol extract of furfural in oil are prepared and obtained. The Raman characteristic peaks of furfural are 1372 cm-1 and 1411 cm-1 and 1675 cm-1 by Raman detection, and qualitative analysis is discussed. The experimental results show that deionized water as an extractant has certain feasibility for Raman detection, and it has the lower limit of detection for Raman detection compared with methanol as extractant, which makes a certain contribution in order to improve the sensitivity of furfural Raman detection in transformer oil.