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The Ahdeb oil field is located in the Mesopotamian Basin of central Iraq within a northwest–southeast-trending anticline. Seven oil-bearing layers exist in the eastern area in the field, but there is only one oil-bearing layer in the western area. This study reveals that the reservoir filling process resulted from the difference in the elements in the petroleum system, the oil generation and migration process, and the formation of the structural trap. Most oils in the field, with pristane/phytane < 1 and a high relative abundance of hopanes exceeding C30, were generated from the Upper Jurassic–Lower Cretaceous Chia Gara Formation, whereas some oils were generated from the Lower Cretaceous Ratawi and Zubair Formations. The mid-Upper Cretaceous reservoirs in the field are composed of lime grainstones, packstones, and wackestones. The main oil accumulation occurred during the Maastrichtian, coinciding with peak oil generation from the Chia Gara Formation with a 50% transformation ratio from organic matter to oil. The reservoirs of the eastern structural trap in the field were filled with large amounts of medium to heavy oils. After the formation of two structural traps in the western area in the mid-Miocene, oils pre-existing in the second layer of the Khasib Formation in the east began migrating toward the structural traps in the west during the late Miocene, as verified by relatively higher 1-/4-methylcarbazole and 1,8-/2,7-dimethycarbazole ratios of oils in the west than that in the east and residual solid bitumen in the east. The strike-slip fault might also have restricted oil or gas migration during the Miocene, limiting oil accumulation in the west.

Feldspar dissolution, quartz cementation, and clay cementation are significant diagenetic processes in deep-water fan feldspar-rich sandstones in the Shengtuo area, Dongying sag (East China). The timing and origin of these water–rock interactions as well as the paleofluids in which relevant chemical reactions occurred were deduced using data from microscopy, fluid-inclusion microthermometry, oxygen-isotope microanalysis, and trace-element microanalysis. Three distinct, separate episodes of quartz overgrowths (referred to as Q1, Q2, and Q3) were distinguished by cathodoluminescence microscopy. The Q1 quartz, identified in all porous sandstones from 2500 to 3600 m (8200 to 11,800 ft), was formed at approximately 100°C–115°C (212°F–239°F) before oil filled the reservoirs. The Q2 quartz was mainly precipitated at 115°C–130°C (239°F–275°F), accompanying or slightly postdating the main phase of oil filling, and was identified in samples from 2800 to 3600 m (9200 to 11,800 ft). The Q3 quartz was only identified in sandstones buried deeper than 3500 m (11,400 ft) and was likely precipitated in the Quaternary when temperature exceeded 130°C–135°C (266°F–275°F). Secondary ion mass spectrometry oxygen-isotope microanalyses yielded δ18OVSMOW (Vienna standard mean ocean water) values ranging from 21.42‰ to 24.35‰ for Q1 quartz, from 22.03‰ to 24.99‰ for Q2 quartz, and from 21.72‰ to 22.91‰ for Q3 quartz. A mass-balance calculation and quantitative petrography data of the amount of leached feldspars and associated secondary minerals suggest that the internal feldspar dissolution is likely the primary source for the authigenic clays and quartz cements in these sandstones. Positive δ18O(water) values (+0.5‰ to +4.5‰ VSMOW) of quartz-forming waters indicate that quartz cementation and feldspar dissolution occurred in a geochemical system with a limited volume of diagenetically modified connate water. The variations of δ18O(cements) and trace-element compositions from Q1 quartz to Q2 quartz in individual overgrowth suggest that hydrocarbon filling changed the chemistry of the pore fluid significantly; further, δ18O(water) values of the pore water increased by approximately 2‰ VSMOW after oil filling. Meteoric freshwater did not contribute to quartz cementation and simultaneous feldspar dissolution. The detected CO2 and hydrocarbons in fluid inclusions in the quartz cements, the existence of CO2 in hydrocarbon-rich natural gas, and the pyrobitumen in the feldspar-hosted pores suggest that acids derived from organic matter (kerogen in source rocks and hydrocarbons in reservoirs) probably have promoted the extensive subsurface leaching reactions of feldspars in these sandstones. The ongoing development of Q2 and Q3 quartz suggests that quartz precipitation did not cease after oil filling. Further, diagenetic reactions likely have proceeded from water–rock interactions to hydrocarbon–water–rock interactions.

Feldspar dissolution and precipitation of clays and quartz cements are important diagenetic reactions affecting reservoir quality evolution in sandstones with detrital feldspars. We examined two sets of sandstone reservoirs to determine whether the sandstone diagenetic systems were open or closed to the mass transfer of products from feldspar dissolution and its impact on reservoir quality. One of the reservoirs is the Eocene fan delta sandstone buried 2.5–4.0 km (1.5–2.5 mi) below sea level (BSL) in the Gaoliu (GL) area of the Nanpu sag, and the other is the Eocene subaqueous fan sandstone buried 1.5–4.5 km (1–2.8 mi) BSL in the Shengtuo (ST) area of the Dongying sag. Both sandstones consist mainly of lithic arkoses and feldspathic litharenites, and have secondary porosity formed by dissolution of feldspars. In the GL sandstones, the absolute amounts of authigenic clays and quartz cements (generally 125°C [257°F]). The low abundance of authigenic clays and quartz cements, and low pore-water salinity indicate that much of the , , and released from leached K-feldspars were exported from the GL sandstone system. And the extensive feldspar dissolution enhanced much porosity and permeability. In contrast, the ST sandstones with secondary pores formed by feldspar dissolution generally contain authigenic clays (kaolinite and illite) and quartz cements with almost identical volume of secondary pores. Kaolinite dominates in the ST sandstones at shallower depth (3.1 km [2 mi] BSL) where temperature exceeds 125°C (257°F). The presence of abundant clays and quartz cements indicates that and released from leached feldspars were retained in the ST sandstone system. The dominance of authigenic illite at greater depth indicates that sufficient should have been retained within the sandstones for occurrence of illitization of kaolinite and feldspars. Secondary porosity in thin sections can be up to 3%, but little porosity ( The diagenetic difference between the GL and the ST sandstones can be interpreted by assessing pore-water evolution in these two areas. The current pore waters with low salinity and negative hydrogen isotopic compositions in the GL sandstone system indicate the significant impact of meteoric water, whereas the current pore waters with high salinity and the paleofluids with positive oxygen isotopic compositions in the ST sandstone system indicate little trace of meteoric water. Access of meteoric freshwater to the GL area probably occurred during the late Oligocene to Neogene through widely developed faults in the Paleogene and Neogene strata. The low-salinity water could have been responsible for flushing of solutes derived from feldspar dissolution. As such, diagenesis in the GL sandstones is considered to have occurred in an open geochemical system, whereas with limited faults and high water salinity, the ST sandstones acted as a closed geochemical system where precipitation of kaolinite, illite, and quartz cements occurred following dissolution of feldspars.

In this paper we describe K-Ar radiometric ages and oxygen isotope ratio measurements of illite cements from eolian sandstone samples of the Permian lower Leman Sandstone Formation (Rotliegendes Group). The samples come from a large (about 100 × 100 km) part of the Southern North Sea basin (Village Fields area) and from a range of burial depths (2.8-3.4 km subsea bed). Mean illite ages in the gas fields of Ravenspurn North (164 Ma ± 20.1 [2^sgr], n = 11), Hyde (161 Ma ± 12.3, n = 7), Cleeton (155Ma ± 20.2, n = 3), and Hoton (152 Ma ± 14.0, n = 14) fields, and in two wells located in Block 47/5A (162 Ma ± 16.1, n = 4) are all in the Middle to Late Jurassic, apart from two Early Cretaceous ages considered to represent unreliable analyses. The m an for all ages is 158 Ma ± 18.6 [2^sgr], n = 39. We largely avoided contamination with (old) detrital K-bearing minerals by careful sample selection and monitoring. To a first approximation, the assumptions of K-Ar dating appear to be fulfilled, so the measured ages are likely to date illite cement precipitation. Oxygen isotope ratios measured on the dated illite samples show small but significant variations among fields and a weak correlation with depth during the Middle Jurassic when illite grew. Both K-Ar dating and oxygen isotope ratios are compatible with a regional Middle to Late Jurassic phase of illite growth during which the mineral precipitated over a large area and over a range of temperatures governed by the depth of the formation at that time. The age of illite cementa ion coincides with rifting, which ultimately may have caused illite growth by driving pore-water flow.