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Start Over Descriptor "Bromides -- Chemical properties" Journal accounts of chemical research
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1. Catalytic enantioselective conjugate addition with Grignard reagents

Author

Lopez, Fernando, Minnaard, Adriaan J., and Feringa, Ben L.

Subjects
Allylic compounds -- Structure, Allylic compounds -- Chemical properties, Bromides -- Structure, Bromides -- Chemical properties, Catalysis -- Analysis, Grignard reagents -- Chemical properties, Chemistry, Science and technology
Abstract

The advances in catalytic asymmetric conjugate addition of Grignard reagents are presented and the scope of the technique is described. The mechanistic study of the catalytic process and the application of the catalytic system to the enantioselective [S.sub.N] 2' substitution reactions of allylic bromides with Grignard reagents are presented.

Published
2007

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