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Hydrogen-based energy systems hold promise for sustainable development and carbon neutrality, minimizing environmental impact with electrolysis as the preferred fossil-fuel-free hydrogen generation method. Effective electrocatalysts are required to reduce energy consumption and improve kinetics, given the need for additional voltage (overpotential, η) despite the theoretical water splitting potential of 1.23 V. To date, platinum has been acknowledged as the most effective but expensive hydrogen evolution reaction (HER) catalyst. Hence, we introduce a cost-effective (∼2-fold cheaper) ruthenium-modified tungsten diphosphide (Ru/WP 2 ) catalyst on carbon fiber for HER in ∼0.5 M H 2 SO 4 , with η ≈ 34 mV at -10 mA cm -2 which can be comparable (only ∼2-fold higher) to benchmark Pt/C (η ≈ 17 mV). The HER performance of WP 2 can be enhanced through the modification of ruthenium, as indicated by the electrochemical characterizations. Considering the Tafel value of ∼40 ± 0.2 mV dec -1 , it can be inferred that Ru/WP 2 follows the Volmer-Heyrovsky reaction pathway for hydrogen generation. Furthermore, the Faradaic efficiency estimation indicates that Ru/WP 2 demonstrates a minimal loss of electrons during the electrochemical reaction with an estimated value of ∼98.7 ± 1.4%. Therefore, this study could emphasize the potential of the Ru/WP 2 electrode in advancing sustainable hydrogen production through water splitting.

Photocatalytic N 2 fixation is a complex reaction, thereby prompting researchers to design and analyze highly efficient materials. Herein, one-pot hydrothermal Bi 2 WO 6 -BiOCl (BW-BiOCl) heterojunctions were synthesized by varying the molar ratio of tungsten: chlorine precursor. Major morphological transformations in BiOCl were observed wherein it turned from thick sheets ∼230 nm in pure BiOCl to ∼30 nm in BW-BiOCl. This was accompanied by extensive growth of {001} facets verified from X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM) analyses. A p-n heterojunction was formed between Bi 2 WO 6 and BiOCl evidenced via photoluminescence (PL), time-resolved photoluminescence (TRPL), photocurrent response, and electrochemical impedance spectroscopy (EIS) analyses. The formation of heterojunction between Bi 2 WO 6 and BiOCl led to the reduction of the work function in the BW-BiOCl 0.25 hybrid confirmed via ultraviolet photoelectron spectroscopy (UPS) analysis. BW-BiOCl 0.25 could produce ammonia up to 345.1 μmol·L -1 ·h -1 owing to the formation of a robust heterojunction with an S-scheme carrier transport mechanism. Recycle tests resulted in no loss in N 2 reduction activities with post-catalytic analysis, showcasing the high stability of the synthesized heterojunction. Novel performance was owed to its excellent chemisorption of N 2 gas on the heterojunction surface verified by N 2 -temperature programmed desorption (TPD). BW-BiOCl 0.25 also displayed a superior rate constant of 3.03 × 10 -2 min -1 for 90 min CIP degradation time, higher than pristine BiOCl and Bi 2 WO 6 . Post-photocatalytic Fourier transform infrared (FTIR) spectroscopy of BW-BiOCl 0.25 revealed the presence of C-H stretching peaks in the range of 2850-2960 cm -1 due to adsorbed CIP and methanol species in CIP degradation and N 2 fixation, respectively. This also confirmed the enhanced adsorption of reacting species onto the heterojunction surface.