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Lead halide perovskites have been extensively studied for their potential applications, including photodetectors, solar cells, and high-energy radiation detection. These applications are possible because of their unique optoelectronic properties, such as tunable band gap, high optical absorption coefficient, and unique defect self-healing properties, which result in high defect tolerance. Despite these advantages, the long-term stability remains a critical issue that could hinder commercial applications of these materials. Reports on the stability of lead halide perovskites for optoelectronic applications have normally focused on methylammonium (MA)/formamidinium (FA), with very limited information for other systems, in particular, Cs-containing perovskites. In this paper, we report the stability of thick CsPbBr 3- x Cl x polycrystalline thin films (∼8 μm) with several halide Br-Cl ratios after exposure to deep UV radiation. The chemical, crystal structure, optical, and electrical properties are analyzed, and the results are used to propose a degradation mechanism. The chemical analysis on the surface and bulk of the films indicates the formation of cesium oxide after UV exposure, with no significant change in the crystalline structure. The proposed mechanism explains the formation of cesium oxides during UV exposure. The I - V characteristics of diode structures also showed significant degradation after UV exposure, primarily at lower diode rectification ratios. The mechanism proposed in this paper can contribute to developing strategies to enhance the long-term stability of inorganic lead halide perovskites under UV exposure., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)

Gold nanoparticles (AuNPs) are commonly synthesized using the citrate reduction method, reducing Au 3+ into Au 1+ ions and facilitating the disproportionation of aurous species to Au atoms (Au 0 ). This method results on citrate-capped AuNPs with valence single states Au 0 . Here, we report a methodology that allows obtaining AuNPs by the dewetting process with three different valence states (Au 3+ , Au 1+ , and Au 0 ), which can be fine-tuned with ion bombardment. The chemical surface changes and binding state of the NPs were investigated using core-level X-ray photoelectron spectroscopy (XPS). This is achieved by recording high-resolution Au 4f XPS spectra as a function of ion dose exposure. The results obtained show a time-dependent tuning effect on the Au valence states using low-energy 200 V acceleration voltage Ar + ion bombardment, and the valence state conversion kinetics involves the reduction from Au 3+ and Au 1+ to Au 0 . Proper control of the reduction in the valence states is critical in surface engineering for controlling catalytic reactions., Competing Interests: The authors declare no competing financial interest., (© 2022 The Authors. Published by American Chemical Society.)

Heavy metal pollution is posing a severe health risk on living organisms. Therefore, significant research efforts are focused on their detection. Here, we developed a sensing platform sensor for the selective detection of lead(II) acetate. The sensor is based on self-assembled polyethyleneimine-functionalized carbon nanotubes (PEI-CNTs) and graphene oxide films deposited onto gold interdigitated electrodes. The graphene-based nanostructure showed a resistive behavior, and the fabricated layer-by-layer film was used to detect Pb(II) acetate in an aqueous solution by comparison of three electrochemical methods: impedance spectroscopy, amperometry, and potentiometry stripping analysis. The results obtained from different methods show that the detection limit was down to 36 pmol/L and the sensitivity up to 4.3 μAL/μmol, with excellent repeatability. The detection mechanism was associated with the high affinity of heavy metal ions with the functional groups present in the PEI-CNTs and GO, allowing high performance and sensitivity. The achieved results are important for the research toward integrated monitoring and sensing platforms for Pb(II) contamination in drinking water., Competing Interests: The authors declare no competing financial interest., (© 2021 The Authors. Published by American Chemical Society.)