1. Equilibrium langbeinite-related phosphates Cs1 + xLn xZr2 − x(PO4)3 (Ln = Sm–Lu) in the melted systems Cs2O–P2O5–LnF3–ZrF4
- Author
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Ogorodnyk, Ivan V., Baumer, Vyacheslav N., Zatovsky, Igor V., Slobodyanik, Nikolay S., Shishkin, Oleg V., and Domasevitch, Konstantin V.
- Subjects
PHOSPHATES ,CRYSTALLIZATION ,CESIUM ,ZIRCONIUM ,RARE earth metals ,CHEMICAL structure ,OPTICAL diffraction - Abstract
Nine novel phosphates, based upon a combination of caesium, zirconium and lanthanide ions, were obtained from fluoride-containing fluxes using high-temperature crystallization. The structures of Cs
1.80 Eu0.80 Zr1.20 (PO4 )3 (CsEuZrP), Cs1.79 Gd0.79 Zr1.21 (PO4 )3 (CsGdZrP), Cs1.87 Tb0.87 Zr1.13 (PO4 )3 (CsTbZrP), Cs1.67 Dy0.67 Zr1.33 (PO4 )3 (CsDyZrP), Cs1.75 Ho0.75 Zr1.25 (PO4 )3 (CsHoZrP), Cs1.78 Er0.78 Zr1.22 (PO4 )3 (CsErZrP), Cs1.70 Tm0.70 Zr1.30 (PO4 )3 (CsTmZrP), Cs1.52 Yb0.52 Zr1.48 (PO4 )3 (CsYbZrP) and Cs1.63 Lu0.63 Zr1.37 (PO4 )3 (CsLuZrP) were solved using single-crystal X-ray diffraction. All compounds are isostructural to the mineral langbeinite (cubic system, space group P21 3). Their framework structures originate from the cross-linking of metal octahedra [ MO6 ] ( M = Zr, Ln) by phosphate tetrahedra. Cs+ cations are located in the closed cavities of the framework and preferentially occupy one of the two available sites. The principles of crystallization of the equilibrium langbeinite-related phosphates in the fluxes of the system Cs2 O–P2 O5 –LnF3 –ZrF4 (Ln = La–Nd, Sm–Lu) are discussed based on their crystal structures. [ABSTRACT FROM AUTHOR]- Published
- 2007
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