1. The titanium-thiolate complex [Li(C4H8O)4][Ti2(SC6H5)9].
- Author
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Puke, Carsten, Schmengler, Kai, Kirschbaum, Kristin, Conrad, Olaf, and Giolando, Dean M.
- Abstract
In the title compound, tetrakis(tetrahydrofuran)lithium(I) tri-μ-phenylthiolato-bis[tris(phenylthiolato)titanate(IV)], [Li(C
4 H8 O)4 ][Ti2 (C6 H5 S)9 ], (I), the central structural motif of the [Ti2 (SC6 H5 )9 ]− anion features a face-sharing bi-octahedron. The charge is balanced with a [Li(C4 H8 O)4 ]+ cation. The asymmetric unit contains Ti, Li and a heavily disordered tetrahydrofuran molecule on a threefold axis, and two terminal and a bridging thiophenolate moiety and a slightly disordered tetrahydrofuran molecule on general positions. [ABSTRACT FROM AUTHOR]- Published
- 2000
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