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1. Diaquadiperchlorato[μ-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]hexacosa-1(25),2,7,9,11,13(26),14,19,21,23-decaene-25,26-diolato-1κ2 N, N′;2κ2 N′′, N′′′;1:2κ2 O: O′]dicadmium(II) diaqua[μ-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]hexacosa-1(25),2,7,9,11,13(26),14,19,21,23-decaene-25,26-diolato-1κ2 N, N′;2κ2 N′′, N′′′;1:2κ2 O: O′]dicadmium(II) diperchlorate

Author

Bo Liu, Hong Zhou, Zhi-Quan Pan, Xue-Lei Hu, and Lei Chen

Subjects
*PERCHLORATES, *COORDINATION compounds, *MOLECULAR association, *CHEMICAL structure, *PHYSICAL & theoretical chemistry
Abstract

In the title complex, [Cd2(C24H26N4O2)(ClO4)2(H2O)2][Cd2(C24H26N4O2)(H2O)2](ClO4)2, the two distinct macrocycles adopt essentially flat structures. They each encapsulate two Cd atoms. One Cd coordination polyhedron, completed by a water O atom and a perchlorate O atom, is distorted octa­hedral, while the other is best described as a CdN2O3 square-based pyramid, with water in the apical site. Both dinuclear complexes are centrosymmetric. [ABSTRACT FROM AUTHOR]

Published
2005
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