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The title compound, [Bi(C3H5OS2)3(C12H8N2)] [systematic name: tris(ethoxymethanedithioato-κ2 S, S′)(1,10-phenanthroline)bismuth(III)], is monomeric, with the Bi atom chelated by the S atoms of three ethylxanthate ligands and the N atoms of 1,10-phenanthroline. The central BiIII atom is eight-coordinate and adopts a distorted capped-pentagonal–bipyramidal geometry. In the crystal structure, weak C—H...S interactions and a close S...S contact stabilize the structure [S...S = 3.509 (3) Å]. [ABSTRACT FROM AUTHOR]

In the title compound, [Sb(C5H8NS2)2Cl], the SbIII ion is coordinated by the four S atoms belonging to two pyrrolidine- 1-dithiocarboxylate ligands and a Cl atom in a distorted trigonal-bipyramidal geometry. The crystal structure is stabilized by intermolecular Sb⋯S interactions of 3.689 (1) Å. [ABSTRACT FROM AUTHOR]