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The title compound, {[Zn(C8H4O5)(C10H8N2)]·H2O}n , was synthesized by reacting Zn(NO3)2, 5-hydroxyisophthalic acid and 2,2′-bipyridine under hydrothermal conditions. Self-assembly between the bridging ligands, chelating ligands and metal ions results in a one-dimensional coordination polymer, in which the ZnII atom is six-coordinate and shows a [ZnN2O4] octahedral geometry. The ribbons are interconnected by an extensive network of hydrogen bonds involving the water molecule, the hydroxyl group and the carboxylate O atoms, forming a two-dimensional layer. These layers are connected through π-π interactions between the pyridyl rings [centroid-to-centroid distance 3.57 (1) Å]. [ABSTRACT FROM AUTHOR]

The title complex, {[Co(4,4′-bipy)(H2O)4](CCA)·2H2O} n (where bipy is bi­pyridine, C10H8N2, and CCA2− is 2-carboxyl­atocinnamate, C10H6O4), is a linear polymer constructed from cobalt and 4,4′-bipy, and which contains uncoordinated CCA2− counter-ions. There are two independent formula units in the asymmetric unit. O—H⋯O hydrogen bonds connect the structure into a three-dimensional network. [ABSTRACT FROM AUTHOR]

The title compound, [Bi(C4H8NS2)2(NO3)(C10H8N2)], is monomeric, with the Bi atom chelated by the S atoms of two pyrrolidine-1-dithiocarboxylate ligands and the N atoms of a 2,2′-bipyridine ligand. A nitrate ligand completes the coordination, with the eight-coordinated Bi atom adopting a highly distorted capped pentagonal–bipyramidal geometry. [ABSTRACT FROM AUTHOR]

The title compound, [Bi(C3H5OS2)3(C12H8N2)] [systematic name: tris(ethoxymethanedithioato-κ2 S, S′)(1,10-phenanthroline)bismuth(III)], is monomeric, with the Bi atom chelated by the S atoms of three ethylxanthate ligands and the N atoms of 1,10-phenanthroline. The central BiIII atom is eight-coordinate and adopts a distorted capped-pentagonal–bipyramidal geometry. In the crystal structure, weak C—H...S interactions and a close S...S contact stabilize the structure [S...S = 3.509 (3) Å]. [ABSTRACT FROM AUTHOR]

The crystal structure of the title complex, (C10H10N2)2[BiBr10] or (bipyH2)2[Bi2Br10], where bipyH2 is 4,4′-bipyridinium, is built of bipyH2 dications and deca­bromo­dibismuthate tetra­anions; the latter occupy special positions at inversion centres. The Bi atom in the anion has a distorted octa­hedral environment. N—H⋯Br hydrogen bonds link the ions into infinite chains running along the [1 ] direction. [ABSTRACT FROM AUTHOR]

The crystal structure of the title compound, (C4H10NO)2[Bi(C5H8NOS2)I4], the BiIII complex anions and morpholinium cations. The BiIII ion is coordinated by four I− anions and two S atoms from a morpholine-4-carbodithio­ate (mcda) dianion with a distorted octa­hedral coordination geometry. In the anion, Bi, the CS2 atoms, N, O and two I atoms are located on a mirror plane; the morpholine C atoms of the mcda ligand are disordered on both sides of the mirror plane. N—H⋯I hydrogen bonding between the morpholinium cation and the BiIII complex stabilize the crystal structure. [ABSTRACT FROM AUTHOR]

The title compound, [Bi(C5H10NS2)2I(C12H8N2)], is monomeric, with the Bi atom chelated by the S atoms of two N, N-diethyl­dithio­carbamate ligands and the N atoms of 1,10-phenanthroline. An iodo ligand completes the coordination, with the seven-coordinate Bi atom adopting a highly distorted capped octa­hedral geometry. [ABSTRACT FROM AUTHOR]

A new three-dimensional coordination polymer, [Dy2(C4H4O4)(C8H4O4)2] n, has been synthesized under hydro­thermal conditions. The coordination of the Dy atoms is distorted square anti­prismatic. The anti­prisms are bridged by the 1,4-benzene­dicarboxyl­ate and succinate ligands, forming a three-dimensional network. The succinate ion is located on an inversion center. [ABSTRACT FROM AUTHOR]

The asymmetric unit of the title complex, [Bi(C10H9-N2O4)2Cl]·5H2O, contains the BiIII complex and five solvent water molecules. The Bi atom is chelated by four O atoms and two N atoms of two (E)-2-{(Z)-[(4-hydroxyphenyl)oxidomethylene] hydrazono}propanoate ligands. A chloride anion completes the coordination environment, with the sevencoordinate Bi atom adopting a distorted capped octahedral geometry. The molecules are connected by extensive O—H⋯O hydrogen-bonding interactions involving the solvent water molecules into a two-dimensional supramolecular network. One water molecule is disordered over two sites with almost equal occupancy factors. [ABSTRACT FROM AUTHOR]

In the title compound, [Sb(C5H8NS2)2Cl], the SbIII ion is coordinated by the four S atoms belonging to two pyrrolidine- 1-dithiocarboxylate ligands and a Cl atom in a distorted trigonal-bipyramidal geometry. The crystal structure is stabilized by intermolecular Sb⋯S interactions of 3.689 (1) Å. [ABSTRACT FROM AUTHOR]

The title compound, [Nd2(C4H4O4)(C8H4O4)2] n, was synthesized by hydro­thermal synthesis. The Nd atom is coordinated by four O atoms from four 1,4-benzene­dicarboxyl­ate ligands and four O atoms from three succinate anions, in a distorted square-anti­prismatic coordination geometry. The anti­prisms are bridged by the 1,4-benzene­dicarboxyl­ate and succinate ligands, forming a three-dimensional network. The succinate ion is located on a centre of inversion. [ABSTRACT FROM AUTHOR]