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1. catena-Poly[[[(pyrazino[2,3- f][1,10]phenanthroline)copper(II)]-μ-4,4′-oxydibenzoato] monohydrate].

Author

Chun-Bo Liu, Yang Liu, Lu Lu, and Sun, Jun

Subjects
*ATOMS, *HYDROGEN bonding, *MOLECULAR association, *SUPRAMOLECULAR chemistry, *CHEMICAL structure, *PHYSICAL & theoretical chemistry
Abstract

In the title compound, {[Cu(C14H8O5)(C14H8N4)]·H2O} n, the CuII atom adopts a distorted cis-CuN2O2 square-planar coordination geometry. 4,4′-Oxydibenzoate ( L) ligands link the CuII atoms, generating a helical chain. Neighbouring chains are linked through π–π interactions between pyrazino[2,3- f][1,10]phenanthroline ligands with a centroid–centroid distance of ca 3.44 Å, resulting in a two-dimensional supramolecular structure. The structure is completed by O—H...O hydrogen bonds. [ABSTRACT FROM AUTHOR]

Published
2007
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