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1. Bis[(diphenyl­phosphino)acetato-κ2 O, P]palladium(II) dichloro­methane solvate.

Author

Meng-Ping Guo, Fang-Fang Jian, Ren He, and Hai-Lian Xiao

Subjects
*ORGANIC compounds, *RING formation (Chemistry), *ATOMS, *HYDROGEN-ion concentration, *PHYSICAL & theoretical chemistry, *CHEMISTRY
Abstract

The title compound, [Pd(C14H12O2P)2]·CH2Cl2, consists of mononuclear [(Ph2PCH2COO)2Pd] complexes and dichloro­methane mol­ecules in a 1:1 molar ratio. The two (diphenyl­phosphino)acetate ligands are coordinated to the central Pd atom by their P and O atoms, forming five-membered chelate rings. The PdII atom has a distorted square-planar configuration [Pd—O = 2.076 (3) and 2.082 (3) Å, and Pd—P = 2.214 (1) and 2.216 (1) Å]. [ABSTRACT FROM AUTHOR]

Published
2005
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