1. (E)-7-[(3-Chlorocinnamoyl)oxy]-4-methylcoumarin.
- Author
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Yang, Shu-Ping, Han, Li-Jun, Wang, Da-Qi, and Xia, Hai-Tao
- Subjects
- *
COUMARINS , *BENZENE , *BENZOPYRANS , *HYDROGEN bonding , *ORGANIC chemistry , *MOLECULAR crystals - Abstract
In the title compound {systematic name: 4-methyl-2-oxo-2 H-1-benzopyran-7-yl 3-(3-chlorophenyl)prop-2-enoate}, C19H13ClO4, the molecules have an E configuration and the dihedral angle between the coumarin unit and the benzene ring of cinnamoyloxy is 49.0 (1)°. The molecules are linked by C—H⋯O and C—H⋯Cl hydrogen bonds into a [101] ribbon of alternating R22(14) rings. The molecules are linked by weak intermolecular C—H⋯O interactions into a C22(12) [001] chain and a C22(14) [ 01] chain. The combination of the [101] ribbons, the [001] chains and the [ 01] chains results in the formation of a three-dimensional network structure. [ABSTRACT FROM AUTHOR]
- Published
- 2006
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