1. ( E, E)-4,4′-Dichloro-2,2′-(1,1′-azinodimethylene)diphenol.
- Author
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Jian-Guo Chang, Guo-Fang He, and Yan-Fei Li
- Subjects
- *
SYMMETRY (Biology) , *MOLECULES , *CHEMICAL templates , *PHYSICAL & theoretical chemistry , *ORGANIC chemistry , *AROMATIC compounds , *ORGANIC cyclic compounds , *ORGANIC compounds - Abstract
The title compound, C16H14Cl2N2O2, was synthesized by the reaction of 1-(5-chloro-2-hydroxyphenyl)ethanone with hydrazine hydrate. The molecule sits on a crystallographic center of symmetry at the mid-point of the central N—N bond and both N atoms are acceptors in an intramolecular hydrogen bond. In the crystal structure, the planar molecules are arranged in a sheet-like motif with one C—H...O bond linking molecules within the sheets and a second C—H...O interaction between neighboring sheets. There is also a close Cl...Cl intermolecular approach of 3.54 (1) Å within the sheets. [ABSTRACT FROM AUTHOR]
- Published
- 2007
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