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The article presents information on the structure of (1,4- Diazacycloheptane-κ2N,N')(2-thioxo-1,3-dithiole-4,5-dithiolato-κ2S4,S5)nickel(II). The molecular structure consists of a central Ni atom. The atom is coplanar with the two S atoms of one dmit ligand. Sulphur-sulphur bond and hydrogen bonds generate a three-dimensional framework of the coordination compound. and two N atoms of one dach ligand. This type of transition metal complexes with bis-ligands are known for their semiconducting, conducting, and even superconducting properties

The Zn atom in the title compound, [Zn(NCS)2(C13H20N2O2)]·CHCl3, is coordinated by two N atoms of two isothio­cyanate ligands, and an O and an imine N atom from the neutral Schiff base ligand 2-[3-(dimethyl­ammonio)propyl­imino­meth­yl]-6-methoxy­phenolate, in a distorted tetra­hedral geometry. [ABSTRACT FROM AUTHOR]

Cocrystallization of 2-hydroxy­benzothia­zole and 2-mercapto­benzothia­zole gives the title complex, C7H5NS2·C7H5NOS. The mol­ecules are linked by N—H⋯S and N—H⋯O hydrogen bonds, forming discrete molecular pairs. [ABSTRACT FROM AUTHOR]

The deprotonated 3-dimethyl­amino- N-salicylidenepropyl­amine Schiff base chelates to a Cd atom in the polymeric title compound with a dinuclear building block, [Cd2(NCS)2(C12H17N2O)2] n. The O atom of the Schiff base also engages in bridging. The bridging NCS group links adjacent dinuclear entities into a helical chain that runs along the b axis of the monoclinic unit cell. [ABSTRACT FROM AUTHOR]

In the title complex, [CuCl2(C3H7NO)(H2O)] n, each CuII atom is in a Cl3O2 five-coordinate environment with a slightly distorted square-pyramidal geometry. Cu atoms are linked by μ2-Cl ions, resulting in a one-dimensional linear chain structure. In the crystal structure, inter­molecular O—H⋯Cl hydrogen bonds link adjacent chains to form a two-dimensional network. [ABSTRACT FROM AUTHOR]

In the crystal structure of the title compound, C14H10N2O2, there are strong π–π inter­actions between mol­ecules, resulting in a one-dimensional chain structure. [ABSTRACT FROM AUTHOR]

The centrosymmetric title compound, [Cu(C7H8O3S)2(H2O)4], forms a pillared hydrogen-bonded layered network. The coordination geometry of the CuII ion is distorted octa­hedral, involving four aqua ligands and two N-atom donors of two 2-(4-pyrid­yl)ethanesulfonate (PES) ligands. The sulfonate group of PES is not involved in coordination to the metal, but participates in hydrogen bonds with the aqua ligands. [ABSTRACT FROM AUTHOR]