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In the title compound, (C4H12N)2[Cu(C3S5)2], the CuII atom lies on a centre of inversion and is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiol­ate ligands in a square-planar geometry. [ABSTRACT FROM AUTHOR]

In the title complex, (C6H8N)2[Cd(C3S5)2], the CdII ion is coordinated by four dmit (2-thioxo-1,3-dithione-4,5-dithiol­ate) S atoms in a distorted tetra­hedral geometry. The N-methyl­pyridinium cations link with the CdII complex anion via weak C—H⋯S hydrogen bonding. [ABSTRACT FROM AUTHOR]

The title compound, (C24H20P)2[Sn(C3S5)3], whose structure has been previously reported in the space group P at 120 K [de Assis, Chohan, Howie, Khan, Low, Spencer, Wardell & Wardell (1999), Polyhedron, 18, 3533–3544], has been crystallized in the space group C2/ c and its structure has been determined at 293 K. The [Sn(C3S5)3]2− anion possesses C2 symmetry, with the SnIV atom and one C=S group lying on the twofold rotation axis. The crystal packing is stabilized by C—H⋯S hydrogen bonds. [ABSTRACT FROM AUTHOR]