1. The titanium–thiolate complex [Li(C4H8O)4][Ti2(SC6H5)9]
- Author
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Puke, Carsten, Schmengler, Kai, Kirschbaum, Kristin, Conrad, Olaf, and Giolando, Dean M.
- Abstract
In the title compound, tetrakis(tetrahydrofuran)lithium(I) tri‐μ‐phenylthiolato‐bis[tris(phenylthiolato)titanate(IV)], [Li(C4H8O)4][Ti2(C6H5S)9], (I), the central structural motif of the [Ti2(SC6H5)9]−anion features a face‐sharing bi‐octahedron. The charge is balanced with a [Li(C4H8O)4]+cation. The asymmetric unit contains Ti, Li and a heavily disordered tetrahydrofuran molecule on a threefold axis, and two terminal and a bridging thiophenolate moiety and a slightly disordered tetrahydrofuran molecule on general positions.
- Published
- 2000
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