1. Dichloridotetrakis(1H-1,2,4-triazole-κN 4)copper(II)
- Author
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Bojan Kozlevčar, Tatjana Kobal, Amalija Golobič, Maja Vidmar, and Primož Šegedin
- Subjects
Metal-Organic Papers ,Chemistry ,Plane (geometry) ,Hydrogen bond ,chemistry.chemical_element ,1,2,4-Triazole ,General Chemistry ,Condensed Matter Physics ,Bioinformatics ,Copper ,Crystal ,chemistry.chemical_compound ,Crystallography ,Atom ,General Materials Science ,Symmetry (geometry) - Abstract
The central CuIIatom of the molecular title complex, [CuCl2(C2H3N3)4], is situated on a site with symmetry 2.22. It is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four N atoms of four 1,2,4-triazole ligands and the axial positions occupied by two Cl atoms situated on a twofold axis. The molecules are connectedviaN—H...Cl hydrogen bonds and the crystal consists of two interpenetrating three-dimensional hydrogen-bonded frameworks.
- Published
- 2012