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Mg batteries utilizing divalent Mg2+ as charge carriers have been attracting significant attention for energy storage owing to their uniqueness in terms of low cost, high safety, and high energy density. However, the short cycling life arising from the accumulation of a passivation layer on the Mg anode prohibits their further development. Here, a new strategy to suppress the accumulation of the passivation layer is presented, thus stabilizing the Mg anode by constructing a robust interfacial layer using organic solvent‐in‐water electrolytes. The organic solvents decompose on the Mg anode to form a MgO, polyether Mg enriched organic‐inorganic hybrid interfacial layer, preventing free water attack to the Mg anode. In addition, the organic solvent forms an H‐bond with H2O to suppress the water activity and therefore protecting the Mg anode. As an illustration to benefits of the solvent‐in‐water electrolytes, a Mg‐MnO2 battery that is coupled by a MnO2 cathode in Mn2+/MnO2 chemistry with the Mg anode is developed. The Mg‐MnO2 battery exhibits a well‐maintained discharge plateau at ≈2.5 V and a discharging capacity of ≈500 mAh g−1 over 1000 cycles. This result highlights the feasibility to stabilize the Mg anode by interface engineering through the solvent‐in‐water electrolyte design. [ABSTRACT FROM AUTHOR]

Solid Electrolyte Interface Regulated by Solvent-in-Water Electrolyte Enables High-Voltage and Stable Aqueous Mg-MnO2 Batteries (Adv. Mg anodes, Mg-MnO 2 batteries, MnO 2 cathodes, solid electrolyte interfaces, solvent-in-water electrolytes The regulated Mg anode enables highly stable aqueous Mg-MnO SB 2 sb batteries with a high discharge voltage of 2.5 V and a greatly improved specific capacity of 500 mAh g SP -1 sp for over 1000 cycles. [Extracted from the article]