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Lithium-sulfur (Li-S) batteries are one of the most promising alternative energy storage systems beyond Li-ion batteries. However, the sluggish kinetics of the nucleation and growth of the solid discharge product of Li2S/Li2S2 in the lower discharge plateau has been recently identified as a critical hurdle for attaining high specific capacity in Li-S batteries with high sulfur loadings under lean electrolyte conditions. Herein, a new strategy of breaking the charge-transport bottleneck by successful generation of experimentally verified stable Li2S2 and a reservoir of quasi-solid lithium polysulfides within the micropores of activated carbon fiber cloth as a high-sulfur-loading host is proposed. The developed Li-S cell is capable of delivering a highly sustainable areal capacity of 6.0 mAh cm-2 under lower electrolyte to sulfur ratios (<3.0 mLE gS -1). Micropore confinement leads to generation of solid Li2S2 that enables high utilization of the entire electroactive area by its inherent self-healing capacity. This strategy opens a new avenue for rational material designs for Li-S batteries under lean electrolyte condition. [ABSTRACT FROM AUTHOR]

Abstract: Lithium (Li) metal is an ideal anode material for high energy density batteries. However, the low Coulombic efficiency (CE) and the formation of dendrites during repeated plating and stripping processes have hindered its applications in rechargeable Li metal batteries. The accurate measurement of Li CE is a critical factor to predict the cycle life of Li metal batteries, but the measurement of Li CE is affected by various factors that often lead to conflicting values reported in the literature. Here, several parameters that affect the measurement of Li CE are investigated and a more accurate method of determining Li CE is proposed. It is also found that the capacity used for cycling greatly affects the stabilization cycles and the average CE. A higher cycling capacity leads to faster stabilization of Li anode and a higher average CE. With a proper operating protocol, the average Li CE can be increased from 99.0% to 99.5% at a high capacity of 6 mA h cm−2 (which is suitable for practical applications) when a high‐concentration ether‐based electrolyte is used. [ABSTRACT FROM AUTHOR]