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The microscopically structural switching of supramolecular networks endows programmable gel materials with dynamic hiding properties and functionalities. However, the reconstruction of supramolecular network will destroy the programming information imprinted on the original network structure, making it difficult to restore to the original state. Here, a novel intelligent programmable photonic gel composed of cellulose nanocrystals (CNC) and acrylamide is constructed. The mechanical properties and optical signals of gel can be switched reversibly on demand by reasonably designing the winding and compression between molecular structures. Under this conversion mechanism, the rigid "skeleton" constructed from the CNC chiral structure perfectly acts as the coding substrate. Importantly, even after multiple dynamic switching of the supramolecular network, the encoded information can be displayed completely and accurately on the CNC chiral structure in the stretched state. In addition, the 5D controllable conversion of stiffness, transparency, stretchability, color, and shape greatly improves the security and confidentiality of the encoded information inside the gel. This is a successful example of the application of CNC chiral structure in switchable supramolecular network materials. It is believed that the flexible variability and advanced camouflage give the intelligent gel the potential to be used in a wider range of practical scenarios. [ABSTRACT FROM AUTHOR]

The development of next‐generation flexible electronics hinges on the creation of materials that are not only mechanically robust but also multifunctional. Herein, a novel approach is presented to fabricate an aramid nanofibers/cellulose nanocrystals/montmorillonite nanoplates (ACM) composite substrate with a robust “brick and mortar” microstructure. This substrate is seamlessly integrated with a high‐performance graphene/silver nanowire (G/Ag) composite conductive layer, resulting in the creation of ACM&G/Ag nanopapers. The resulting nanopapers achieve remarkable tensile strength (δc) (543.82 MPa), tensile modulus (Ec) (10.93 GPa), and toughness (Uc) (95.18 MJ m−3). Notably, when normalized by weight, the specific tensile strength of these nanopapers surpasses that of commercial titanium alloy, reaching 399.87 MPa g−1 cm3, compared to titanium alloy's 257.00 MPa g−1 cm3. With a high conductivity of 1398.08 S cm−1, ACM&G/Ag nanopapers exhibit impressive electromagnetic interference shielding effectiveness (EMI SE) of 39.59 dB and EMI SE/t of 16359.26 dB cm−1. Moreover, ACM&G/Ag nanopapers exhibit exceptional thermal management performance, featuring high electrical heating temperature (280 °C), rapid response time (<6 s), enduring heating stability, deicing capacity, and reliable heating performance even in humid environments. These results underscore the substantial potential of these high‐performance nanopapers in diverse applications such as wearable devices, electromagnetic compatibility, thermal management, human health, and aerospace. [ABSTRACT FROM AUTHOR]