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This review is inspired by the increasing shortage of fresh water in areas of the world, and is written in response to the expanding demand for sustainable technologies due to the prevailing crisis of depleting natural water resources. It focuses on comprehending different solar energy-based technologies. Since the increasing population has resulted in the rising demand for freshwater, desalination installation volume is rapidly increasing globally. Conventional ways of desalination technologies involve the use of fossil fuels to extract thermal energy which imparts adverse impacts on the environment. To lessen the carbon footprint left by energy-intensive desalination processes, the emphasis has shifted to using renewable energy sources to drive desalination systems. The growing interest in combining solar energy with desalination with an emphasis on increasing energy efficiency has been sparked by the rapid advancements in solar energy technology, particularly solar thermal. This review paper aims to reflect various developments in solar thermal desalination technologies and presents prospects of solar energy-based desalination techniques. This paper reviews direct and indirect desalination techniques coupled with solar energy, and goes on to explain recent trends in technologies. This review also summarizes the emerging trends in the field of solar thermal desalination technologies. The use of nanoparticles and photo-thermal materials for localized heating in solar desalination systems has decreased energy consumption and enhanced the efficiency of the system. Solar power combined with emerging processes like membrane distillation (MD) has also a recent resurgence.