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Severe vibration of the core of ultra-high voltage (UHV) shunt reactors under operating conditions often leads to the occurrence of suspension electrode, and such a suspended discharge defect will destroy the oil-paper insulation. It is necessary to investigate the influence of vibration on suspended discharge when determining the best operating condition of UHV shunt reactors. The vibration frequency of the suspension electrode and the phase difference between the applied voltage and the vibration are studied by simulation and experiment. The simulation results show that the phase difference between the voltage and the vibration parameters will lead to an increase in the surface maximum field strength. The distortion of the field intensity caused by several typical vibration frequencies of reactor vibration is ranked (in ascending order) thus: 100, 300, 50, and 200 Hz. There is a coupling relationship between the phase difference and the vibration frequency on the suspended discharge, which will lead to an inconsistency between the field intensity and each single factor. The partial discharge test results of the collision between the suspension electrode and the high-voltage electrode show that the discharge generated by vibration at 100 Hz is much higher than that at other frequencies, followed by those at 300 and 50 Hz, and the discharge generated by vibration at 200 Hz is very small. When the phase difference of voltage advance vibration is between 0° and 90°, the quantity of local discharge is large. When the phase difference is between 90° and 180°, the local discharge is small.

Partial Discharges (PDs) are a significant factor in reducing the insulation life of traction transformers. In recent years, the Acoustic Emission (AE) method has become the most advanced method for detecting PD signals in transformers. The AE method utilizes AE sensors placed on the transformer tank to detect ultrasonic signals emitted by PD and determine the Time Of Arrival (TOA) of the head wave. The windings and cores of a traction transformer consist mainly of metal, which greatly affects the propagation of PD ultrasonic waves. This paper establishes a 110 kV “pressure acoustic, transient” physical field model of the traction transformer with dimensions of 4.63 × 1.48 × 2.84 m3. The model is used to carry out the PD pressure acoustic physical field simulation study of the traction transformer, to clarify the physical characteristics of the ultrasound of the PD defects, and to establish observation points on the transformer tanks to receive ultrasonic time-domain waveforms for PD detection. The simulation results indicate that PD ultrasonic waves exhibit complex propagation characteristics, including reflection, refraction, and reverberation, as they pass through the windings and cores to the observation points. The TOA of the head wave in the ultrasound time-domain waveform is indicated by the first maximum value of the wave crest line. Finally, this paper proposes a multi-level localization method based on the AE method to determine which winding generates the PD in the large-scale traction transformer using only four dynamically moving observation points.

Severe vibration of the core of ultra-high voltage (UHV) shunt reactors under operating conditions often leads to the occurrence of suspension electrode, and such a suspended discharge defect will destroy the oil-paper insulation. It is necessary to investigate the influence of vibration on suspended discharge when determining the best operating condition of UHV shunt reactors. The vibration frequency of the suspension electrode and the phase difference between the applied voltage and the vibration are studied by simulation and experiment. The simulation results show that the phase difference between the voltage and the vibration parameters will lead to an increase in the surface maximum field strength. The distortion of the field intensity caused by several typical vibration frequencies of reactor vibration is ranked (in ascending order) thus: 100, 300, 50, and 200 Hz. There is a coupling relationship between the phase difference and the vibration frequency on the suspended discharge, which will lead to an inconsistency between the field intensity and each single factor. The partial discharge test results of the collision between the suspension electrode and the high-voltage electrode show that the discharge generated by vibration at 100 Hz is much higher than that at other frequencies, followed by those at 300 and 50 Hz, and the discharge generated by vibration at 200 Hz is very small. When the phase difference of voltage advance vibration is between 0° and 90°, the quantity of local discharge is large. When the phase difference is between 90° and 180°, the local discharge is small. [ABSTRACT FROM AUTHOR]

The parameter of tensile strength for transformer bushing insulating paper occupies an important position in the structural design and life evaluation of transformer bushing. In order to precisely achieve the effect of aging time and moisture content on the tensile strength of transformer bushing paper, transformer insulating paper samples with a thickness of 0.13 mm were prepared for tensile strength and dielectric strength testing under different moisture contents and aging states. The results show that the tensile strength (MPa) of insulating paper decreases linearly in the range of 0–648 h under accelerated thermal aging at 130 °C. However, there is a more serious exponential decline in the tensile strength (MPa) of insulation paper with its moisture content is boosted. The moisture content in insulation paper is the most important factor for insulation paper deterioration in oil-impregnated paper insulation equipment, which could accelerate the end of insulation service life. The value of capacitance increment ΔC of the insulation paper samples displayed closely linear growth with a moisture content from 0.5% to 5.9%. Strictly controlling the moisture content by monitoring the ΔC value of transformer insulation paper is of significance for prolonging its service life. [ABSTRACT FROM AUTHOR]

Partial Discharges (PDs) are a significant factor in reducing the insulation life of traction transformers. In recent years, the Acoustic Emission (AE) method has become the most advanced method for detecting PD signals in transformers. The AE method utilizes AE sensors placed on the transformer tank to detect ultrasonic signals emitted by PD and determine the Time Of Arrival (TOA) of the head wave. The windings and cores of a traction transformer consist mainly of metal, which greatly affects the propagation of PD ultrasonic waves. This paper establishes a 110 kV "pressure acoustic, transient" physical field model of the traction transformer with dimensions of 4.63 × 1.48 × 2.84 m3. The model is used to carry out the PD pressure acoustic physical field simulation study of the traction transformer, to clarify the physical characteristics of the ultrasound of the PD defects, and to establish observation points on the transformer tanks to receive ultrasonic time-domain waveforms for PD detection. The simulation results indicate that PD ultrasonic waves exhibit complex propagation characteristics, including reflection, refraction, and reverberation, as they pass through the windings and cores to the observation points. The TOA of the head wave in the ultrasound time-domain waveform is indicated by the first maximum value of the wave crest line. Finally, this paper proposes a multi-level localization method based on the AE method to determine which winding generates the PD in the large-scale traction transformer using only four dynamically moving observation points. [ABSTRACT FROM AUTHOR]

The regular operation of transformers is significantly impacted by the insulation effectiveness of the transformer insulation oil–paper. In order to explore the mechanism of the influence of an electric field on the thermal decomposition performance of insulating oil–paper, this paper simulated the process of electrothermal coupling decomposition of insulating oil–paper from the micro-level based on molecular dynamics. It was determined that the insulating oil is made up of three 16-carbon hydrocarbon molecules, while the insulating paper is made up of 30 fibrous disaccharide molecules. Using the molecular dynamics simulation approach, the pyrolysis of the insulating oil and insulating paper under various electric field strengths was simulated, and the lysis of reactants and the distribution of products were statistically examined. This paper also studied how the electric field affected the microscopic process of the insulating oil–paper pyrolysis. The findings demonstrate that under the influence of electrothermal coupling, the big molecules of the insulating oil and insulating paper are pyrolyzed to produce a variety of tiny molecules. For the insulating oil, it is easily subject to electron displacement polarization under the influence of an external electric field since it contains non-polar molecules, especially impacted by an electric field of 100 V/m. For the insulating paper, its polar nature, on the other hand, makes itself a good candidate for guiding polarization when exposed to an external electric field. So, the greater the electric field strength is, the greater the impact on the thermal decomposition of the insulating paper is.

As an important high-voltage electrical equipment in the substation, the performance stability of high-voltage current transformers is directly related to the safe operation of the power grid. The insulating medium of the traditional oil-immersed current transformer is an oil-immersed paper structure. When the oil-immersed current transformer malfunctions, it is easy to cause fire and explosion, resulting in very serious consequences. If the transformer with the epoxy resin impregnated paper insulation medium is used, there is no oil and gas inside; thus, it has high reliability, which greatly reduces the risk of fire and explosion. Based on this, considering the application research on the high-voltage current transformers epoxy resin impregnated paper technology, this paper mainly analyzes some precautions for the application of epoxy resin impregnated paper technology to the high-voltage current transformers from three aspects: the research on the insulation performance of the epoxy resin impregnated paper transformers, the research on the mechanical properties, and the research on the relevant experimental methods of the epoxy resin impregnated paper technology application to the high-voltage current transformers.

We report a liquid metal microstrip antenna on a printing paper whose resonant frequency was tunable by folding the paper. The gallium-based alloy was used as liquid metal, which is instantly oxidized in ambient air. The oxidized liquid metal is easily wettable on printing paper surfaces, while it is non-wettable on laser-printed toner surfaces. An antenna with a 3 mm wide and 39 mm long copper-liquid metal overlapped-feedline linked to the liquid metal microstrip rectangle-shaped patch (40 × 31 mm2) was designed. The antenna pattern was printed on a printing paper using a laser printer. A liquid metal soaked roller was rolled on the antenna pattern printed paper, resulting in a liquid metal pattern where there was no toner. The resonant frequency of the liquid metal on the paper microstrip patch antenna was 2.88 GHz with −18.5 dB S11. The measured characteristics of the antenna were in good agreement with the simulation results. When the antenna was folded, the resonant frequency was changed to 2.68 GHz (x-axis folding) or 2.72 GHz (y-axis folding). Liquid metal on paper fabrication is simple but effective for creating custom-designed antennas that are easily re-designed and fabricated in the field. [ABSTRACT FROM AUTHOR]

Frequency Domain Spectroscopy (FDS) is widely used to estimate oil–paper insulation. The high moisture and long aging change the FDS characteristics of the insulating oil–paper, so normalization processing is required. Still, the choice of single activation energy needs further research. This paper studies the FDS characteristic of oil–paper insulation samples with different moisture and aging degrees and improves the traditional temperature correction method. The enhanced Arrhenius model uses the segmented activation energy to make the normalized FDS curve coincide better with the target curve, and the error is reduced. In addition, to verify the method’s effectiveness, this paper proposes an iterative correction process. It corrects the tan δ-f curve of the bushing with an aging time of 800 h based on segmented activation energy, and the overall normalization effect is improved.

We report a liquid metal microstrip antenna on a printing paper whose resonant frequency was tunable by folding the paper. The gallium-based alloy was used as liquid metal, which is instantly oxidized in ambient air. The oxidized liquid metal is easily wettable on printing paper surfaces, while it is non-wettable on laser-printed toner surfaces. An antenna with a 3 mm wide and 39 mm long copper-liquid metal overlapped-feedline linked to the liquid metal microstrip rectangle-shaped patch (40 × 31 mm2) was designed. The antenna pattern was printed on a printing paper using a laser printer. A liquid metal soaked roller was rolled on the antenna pattern printed paper, resulting in a liquid metal pattern where there was no toner. The resonant frequency of the liquid metal on the paper microstrip patch antenna was 2.88 GHz with −18.5 dB S11. The measured characteristics of the antenna were in good agreement with the simulation results. When the antenna was folded, the resonant frequency was changed to 2.68 GHz (x-axis folding) or 2.72 GHz (y-axis folding). Liquid metal on paper fabrication is simple but effective for creating custom-designed antennas that are easily re-designed and fabricated in the field.

Geotechnical designs and analyses of earth structures and foundations exclusively involve the assessment and consideration of unsaturated soil shear strength. The laboratory testing equipment and methods for predicting the unsaturated soil shear strength are complicated and more expensive. The experimental program attempted to involve undrained triaxial and filter paper for evaluating the unsaturated soil shear strength of identically compacted clayey soil. This study undertakes a comparison of shear strength in clayey soil under undrained loads, examining both saturated and unsaturated conditions. A 60 kPa air entry suction value is the key point at which linearity between the unsaturated shear strength parameter Øb and effective friction Ø′ with 15° linear slopes turns to non-linearity. Unsaturated shear strength increased by 22.76% in optimally wet conditions, 52.68% in optimum conditions, and 77.81% in optimally dry conditions as compared to saturated shear strength. This study utilizes an artificial neural network (ANN) to predict clayey soil's unsaturated shear strength, finding that the optimal ANN configuration (2-5-1 topology, Levenberg–Marquard optimization, and logsig transfer function) achieved high reliability with a correlation coefficient (R) of 0.9289 and mean square error values of 2.22, 7.12, and 3.012 for training, testing, and validation, respectively. This experimental investigation improves our understanding of clayey soil shear strength and emphasizes the importance of saturation and moisture content in geotechnical assessments under undrained loading conditions. [ABSTRACT FROM AUTHOR]

The regular operation of transformers is significantly impacted by the insulation effectiveness of the transformer insulation oil–paper. In order to explore the mechanism of the influence of an electric field on the thermal decomposition performance of insulating oil–paper, this paper simulated the process of electrothermal coupling decomposition of insulating oil–paper from the micro-level based on molecular dynamics. It was determined that the insulating oil is made up of three 16-carbon hydrocarbon molecules, while the insulating paper is made up of 30 fibrous disaccharide molecules. Using the molecular dynamics simulation approach, the pyrolysis of the insulating oil and insulating paper under various electric field strengths was simulated, and the lysis of reactants and the distribution of products were statistically examined. This paper also studied how the electric field affected the microscopic process of the insulating oil–paper pyrolysis. The findings demonstrate that under the influence of electrothermal coupling, the big molecules of the insulating oil and insulating paper are pyrolyzed to produce a variety of tiny molecules. For the insulating oil, it is easily subject to electron displacement polarization under the influence of an external electric field since it contains non-polar molecules, especially impacted by an electric field of 100 V/m. For the insulating paper, its polar nature, on the other hand, makes itself a good candidate for guiding polarization when exposed to an external electric field. So, the greater the electric field strength is, the greater the impact on the thermal decomposition of the insulating paper is. [ABSTRACT FROM AUTHOR]

The parameter of tensile strength for transformer bushing insulating paper occupies an important position in the structural design and life evaluation of transformer bushing. In order to precisely achieve the effect of aging time and moisture content on the tensile strength of transformer bushing paper, transformer insulating paper samples with a thickness of 0.13 mm were prepared for tensile strength and dielectric strength testing under different moisture contents and aging states. The results show that the tensile strength (MPa) of insulating paper decreases linearly in the range of 0–648 h under accelerated thermal aging at 130 °C. However, there is a more serious exponential decline in the tensile strength (MPa) of insulation paper with its moisture content is boosted. The moisture content in insulation paper is the most important factor for insulation paper deterioration in oil-impregnated paper insulation equipment, which could accelerate the end of insulation service life. The value of capacitance increment ΔC of the insulation paper samples displayed closely linear growth with a moisture content from 0.5% to 5.9%. Strictly controlling the moisture content by monitoring the ΔC value of transformer insulation paper is of significance for prolonging its service life.

As an important high-voltage electrical equipment in the substation, the performance stability of high-voltage current transformers is directly related to the safe operation of the power grid. The insulating medium of the traditional oil-immersed current transformer is an oil-immersed paper structure. When the oil-immersed current transformer malfunctions, it is easy to cause fire and explosion, resulting in very serious consequences. If the transformer with the epoxy resin impregnated paper insulation medium is used, there is no oil and gas inside; thus, it has high reliability, which greatly reduces the risk of fire and explosion. Based on this, considering the application research on the high-voltage current transformers epoxy resin impregnated paper technology, this paper mainly analyzes some precautions for the application of epoxy resin impregnated paper technology to the high-voltage current transformers from three aspects: the research on the insulation performance of the epoxy resin impregnated paper transformers, the research on the mechanical properties, and the research on the relevant experimental methods of the epoxy resin impregnated paper technology application to the high-voltage current transformers. [ABSTRACT FROM AUTHOR]

Frequency Domain Spectroscopy (FDS) is widely used to estimate oil–paper insulation. The high moisture and long aging change the FDS characteristics of the insulating oil–paper, so normalization processing is required. Still, the choice of single activation energy needs further research. This paper studies the FDS characteristic of oil–paper insulation samples with different moisture and aging degrees and improves the traditional temperature correction method. The enhanced Arrhenius model uses the segmented activation energy to make the normalized FDS curve coincide better with the target curve, and the error is reduced. In addition, to verify the method's effectiveness, this paper proposes an iterative correction process. It corrects the tan δ-f curve of the bushing with an aging time of 800 h based on segmented activation energy, and the overall normalization effect is improved. [ABSTRACT FROM AUTHOR]

Accurate monitoring of insulation aging of oil-paper insulation power equipment such as oil-immersed transformers is a key and difficult point in the field of high voltage research. In this paper, a method based on Raman spectroscopy to diagnose the aging degree of oil-paper insulation is discussed. Raman detections of the samples were carried out on a self-built Raman detection platform. The partial least squares method was used to extract and analyze the spectral features. The aging time of the sample was used to supervise the feature extraction of oil-paper insulation Raman data, and the intrinsic mathematical relationship between the Raman features of oil-paper insulation and the aging was excavated. Finally, a quantitative aging diagnostic model based on Raman spectral features of oil-paper insulation to predict its aging state was built with the assistance of the support vector regression method. The results of aging time prediction for 30 test samples show that the mean square error is 0.0123 and the square of correlation coefficient is 0.987. The proposed method provides a new idea for Raman aging diagnosis of oil-paper insulation.

In this study, we composite coated silica nanoparticles with functional groups on paper to form a double-size surface roughness, then hexafluorobutyl methacrylate was polymerized with 3-trimethoxymethylsilyl propyl methacrylate (TSPM), a one-step method is used to prepare a hydrophobic polymer with low surface energy (PHFMA-co-TSPM), and the superhydrophobic surface was prepared by hydrophobic treatment of the paper with a low surface energy polymer. Further tests show that the superhydrophobic paper prepared by this method not only exhibits extremely strong hydrophobicity, but also has strong stability, transparency, and self-cleaning properties.

In this study, we composite coated silica nanoparticles with functional groups on paper to form a double-size surface roughness, then hexafluorobutyl methacrylate was polymerized with 3-trimethoxymethylsilyl propyl methacrylate (TSPM), a one-step method is used to prepare a hydrophobic polymer with low surface energy (PHFMA-co-TSPM), and the superhydrophobic surface was prepared by hydrophobic treatment of the paper with a low surface energy polymer. Further tests show that the superhydrophobic paper prepared by this method not only exhibits extremely strong hydrophobicity, but also has strong stability, transparency, and self-cleaning properties. [ABSTRACT FROM AUTHOR]

The accuracy of insulation defect diagnosis based on the dielectric spectrum response is severely influenced by temperature for oil-impregnated paper bushing. The dielectric loss (tan δ) mathematical model with a temperature–frequency factor to restrict the application of the frequency domain dielectric spectrum (FDS) for insulation diagnosis is not clear. In this paper, five temperatures are selected to study the frequency temperature characteristic of the FDS and polarization current for oil-impregnated paper bushing. The experimental results show that the temperature has different effects on the lower frequency (0.001 Hz–1 Hz) and higher frequency (1000 Hz–10 kHz) of FDS. With the increasing temperature, the lower frequency tan δ of 1 mHz–1 Hz shows a better pattern of exponential growth, while the higher frequency tan δ at 1 kHz–10 kHz shows the declining law with the rising temperature. With the increasing temperature, the polarization current shows a better pattern of exponential growth, while resistance obviously shows the declining law of the exponential pattern. The FDS curve of oil-impregnated paper bushings can be amended by the mathematical model of tan δ for the dielectric response on site for accuracy diagnosis.

Thermodynamic properties of cellulose insulation paper are vital factors affecting the life of a transformer; in order to obtain cellulose insulation paper with better thermodynamic properties, three types of silane coupling agents—3-aminopropyltriethoxy silane (KH550), 3-glycidoxypropyltrimethoxy silane (KH560), and 3-methacryloyloxypropyltrimethoxy silane (KH570)—were grafted on the surface of nano-SiO2, and thermodynamic properties of cellulose modified with nano-SiO2 were explored. The molecular dynamics method was used to establish a composite model of nano-SiO2/cellulose. Also, different silane coupling agent grafted nano-SiO2/cellulose models were established to explore the effect of mechanical properties, interaction energy, free volume, and hydrogen bonds on thermodynamic properties. The results showed that KH550 was the best modification of the nano-SiO2/cellulose system among the three grafted silane coupling agents because KH550 grafted on the surface of nano-SiO2 formed more hydrogen bonds in the cellulose system. The interfacial bonding strength between the nano-SiO2 and the cellulose chains can effectively improve the thermal stability of the cellulose insulating paper.

A study of plasma treatment of clay-coated paper is presented. The wettability of the paper surface before and after the plasma treatment was determined by measuring the water contact angle and surface free energy. The appearance of the surface-functional groups was determined by using high-resolution X-ray photoelectron spectroscopy, while changes in the surface morphology were monitored by scanning electron microscopy. Already after 0.25 s of the plasma treatment, the paper surface improved its wettability. The X-ray photoelectron spectroscopy analyses showed a gradual increase of oxygen-rich functional groups on the surface while scanning electron microscopy analyses did not show a significant modification of the morphology and no alternation of the surface structure after the plasma treatment.

Cantilevers are one of the most utilized mechanical elements for acoustic sensing. In comparison to the edge clamped diaphragms of different shapes, a single edge clamped cantilever makes an acoustic sensor mechanically sensitive for detection of lower pressure. The aspect ratio of cantilevers is one of the most important parameters which affect sensitivity. Herein, we present a mathematical, finite element method and experimental analysis to determine the effect of the aspect ratio on the resonant frequency, response time, mechanical sensitivity, and capacitive sensitivity of a cantilever-based acoustic pressure sensor. Three cantilevers of different aspect ratios (0.67, 1, and 1.5) have been chosen for sound pressure application to detect capacitance change. The cantilever with the smallest aspect ratio (0.67) has the highest response time (206 ms), mechanical sensitivity, and capacitive sensitivity (22 fF), which reduce after increasing the aspect ratio. The resonant frequency of the cantilever was also analyzed by applying sweep in sound frequency. It was found to be minimum for the cantilever with the smallest aspect ratio (510 Hz) and increases with an increase in the aspect ratio. We have applied the garage fabrication process using low cost, recyclable, and easily available materials such as metal coated polymer sheets, mounting tapes and glass slides as alternative materials for expensive materials.

Smart materials with reversible wettability have attracted a lot of attention for application in sewage treatment. In this work, a pH-responsive polymer was prepared via the one-step free radical polymerization of 3-(trimethoxysilyl) acrylate and 2-dimethylaminoethyl methacrylate. The obtained pH-responsive polymer was then coated with a hydrogenated styrene–ethylene–butadiene–styrene block copolymer to endow the material with pH-responsive switchable superhydrophilic and superhydrophobic properties. Due to the excellent self-cleaning and mechanical stability of the coating, it was used to modify paper, which was then successfully utilized in the treatment of oily wastewater, showing great potential for use in advanced applications. [ABSTRACT FROM AUTHOR]

In order to improve the thermal stability of insulation paper cellulose in micro-water environment, the molecular simulation was used to compare and analyze the thermal stability of polysiloxane-grafted cellulose with 3% micro-water content in the present study. The static mechanics, glass transition temperature and number of hydrogen bonds are used to characterize the thermal stability of insulating paper cellulose in this paper. First, analysis of the mechanical properties of the model demonstrated that the value of the elastic moduli (E) and bulk moduli (K) of the grafted model were greater than those of the ungrafted model at each temperature. Second, the glass transition temperature of the grafted model was 60 K higher than that of the ungrafted model. Finally, the analysis of the radial distribution function (RDF) and hydrogen bonding showed that polysiloxane-grafted insulation paper cellulose can reduce the number of hydrogen bonds formed between the water molecules and the cellulose chains, which can reduce the damage caused to the cellulose chains by the water molecules. Therefore, the present study shows that the polysiloxane-grafted insulation paper cellulose can improve its thermal stability in micro-water environment.

A method of delaying the aging of natural ester oil-paper insulation systems by adding glyceryl triacetate is proposed in this work. A study was conducted on the thermal aging performance of soybean insulating oil mixed with glyceryl triacetate at a volume fraction of 7.5%. Through a 42-day accelerated thermal aging experiment, it was found that the addition of glyceryl triacetate effectively delayed the increase in kinematic viscosity of the insulating oil and reduced the generation of aging products such as moisture and acid. However, the polar compounds in glyceryl triacetate reduced the breakdown voltage of the mixed oil and made the dielectric loss factor higher than that of pure oil. In addition, tests were conducted on the insulating paper immersed in two types of oil, and it was found that the addition of glyceryl triacetate helps to distribute mixed oil molecules on the surface of insulating paper, which effectively helped absorb moisture from the paper, weakening the hydrolysis reaction of cellulose and delaying the aging of insulating paper. In addition, the insulating paper immersed in the mixed oil maintains good power frequency breakdown voltage and dielectric properties throughout the thermal aging experiment. [ABSTRACT FROM AUTHOR]

Accurate monitoring of insulation aging of oil-paper insulation power equipment such as oil-immersed transformers is a key and difficult point in the field of high voltage research. In this paper, a method based on Raman spectroscopy to diagnose the aging degree of oil-paper insulation is discussed. Raman detections of the samples were carried out on a self-built Raman detection platform. The partial least squares method was used to extract and analyze the spectral features. The aging time of the sample was used to supervise the feature extraction of oil-paper insulation Raman data, and the intrinsic mathematical relationship between the Raman features of oil-paper insulation and the aging was excavated. Finally, a quantitative aging diagnostic model based on Raman spectral features of oil-paper insulation to predict its aging state was built with the assistance of the support vector regression method. The results of aging time prediction for 30 test samples show that the mean square error is 0.0123 and the square of correlation coefficient is 0.987. The proposed method provides a new idea for Raman aging diagnosis of oil-paper insulation. [ABSTRACT FROM AUTHOR]

We have coated phase change materials (PCMs) on rough and flexible substrates to achieve multicolor changeable devices. The principle of the device is based on an earlier discovery that lights have strong interference effect in PCM films, leading to various colors by reflection. In this work, paper substrates are laminated by parylene layers to protect the device from water before coated with functional PCM films. The PCM-based color printing (PCP) on paper is not affected by rough surfaces and shows a similar color appearance as that on smooth surfaces. In particular, the color-printed device can be patterned by UV lithography to display a clear and tunable optical image, and it exhibits a low sensitivity to the angle of view. Such PCP has potential applications for low-cost, disposable, and flexible displays.

In order to improve the thermal stability of insulation paper cellulose in micro-water environment, the molecular simulation was used to compare and analyze the thermal stability of polysiloxane-grafted cellulose with 3% micro-water content in the present study. The static mechanics, glass transition temperature and number of hydrogen bonds are used to characterize the thermal stability of insulating paper cellulose in this paper. First, analysis of the mechanical properties of the model demonstrated that the value of the elastic moduli (E) and bulk moduli (K) of the grafted model were greater than those of the ungrafted model at each temperature. Second, the glass transition temperature of the grafted model was 60 K higher than that of the ungrafted model. Finally, the analysis of the radial distribution function (RDF) and hydrogen bonding showed that polysiloxane-grafted insulation paper cellulose can reduce the number of hydrogen bonds formed between the water molecules and the cellulose chains, which can reduce the damage caused to the cellulose chains by the water molecules. Therefore, the present study shows that the polysiloxane-grafted insulation paper cellulose can improve its thermal stability in micro-water environment. [ABSTRACT FROM AUTHOR]

We presented a distance-based detection method for visual quantification of mercury ions on a microfluidic paper-based analytical device (μPAD). Dithizone in NaOH solution was used as chromogenic reagent and deposited onto paper channel delimited by hydrophobic wax barrier. Reactions happened between mercury ions and dithizone to form an insoluble colored complex, producing colored precipitate on the paper channel. The length of colored precipitate could be readily measured using the printed ruler along each device. The length of precipitate increase linearly with the mercury concentrations, mercury in sample solution could be quantified by measuring the length of the colored precipitate. Being free of any electronic instruments, this method has the advantages of portability, ease of use, low cost and disposability. This presented method was used to detect mercury ions in a synthetic sample, demonstrating its potential in on-site and real time analysis.

In recent years, the field of flexible electronics has become one of the cross-disciplinary research hotspots, attracting worldwide attention and making rapid advances. So far, there has been plenty of research on the use of two-dimensional (2D) materials in flexible electronics, including graphene, transition metal dichalcogenide, and so on. In this work, we successfully prepared quasi-one-dimensional (Q1D) Nb2Pd0.73S5.97 superconductors on flexible paper by mechanical friction and systematically studied their physical properties at low temperatures. Superconductivity with transition temperature (Tc) ∼ 6.05 K by Meissner effect was observed in Nb2Pd0.73S5.97 wires coated on flexible paper, and a resistance drop at 4.80 K was confirmed in electrical transport measurements. The lower critical field (Hc1) of coated paper shows anisotropy effect under parallel and perpendicular magnetic fields, exhibiting a 2D-like feature, unlike the bulk Nb2Pd0.73S5.97 fibers. Our work provides a broader platform for the application of low-dimensional materials in flexible functional devices. [ABSTRACT FROM AUTHOR]

The effect of silica nanoparticle (Nano-SiO2) dopants on insulation paper cellulose, and the interaction between them, was investigated using molecular dynamics simulations. The mechanical properties, interactions, and cellulose-Nano-SiO2 compatibility of composite models of cellulose doped with Nano-SiO2 were studied. An increase in Nano-SiO2 size leads to a decrease in the mechanical properties, and a decrease in the anti-deformation ability of the composite model. The binding energies and bond energies per surface area of the composite models indicate that the bonding interaction between spherical Nano-SiO2 and cellulose is the strongest among the four different Nano-SiO2 shapes that are investigated. The solubilities of the four composite models decrease with increasing Nano-SiO2 size, and the difference between the solubility of pure cellulose and those of the composite models increases with increasing Nano-SiO2 size. Good doping effects with the highest cellulose-Nano-SiO2 compatibility are achieved for the cellulose model doped with spherical Nano-SiO2 of 10 Å in diameter. These findings provide a method for modifying the mechanical properties of cellulose by doping, perhaps for improving insulation dielectrics.

Paper-based batteries represent a new frontier in battery technology. However, low-flexibility and poor ionic conductivity of solid electrolytes have been major impediments in achieving practical mechanically flexible batteries. This work discuss new highly ionic conductive polymer gel electrolytes for paper-based battery applications. In this paper, we present a poly(vinylidene fluoride-hexafluoropropylene) (PVDH-HFP) porous membrane electrolyte enhanced with lithium bis(trifluoromethane sulphone)imide (LiTFSI) and lithium aluminum titanium phosphate (LATP), with an ionic conductivity of 2.1 × 10−3 S cm−1. Combining ceramic (LATP) with the gel structure of PVDF-HFP and LiTFSI ionic liquid harnesses benefits of ceramic and gel electrolytes in providing flexible electrolytes with a high ionic conductivity. In a flexibility test experiment, bending the polymer electrolyte at 90° for 20 times resulted in 14% decrease in ionic conductivity. Efforts to further improving the flexibility of the presented electrolyte are ongoing. Using this electrolyte, full-cell batteries with lithium titanium oxide (LTO) and lithium cobalt oxide (LCO) electrodes and (i) standard metallic current collectors and (ii) paper-based current collectors were fabricated and tested. The achieved specific capacities were (i) 123 mAh g−1 for standard metallic current collectors and (ii) 99.5 mAh g−1 for paper-based current collectors. Thus, the presented electrolyte has potential to become a viable candidate in paper-based and flexible battery applications. Fabrication methods, experimental procedures, and test results for the polymer gel electrolyte and batteries are presented and discussed.

The accuracy of insulation defect diagnosis based on the dielectric spectrum response is severely influenced by temperature for oil-impregnated paper bushing. The dielectric loss (tan δ) mathematical model with a temperature–frequency factor to restrict the application of the frequency domain dielectric spectrum (FDS) for insulation diagnosis is not clear. In this paper, five temperatures are selected to study the frequency temperature characteristic of the FDS and polarization current for oil-impregnated paper bushing. The experimental results show that the temperature has different effects on the lower frequency (0.001 Hz–1 Hz) and higher frequency (1000 Hz–10 kHz) of FDS. With the increasing temperature, the lower frequency tan δ of 1 mHz–1 Hz shows a better pattern of exponential growth, while the higher frequency tan δ at 1 kHz–10 kHz shows the declining law with the rising temperature. With the increasing temperature, the polarization current shows a better pattern of exponential growth, while resistance obviously shows the declining law of the exponential pattern. The FDS curve of oil-impregnated paper bushings can be amended by the mathematical model of tan δ for the dielectric response on site for accuracy diagnosis. [ABSTRACT FROM AUTHOR]

Because of the overly averaged element sensitivity in the topological optimization of an irregular structure with a grid independent filter, a topological optimization model was built for the structural domain. The maximization of stiffness was first taken as the goal for the topological optimization of irregular structure stiffness. Subsequently, an element size filter was proposed to address the overly averaged local element sensitivity with the grid independent filter when the designed domain element size varied dramatically. Finally, the element sensitivity of the objective function was derived under the given constraints. A case study was then conducted on a naval gun mount with the maximization of structural flexibility as the objective function and the volume of structural material as a constraint. A stiffness optimization model based on the bi-directional evolutionary structural optimization algorithm was adopted for the topological optimization of the gun mount. Structural optimization was conducted for the gun mount with different shooting angles to realize its optimal stiffness and strength under the constraint of consistent material volume. The optimization results proved that the element independent filter proposed in this paper could be effectively applied in the topological optimization of an irregular structure and used to explore the topological optimization of the supporting structure under impact. [ABSTRACT FROM AUTHOR]

Thermodynamic properties of cellulose insulation paper are vital factors affecting the life of a transformer; in order to obtain cellulose insulation paper with better thermodynamic properties, three types of silane coupling agents—3-aminopropyltriethoxy silane (KH550), 3-glycidoxypropyltrimethoxy silane (KH560), and 3-methacryloyloxypropyltrimethoxy silane (KH570)—were grafted on the surface of nano-SiO2, and thermodynamic properties of cellulose modified with nano-SiO2 were explored. The molecular dynamics method was used to establish a composite model of nano-SiO2/cellulose. Also, different silane coupling agent grafted nano-SiO2/cellulose models were established to explore the effect of mechanical properties, interaction energy, free volume, and hydrogen bonds on thermodynamic properties. The results showed that KH550 was the best modification of the nano-SiO2/cellulose system among the three grafted silane coupling agents because KH550 grafted on the surface of nano-SiO2 formed more hydrogen bonds in the cellulose system. The interfacial bonding strength between the nano-SiO2 and the cellulose chains can effectively improve the thermal stability of the cellulose insulating paper. [ABSTRACT FROM AUTHOR]

A study of plasma treatment of clay-coated paper is presented. The wettability of the paper surface before and after the plasma treatment was determined by measuring the water contact angle and surface free energy. The appearance of the surface-functional groups was determined by using high-resolution X-ray photoelectron spectroscopy, while changes in the surface morphology were monitored by scanning electron microscopy. Already after 0.25 s of the plasma treatment, the paper surface improved its wettability. The X-ray photoelectron spectroscopy analyses showed a gradual increase of oxygen-rich functional groups on the surface while scanning electron microscopy analyses did not show a significant modification of the morphology and no alternation of the surface structure after the plasma treatment. [ABSTRACT FROM AUTHOR]

Cantilevers are one of the most utilized mechanical elements for acoustic sensing. In comparison to the edge clamped diaphragms of different shapes, a single edge clamped cantilever makes an acoustic sensor mechanically sensitive for detection of lower pressure. The aspect ratio of cantilevers is one of the most important parameters which affect sensitivity. Herein, we present a mathematical, finite element method and experimental analysis to determine the effect of the aspect ratio on the resonant frequency, response time, mechanical sensitivity, and capacitive sensitivity of a cantilever-based acoustic pressure sensor. Three cantilevers of different aspect ratios (0.67, 1, and 1.5) have been chosen for sound pressure application to detect capacitance change. The cantilever with the smallest aspect ratio (0.67) has the highest response time (206 ms), mechanical sensitivity, and capacitive sensitivity (22 fF), which reduce after increasing the aspect ratio. The resonant frequency of the cantilever was also analyzed by applying sweep in sound frequency. It was found to be minimum for the cantilever with the smallest aspect ratio (510 Hz) and increases with an increase in the aspect ratio. We have applied the garage fabrication process using low cost, recyclable, and easily available materials such as metal coated polymer sheets, mounting tapes and glass slides as alternative materials for expensive materials. [ABSTRACT FROM AUTHOR]

Wood–plastic composites were prepared from polyethylene terephthalate- 1,4-cyclohexanedimethanol ester (PETG) and waste-paper fiber that was unmodified, modified with alkyl-ketene-dimer (AKD), and modified with a silane-coupling agent. The mechanical properties, water absorption properties, surface structure, and thermal properties of the three prepared materials were compared. The results showed that the optimum amount of waste-paper powder is 10 wt%, while that of the waste-paper particles is 60–80 mesh. The use of AKD and coupling agent KH550 can reduce the water absorption of the composite; however, the reductive effect of the coupling agent is better, in that it is reduced by 0.3%. Modification using a 1-wt% KH550 coupling agent can effectively increase the tensile strength of a composite from 31.36 to 41.67 MPa (increase of 32.8%), while the bending strength increased from 86.47 to 98.31 MPa (increase of 13.7%). This also enhances the thermal stability of the composites. With the addition of the coupling agent, the composite material maintains good mechanical properties even after being immersed in water; this can enable the safe use of these composite materials in outdoor environments. [ABSTRACT FROM AUTHOR]

Superhydrophobic coatings have been applied in various fields. The materials used in the preparation of superhydrophobic coatings have attracted the attention of scholars. Due to the harm of fluorine-containing substances with low surface energy to the environment, fluorine-free superhydrophobic coatings have become a hotspot in the research field. Herein, a fluorine-free superhydrophobic coating with oil/water separation was made by a solution immersion way. The fluorine-free copolymer and polydimethylsiloxane (PDMS)/SiO2 nanoparticles (NPs) were mixed to prepare a composite solution, and the superhydrophobic surface was obtained on the paper by a dipping method. The scanning electron microscope, x-ray photoelectron spectrometer, 1H nuclear magnetic resonance, and Fourier transform infrared were used to study the surface characteristics and structural composition of the superhydrophobic material. The research proved that the copolymer and PDMS/SiO2 NPs were successfully coated on the paper surface, and the rough structure of the superhydrophobic surface was also attributed to the introduction of the copolymer and PDMS/SiO2 NPs. The evaluation of the coating has proved its excellent hydrophobicity, oil/water separation performance, and self-cleaning performance. The coating is a sustainable and environmentally friendly superhydrophobic material that can be used in packaging, construction, petrochemical, and other industries. [ABSTRACT FROM AUTHOR]

Cellulose insulation paper is an essential part of the transformer oil-paper insulation system, and many types of nano-modified insulating paper are available. For studying the effects of various nano-modified molecules on cellulose and the differences in performance, the pure cellulose model and polyoctaaminophenylsesquioxane and grafted 3-aminopropyltriethoxysilane (KH550) SiO2 and Al2O3 cellulose models were developed using molecular dynamics methods, and the mechanical properties and thermally stability were calculated and compared. The findings show that, in general, all three nano-modification models improved the thermal stability and mechanical properties, with nano-SiO2-KH550 cellulose having the best overall modification effect. In terms of mechanical properties, the nano-SiO2-KH550 cellulose showed the largest increase in compressive strength, with an 18.1% improvement. In terms of thermal stability, the KH550 grafted nano-silica/cellulose composite model showed the best modification effect, as evidenced by the smaller cohesive energy density and free volume region compressing the space between cellulose molecules, making the modified cellulose more compact internally, thus achieving the effect of inhibiting the movement of cellulose chains. [ABSTRACT FROM AUTHOR]

Transformer oil plays the role of heat dissipation and insulation in power transformers, and its electrical and thermal characteristics are directly related to the stable operation of the transformer. At the same time, it is important to master the electric–thermal characteristics of transformer oil for transformer state evaluation, latent fault prediction, and maintenance planning. Based on this, the gas production rule and electrical characteristics of transformer oil under accelerated aging are studied in this paper. First, the experimental platform for power transformer aging is established to accelerate the aging of power transformers. Second, the accelerated aging transformer oil is taken as the research object, and the power frequency, DC, lightning, and gas chromatography are measured and analyzed. Finally, a transformer oil aging evaluation model is established, which takes into account four factors: carbon and oxygen gas factors in transformers, life loss factors calculated by hotspot temperature, hydrocarbon gas factors dissolved in transformer oil, and oil quality factors, and conducts aging evaluation. The conclusion shows that the T parameter proposed in this paper can effectively evaluate the quality of transformer oil. When T is less than or equal to 0.6, there is no aging of the oil. When T is greater than 0.6 and less than 1, the transformer oil has been aging, but it is not manifested. Those are parameters whose chromatography and breakdown voltage are not far beyond the IEEE standard. When T = 1, the aging of oil with significant changes in gas content and breakdown voltage can be observed. When T is greater than 1, the oil has undergone serious aging. [ABSTRACT FROM AUTHOR]

With the increasing demand for the resilient capacity of transformers in high-proportion renewable energy grids, the overload capacity of transformers and the thermal conductivity of winding insulation materials have been put forward as important requirements. In response to these requirements, a novel ceramic high temperature tolerance insulation winding is proposed in this paper and is applied in a ceramic insulated winding transformer. A combination of simulation and experimentation is used to analyze the thermal-flow characteristics of this transformer. The temperature and flow field distribution characteristics of transformers with both winding insulation methods (ceramic and Nomex paper) are compared. The internal mechanism of reflux near the iron core and high voltage winding under forced air cooling is clarified. A superior outside cooling condition is obtained. A prototype ceramic insulated winding transformer is developed and tested to verify the accuracy of the simulation model. The results show that the hotspot temperature of the ceramic insulated winding transformer under natural cooling is 10.7% lower than that of the Nomex paper insulated winding transformer. With forced air cooling of 2, 3, 4, 5, and 6 m/s applied at the bottom, the hotspot temperature of the ceramic insulated winding transformer is 11.4%, 10.5%, 9.7%, 14.0%, and 17.8% lower than that of the Nomex paper insulation winding transformer, respectively. Under forced air cooling, a reflux phenomenon is observed in both transformers in the vicinity of the iron core and high voltage winding due to the formation of adverse pressure gradient region and wall viscous force blocking. The strength of the reflux is affected by the magnitude of the forced air cooling flow velocity and the construction of the transformer. The optimal range of the external cooling flow velocity for the ceramic insulated winding transformer is 3–4 m/s. The errors between the simulated temperature and the measured temperature at the nine monitoring points of the prototype are all less than 5%, which verifies the effectiveness of the simulation model. The experimental and theoretical basis for the design and application of resilient capacity dry type transformers is provided by this research. [ABSTRACT FROM AUTHOR]

Paper-based batteries represent a new frontier in battery technology. However, lowflexibility and poor ionic conductivity of solid electrolytes have been major impediments in achieving practical mechanically flexible batteries. This work discuss new highly ionic conductive polymer gel electrolytes for paper-based battery applications. In this paper, we present a poly(vinylidene fluoride-hexafluoropropylene) (PVDHHFP) porous membrane electrolyte enhanced with lithium bis(trifluoromethane sulphone) imide (LiTFSI) and lithium aluminum titanium phosphate (LATP), with an ionic conductivity of 2.1 × 10-3 S cm-1. Combining ceramic (LATP) with the gel structure of PVDF-HFP and LiTFSI ionic liquid harnesses benefits of ceramic and gel electrolytes in providing flexible electrolytes with a high ionic conductivity. In a flexibility test experiment, bending the polymer electrolyte at 90° for 20 times resulted in 14% decrease in ionic conductivity. Efforts to further improving the flexibility of the presented electrolyte are ongoing. Using this electrolyte, full-cell batteries with lithium titanium oxide (LTO) and lithium cobalt oxide (LCO) electrodes and (i) standard metallic current collectors and (ii) paper-based current collectors were fabricated and tested. The achieved specific capacities were (i) 123 mAh g-1 for standard metallic current collectors and (ii) 99.5 mAh g-1 for paper-based current collectors. Thus, the presented electrolyte has potential to become a viable candidate in paper-based and flexible battery applications. Fabrication methods, experimental procedures, and test results for the polymer gel electrolyte and batteries are presented and discussed. [ABSTRACT FROM AUTHOR]