Search

Your search keyword '"Aleshin, Dmitry Yu."' showing total 3 results
Start Over Author "Aleshin, Dmitry Yu." Search Limiters Peer Reviewed Publication Year Range Last 10 years Journal angewandte chemie
3 results on '"Aleshin, Dmitry Yu."'

3. Unravelling of a [High Spin—Low Spin] ↔ [Low Spin—High Spin] Equilibrium in Spin‐Crossover Iron(II) Dinuclear Helicates Using Paramagnetic NMR Spectroscopy.

Author

Aleshin, Dmitry Yu., Diego, Rosa, Barrios, Leoní A., Nelyubina, Yulia V., Aromí, Guillem, and Novikov, Valentin V.

Subjects
*NUCLEAR magnetic resonance spectroscopy, *ELECTRON paramagnetic resonance spectroscopy, *TRANSITION metal ions, *IRON, *CELLULAR automata, *ELECTRONIC equipment
Abstract

Spin‐crossover between high‐spin (HS) and low‐spin (LS) states of selected transition metal ions in polynuclear and polymeric compounds is behind their use as multistep switchable materials in breakthrough electronic and spintronic devices. We report the first successful attempt to observe the dynamics of a rarely found broken‐symmetry spin state in binuclear complexes, which mixes the states [HS‐LS] and [LS‐HS] on a millisecond timescale. The slow exchange between these two states, which was identified by paramagnetic NMR spectroscopy in solutions of two spin‐crossover iron(II) binuclear helicates that are amenable to molecular design, opens a path to double quantum dot cellular automata for information storage and processing. [ABSTRACT FROM AUTHOR]

Published
2022
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results