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Your search keyword '"Nakano, Motohiro"' showing total 9 results
Start Over Author "Nakano, Motohiro" Journal angewandte chemie
9 results on '"Nakano, Motohiro"'

3. Charge-Transfer Phase Transition of a Cyanide-Bridged FeII/FeIII Coordination Polymer.

Author

Zhang, Kuirun, Kang, Soonchul, Yao, Zi ‐ shuo, Nakamura, Kazusa, Yamamoto, Takashi, Einaga, Yasuaki, Azuma, Nobuaki, Miyazaki, Yuji, Nakano, Motohiro, Kanegawa, Shinji, and Sato, Osamu

Subjects
CHARGE-transfer transitions, COORDINATION polymers, CYANIDES, IRON-cobalt alloys, SPIN crossover
Abstract

Heterometallic Prussian blue analogues are known to exhibit thermally induced charge transfer, resulting in switching of optical and magnetic properties. However, charge-transfer phase transitions have not been reported for the simplest FeFe cyanide-bridged systems. A mixed-valence FeII/FeIII cyanide-bridged coordination polymer, {[Fe(Tp)(CN)3]2Fe(bpe)⋅5 H2O} n, which demonstrates a thermally induced charge-transfer phase transition, is described. As a result of the charge transfer during this phase transition, the high-spin state of the whole system does not change to a low-spin state. This result is in contrast to FeCo cyanide-bridged systems that exhibit charge-transfer-induced spin transitions. [ABSTRACT FROM AUTHOR]

Published
2016
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5. Redox‐Controlled Magnetic {Mn13} Keggin Systems

Author

Newton, Graham N., primary, Yamashita, Satoshi, additional, Hasumi, Koen, additional, Matsuno, Junzo, additional, Yoshida, Norifumi, additional, Nihei, Masayuki, additional, Shiga, Takuya, additional, Nakano, Motohiro, additional, Nojiri, Hiroyuki, additional, Wernsdorfer, Wolfgang, additional, and Oshio, Hiroki, additional

Published
2011
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9. Wheel-Shaped Er.

Author

Yamashita, Aika, Watanabe, Akiko, Akine, Shigehisa, Nabeshima, Tatsuya, Nakano, Motohiro, Yamamura, Tomoo, and Kajiwara, Takashi

Published
2011
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