1. Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity.
- Author
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Bilyachenko AN, Levitsky MM, Yalymov AI, Korlyukov AA, Khrustalev VN, Vologzhanina AV, Shul'pina LS, Ikonnikov NS, Trigub AE, Dorovatovskii PV, Bantreil X, Lamaty F, Long J, Larionova J, Golub IE, Shubina ES, and Shul'pin GB
- Abstract
A series of four unprecedented heterometallic metallagermsesquioxanes were synthesized. Their cage-like architectures have a unique type of molecular topology consisting of the hexairon oxo {Fe
6 O19 } core surrounded in a triangular manner by three cyclic germoxanolates [PhGe(O)O]5 . This structural organization induces antiferromagnetic interactions between the FeIII ions through the oxygen atoms. Evaluated for this first time in catalysis, these compounds showed a high catalytic activity in the oxidation of alkanes and the oxidative formation of benzamides from alcohols., (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)- Published
- 2016
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