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Recently, metal‐free, heteroatom‐doped carbon nanomaterials have emerged as promising electrocatalysts for the oxygen evolution reaction (OER), but their synthesis is a tedious process involving energy‐wasting calcination. Molecular electrocatalysts offer attractive catalysts for the OER. Here, phytic acid (PA) was selected to investigate the OER activity of carbons in organic molecules by DFT calculations and experiments. Positively charged carbons on PA were very active towards the OER. The PA molecules were fixed into a porous, conductive hydrogel with a superhydrophilic surface. This outperformed most metal‐free electrocatalysts. Besides the active sites on PA, the high OER activity was also related to the porous and conductive networks on the hydrogel, which allowed fast charge and mass transport during the OER. Therefore, this work provides a metal‐free, organic‐molecule‐based electrocatalyst to replace carbon nanomaterials for efficient OER. Positively charged carbons on organic molecules (i.e. phytic acid, denoted PA) can participate in the oxygen evolution reaction (OER), as shown by DFT calculations and experiments. Moreover, doping of PA into a porous and conductive hydrogel is a robust strategy for stabilizing PA, as well as boosting the charge and mass transport of PA during the OER. [ABSTRACT FROM AUTHOR]