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Naphthospironone A, a polyhydroxy cagelike bioactive natural product, was synthesised for the first time in this study. The spiro[bicyclo[3.2.1]octane‐pyran] core was constructed by an acid‐promoted epoxide‐opening lactonisation and a base‐induced intramolecular aldol‐type cyclisation. [ABSTRACT FROM AUTHOR]

Fundamental insights into the reaction kinetics of organic–inorganic lead halide perovskite nanocrystals (LHP NCs) are still limited due to their ultrafast formation rate. Herein, we develop a water–oil interfacial synthesis of MAPbBr3 NCs (MA=CH3NH3+), which prolongs the reaction time to tens of minutes. This method makes it possible to monitor in situ the formation process of MAPbBr3 NCs and observe successive spectral evolutions from 438 to 534 nm in a single reaction by extending reaction time. The implementation of this method depends on reducing the formation rate of PbBr64− octahedra and the diffusion rate of MA. The formation of PbBr64− is a rate‐determining step, and the biphasic system offers a favorable reaction condition to control the mass transfer of MA. The effects of temperature and concentration of precursor and ligand are investigated in detail. [ABSTRACT FROM AUTHOR]

Abstract: Methylammonium lead halide perovskite nanocrystals offer attractive optoelectronic properties but suffer from fast degradation in the presence of water. In contradiction to this observation, we demonstrate the possibility of a direct aqueous synthesis of CH3NH3PbX3 (X=Br or Cl/Br) nanocrystals through the reaction between the lead halide complex and methylamine when the pH is maintained in the range of 0–5. Under these synthetic conditions, the positively charged surface of the perovskite nanocrystals and the proper ionic balance help to prevent their decomposition in water. Additional surface capping with organic amine ligands further improves the photoluminescence quantum yield of the perovskite nanocrystals to values close to 40 %, ensures their stability under ambient conditions for several months, and their photoluminescence performance under continuous 0.1 W mm−2 405 nm light irradiation for over 250 hours. [ABSTRACT FROM AUTHOR]

Abstract: Free‐standing macroporous air electrodes with enhanced interfacial contact, rapid mass transport, and tailored deposition space for large amounts of Li2O2 are essential for improving the rate performance of Li‐O2 batteries. An ordered mesoporous carbon membrane with continuous macroporous channels was prepared by inversely topological transformation from ZnO nanorod array. Utilized as a free‐standing air cathode for Li‐O2 battery, the hierarchically porous carbon membrane shows superior rate performance. However, the increased cross‐sectional area of the continuous macropores on the cathode surface leads to a kinetic overpotential with large voltage hysteresis and linear voltage variation against Butler–Volmer behavior. The kinetics were investigated based on the rate‐determining step of second electron transfer accompanied by migration of Li+ in solid or quasi‐solid intermediates. These discoveries shed light on the design of the air cathode for Li‐O2 batteries with high‐rate performance. [ABSTRACT FROM AUTHOR]

A highly stereocontrolled, convergent total synthesis of kendomycin [(−)-TAN2162], an ansa-macrocyclic antibiotic, is reported. The key of the strategy is an unprecedented Tsuji-Trost macrocyclic etherification, followed by a transannular Claisen rearrangement to construct the 18-membered carbocyclic framework. The oxa-six- and five-membered rings were also stereoselectively constructed respectively by a cascade oxidative cyclization at an unfunctionalized benzylic position and using a one-pot epoxidation/5- exo-tet epoxide opening. [ABSTRACT FROM AUTHOR]