1. A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds.
- Author
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Jono, Keisuke, Suzuki, Akira, Akita, Munetaka, Albrecht, Ken, Yamamoto, Kimihisa, and Yoshizawa, Michito
- Subjects
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DENDRIMERS synthesis , *CARBON nanotubes , *NANOTUBES , *NANOSTRUCTURED materials synthesis , *SYNTHESIS of Nanocomposite materials , *HYDROPHOBIC interactions , *NUCLEAR magnetic resonance spectroscopy - Abstract
By the covalent linkage of two bent bisanthracene amphiphiles with a biphenyl spacer bearing hydrophilic pendants, we synthesized a new molecular clip with a C-shaped conformation. The molecular clip provides an acyclic, open cavity surrounded by four anthracene panels in water. In contrast to previous clip- and tweezers-like compounds as well as cage-shaped compounds, the C-shaped polyaromatic cavity displays unusual wide-ranging capturing abilities toward not only planar perylene-based pigments and cylindrical single-walled carbon nanotubes but also highly branched macromolecules (carbazole dendrimers). [ABSTRACT FROM AUTHOR]
- Published
- 2017
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