21 results on '"*ACYL group"'
Search Results
2. Alkyne Insertion Enabled Vinyl to Acyl 1,5‐Palladium Migration: Rapid Access to Substituted 5‐Membered‐Dihydrobenzofurans and Indolines.
- Author
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Ding, Mingruo, Ou, Pengcheng, Li, Xuening, Yu, Yinghua, Niu, Mengmeng, Yang, Yongjian, Huang, Yewei, Wang, Zhi‐Xiang, and Huang, Xueliang
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ACYL group , *VINYL polymers , *VINYLATION , *PALLADIUM , *INDOLINE , *ALLYLIC amination - Abstract
"Through space" palladium/hydrogen shift is an efficient strategy to achieve selective functionalization of a specific remote C−H bond. Compared with relatively extensive exploited 1,4‐palladium migration process, the relevant 1,5‐Pd/H shift was far less investigated. We herein report a novel 1,5‐Pd/H shift pattern between a vinyl and an acyl group. Through the pattern, rapid access to 5‐membered‐dihydrobenzofuran and indoline derivatives has been achieved. Further studies have unveiled an unprecedented trifunctionalization (vinylation, alkynylation and amination) of a phenyl ring through 1,5‐palladium migration relayed decarbonylative Catellani type reaction. A series of mechanistic investigations and DFT calculations have provided insights into the reaction pathway. Notably, it was unveiled that the 1,5‐palladium migration in our case prefers a stepwise mechanism involving a PdIV intermediate. [ABSTRACT FROM AUTHOR]
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- 2023
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3. Easy Access to Diverse Multiblock Copolymers with On‐Demand Blocks via Thioester‐Relayed In‐Chain Cascade Copolymerization.
- Author
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Zhang, Ze, Xiong, Yu, Yang, Peng, Li, Yang, Tang, Rui, Nie, Xuan, Chen, Guang, Wang, Long‐Hai, Hong, Chun‐Yan, and You, Ye‐Zi
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COPOLYMERIZATION , *DEGREE of polymerization , *LIVING polymerization , *RING-opening polymerization , *ACYL group , *BLOCK copolymers - Abstract
Multiblock copolymers are envisioned as promising materials with enhanced properties and functionality compared with their diblock/triblock counterparts. However, the current approaches can construct multiblock copolymers with a limited number of blocks but tedious procedures. Here, we report a thioester‐relayed in‐chain cascade copolymerization strategy for the easy preparation of multiblock copolymers with on‐demand blocks, in which thioester groups with on‐demand numbers are built in the polymer backbone by controlled/living polymerizations. These thioester groups further serve as the in‐chain initiating centers to trigger the acyl group transfer ring‐opening polymerization of episulfides independently and concurrently to extend the polymer backbone into multiblock structures. The compositions, number of blocks, and block degree of polymerization can be easily regulated. This strategy can offer easy access to a library of multiblock copolymers with ≈100 blocks in only 2 to 4 steps. [ABSTRACT FROM AUTHOR]
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- 2023
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4. Total Synthesis of Taxol Enabled by Inter‐ and Intramolecular Radical Coupling Reactions.
- Author
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Imamura, Yusuke, Takaoka, Kyohei, Komori, Yuma, Nagatomo, Masanori, and Inoue, Masayuki
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PACLITAXEL , *ACYL group , *STEREOSELECTIVE reactions , *FUNCTIONAL groups , *NATURAL products , *CHEMOSELECTIVITY - Abstract
Taxol is a clinically used drug for the treatment of various types of cancers. Its 6/8/6/4‐membered ring (ABCD‐ring) system is substituted by eight oxygen functional groups and flanked by four acyl groups, including a β‐amino acid side chain. Here we report a 34‐step total synthesis of this unusually oxygenated and intricately fused structure. Inter‐ and intramolecular radical coupling reactions connected the A‐ and C‐ring fragments and cyclized the B‐ring, respectively. Functional groups of the A‐ and C‐rings were then efficiently decorated by employing newly developed chemo‐, regio‐, and stereoselective reactions. Finally, construction of the D‐ring and conjugation with the β‐amino acid delivered taxol. The powerful coupling reactions and functional group manipulations implemented in the present synthesis provide new valuable information for designing multistep target‐oriented syntheses of diverse bioactive natural products. [ABSTRACT FROM AUTHOR]
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- 2023
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5. Chiral Symmetry Breaking of Monoacylated Anhydroerythritols and meso‐1,2‐Diols through Crystallization‐Induced Deracemization.
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Sanada, Kazutaka, Washio, Aoi, Ishikawa, Hiroki, Yoshida, Yasushi, Mino, Takashi, and Sakamoto, Masami
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DERACEMIZATION , *SYMMETRY breaking , *CHIRALITY of nuclear particles , *ACYL group , *CRYSTAL structure , *RESOLUTION (Chemistry) , *DEMETHYLATION - Abstract
We developed a chiral symmetry breaking method for monoacylated meso diols. The X‐ray crystal structure analysis of monoacylated 1,4‐anhydroerythritols, meso cyclic diols with a cis configuration, revealed that the O‐(p‐anisoyl) derivative crystallized as a racemic conglomerate of the P212121 crystal system. It was confirmed that the substrate racemized by intramolecular transfer of the acyl group in the presence of a catalytic amount of base. Evaporating the solvent gradually from the solution or Viedma ripening to promote crystallization‐induced deracemization efficiently led to enantiomer crystals. These results provide the first successful example of asymmetric expression and amplification by deracemization of sugar derivatives without an external chemical chiral source. Furthermore, we applied this methodology to acyclic meso‐1,2‐diols. Three O‐monoacylated substrates were successfully deracemized to 99 % ee by Viedma ripening. We also developed asymmetric desymmetrization of meso‐1,2‐diols by combining acylation and crystallization‐induced deracemization. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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6. Characterization of Mannosyl Dioxanium Ions in Solution Using Chemical Exchange Saturation Transfer NMR Spectroscopy.
- Author
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de Kleijne, Frank F. J., Elferink, Hidde, Moons, Sam J., White, Paul B., and Boltje, Thomas J.
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MAGNETIZATION transfer , *NUCLEAR magnetic resonance spectroscopy , *IONS , *IONIC structure , *ACYL group - Abstract
The stereoselective introduction of the glycosidic bond remains one of the main challenges in carbohydrate synthesis. Characterizing the reactive intermediates of this reaction is key to develop stereoselective glycosylation reactions. Herein we report the characterization of low‐populated, rapidly equilibrating mannosyl dioxanium ions that arise from participation of a C‐3 acyl group using chemical exchange saturation transfer (CEST) NMR spectroscopy. Dioxanium ion structure and equilibration kinetics were measured under relevant glycosylation conditions and highly α‐selective couplings were observed suggesting glycosylation took place via this elusive intermediate. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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7. 1,3‐Alkyl Transposition in Allylic Alcohols Enabled by Proton‐Coupled Electron Transfer.
- Author
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Zhao, Kuo, Seidler, Gesa, and Knowles, Robert R.
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CHARGE exchange , *ALLYL alcohol , *ACYL group , *ALKYL radicals , *ISOMERIZATION , *KETONES - Abstract
A method is described for the isomerization of acyclic allylic alcohols into β‐functionalized ketones via 1,3‐alkyl transposition. This reaction proceeds via light‐driven proton‐coupled electron transfer (PCET) activation of the O−H bond in the allylic alcohol substrate, followed by C−C β‐scission of the resulting alkoxy radical. The transient alkyl radical and enone acceptor generated in the scission event subsequently recombine via radical conjugate addition to deliver β‐functionalized ketone products. A variety of allylic alcohol substrates bearing alkyl and acyl migratory groups were successfully accommodated. Insights from mechanistic studies led to a modified reaction protocol that improves reaction performance for challenging substrates. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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8. Consecutive O−S/N−S Bond Cleavage in Gold‐Catalyzed Rearrangement Reactions of Alkynyl N‐Sulfinylimines.
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Tashiro, Hiroki, Terada, Masahiro, and Nakamura, Itaru
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REARRANGEMENTS (Chemistry) , *SCISSION (Chemistry) , *ACYL group , *SULFENYL group , *MOIETIES (Chemistry) - Abstract
Gold‐catalyzed reactions of alkynyl N‐sulfinylimines were used to produce the corresponding 2H‐azirines possessing sulfenyl and acyl groups at the 3‐position of the azirine ring in good to excellent yields. These reactions involved internal transfer of the sulfinyl oxygen atom to form a thiooxime intermediate tethered to an α‐oxo gold carbene moiety. Subsequent insertion of the carbene into the N−S bond resulted in ring construction. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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9. 1,2‐Aryl Migration Induced by Amide C−N Bond‐Formation: Reaction of Alkyl Aryl Ketones with Primary Amines Towards α,α‐Diaryl β,γ‐Unsaturated γ‐Lactams.
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Hu, Rong, Tao, Yigao, Zhang, Xiaofeng, and Su, Weiping
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LACTAMS , *KETONES , *ARYL group , *AMINES , *REARRANGEMENTS (Chemistry) , *ACYL group - Abstract
Rearrangement reactions incorporated into cascade reactions play an important role in rapidly increasing molecular complexity from readily available starting materials. Reported here is a Cu‐catalyzed cascade reaction of α‐(hetero)aryl‐substituted alkyl (hetero)aryl ketones with primary amines that incorporates an unusual 1,2‐aryl migration induced by amide C−N bond formation to produce a class of structurally novel α,α‐diaryl β,γ‐unsaturated γ‐lactams in generally good‐to‐excellent yields. This cascade reaction has a broad substrate scope with respect to primary amines, allows a wide spectrum of (hetero)aryl groups to smoothly undergo 1,2‐migration, and tolerates electronically diverse α‐substituents on the (hetero)aryl ring of the ketones. Mechanistically, this 1,2‐aryl migration may stem from the intramolecular amide C−N bond formation which induces nucleophilic migration of the aryl group from the acyl carbon center to the electrophilic carbon center that is conjugated with the resulting iminium moiety. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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10. Solid‐Phase Total Synthesis of Yaku'amide B Enabled by Traceless Staudinger Ligation.
- Author
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Itoh, Hiroaki, Miura, Kensuke, Kamiya, Koichi, Yamashita, Tomoya, and Inoue, Masayuki
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SOLID-phase synthesis , *EXCHANGE reactions , *ACYL group , *N-terminal residues , *NATURAL products - Abstract
We report a solid‐phase strategy for total synthesis of the peptidic natural product yaku'amide B (1), which exhibits antiproliferative activity against various cancer cells. Its linear tridecapeptide sequence bears four β,β‐dialkylated α,β‐dehydroamino acid residues and is capped with an N‐terminal acyl group (NTA) and a C‐terminal amine (CTA). To realize the Fmoc‐based solid‐phase synthesis of this complex structure, we developed new methods for enamide formation, enamide deprotection, and C‐terminal modification. First, traceless Staudinger ligation enabled enamide formation between sterically encumbered alkenyl azides and newly designed phosphinophenol esters. Second, application of Eu(OTf)3 led to chemoselective removal of the enamide Boc groups without detaching the resin linker. Finally, resin‐cleavage and C‐terminus modification were simultaneously achieved with an ester–amide exchange reaction using CTA and AlMe3 to deliver 1 in 9.1 % overall yield (24 steps from the resin). [ABSTRACT FROM AUTHOR]
- Published
- 2020
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11. Acyl‐Directed ortho‐Borylation of Anilines and C7 Borylation of Indoles using just BBr3.
- Author
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Iqbal, Saqib A., Cid, Jessica, Procter, Richard J., Uzelac, Marina, Yuan, Kang, and Ingleson, Michael J.
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BORYLATION , *ANILINE , *INDOLE , *ACYL group , *BORONIC esters , *ELECTROPHILIC substitution reactions , *CARBAZOLE - Abstract
Indoles are privileged heterocycles found in many biologically active pharmaceuticals and natural products. However, the selective functionalization of the benzenoid moiety in indoles in preference to the more reactive pyrrolic unit is a significant challenge. Herein we report that N‐acyl directing groups enable the C7‐selective C−H borylation of indoles using just BBr3. This transformation shows some functional‐group tolerance and notably proceeds with C6 substituted indoles. The directing group can be readily removed in situ and the products isolated as the pinacol boronate esters. Acyl‐directed electrophilic borylation can be extended to carbazoles and anilines with excellent ortho selectivity. 4‐amino‐indoles are amenable to this process, with acyl group installation and directed electrophilic C−H borylation enabling selective formation of C5‐BPin‐indoles. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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12. Acyl‐Directed ortho‐Borylation of Anilines and C7 Borylation of Indoles using just BBr3.
- Author
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Iqbal, Saqib A., Cid, Jessica, Procter, Richard J., Uzelac, Marina, Yuan, Kang, and Ingleson, Michael J.
- Subjects
BORYLATION ,ANILINE ,INDOLE ,ACYL group ,BORONIC esters ,ELECTROPHILIC substitution reactions ,CARBAZOLE - Abstract
Indoles are privileged heterocycles found in many biologically active pharmaceuticals and natural products. However, the selective functionalization of the benzenoid moiety in indoles in preference to the more reactive pyrrolic unit is a significant challenge. Herein we report that N‐acyl directing groups enable the C7‐selective C−H borylation of indoles using just BBr3. This transformation shows some functional‐group tolerance and notably proceeds with C6 substituted indoles. The directing group can be readily removed in situ and the products isolated as the pinacol boronate esters. Acyl‐directed electrophilic borylation can be extended to carbazoles and anilines with excellent ortho selectivity. 4‐amino‐indoles are amenable to this process, with acyl group installation and directed electrophilic C−H borylation enabling selective formation of C5‐BPin‐indoles. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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13. Macrolide Synthesis through Intramolecular Oxidative Cross-Coupling of Alkenes.
- Author
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Jiang, Bing, Zhao, Meng, Li, Shu‐Sen, Xu, Yun‐He, and Loh, Teck‐Peng
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CHEMICAL synthesis , *MACROLIDE antibiotics , *ENANTIOSELECTIVE catalysis , *ALKYNES , *FUNCTIONAL groups , *ACYL group - Abstract
A RhIII-catalyzed intramolecular oxidative cross-coupling between double bonds for the synthesis of macrolides is described. Under the optimized reaction conditions, macrocycles containing a diene moiety can be formed in reasonable yields and with excellent chemo- and stereoselectivity. This method provides an efficient approach to synthesize macrocyclic compounds containing a 1,3-conjugated diene structure. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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14. Graphical Abstract: Angew. Chem. Int. Ed. 26/2017.
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ACYL group , *INTERMEDIATES (Chemistry) , *FERTILIZERS , *HYDROGENATION , *SCISSION (Chemistry) - Published
- 2017
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15. Metabolic Glycoengineering with N-Acyl Side Chain Modified Mannosamines.
- Author
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Wratil, Paul R., Horstkorte, Rüdiger, and Reutter, Werner
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METABOLISM , *ACYL group , *SUBSTITUENTS (Chemistry) , *GLYCOCONJUGATES , *BIOSYNTHESIS , *MANNOSAMINE - Abstract
In metabolic glycoengineering (MGE), cells or animals are treated with unnatural derivatives of monosaccharides. After entering the cytosol, these sugar analogues are metabolized and subsequently expressed on newly synthesized glycoconjugates. The feasibility of MGE was first discovered for sialylated glycans, by using N-acyl-modified mannosamines as precursor molecules for unnatural sialic acids. Prerequisite is the promiscuity of the enzymes of the Roseman-Warren biosynthetic pathway. These enzymes were shown to tolerate specific modifications of the N-acyl side chain of mannosamine analogues, for example, elongation by one or more methylene groups (aliphatic modifications) or by insertion of reactive groups (bioorthogonal modifications). Unnatural sialic acids are incorporated into glycoconjugates of cells and organs. MGE has intriguing biological consequences for treated cells (aliphatic MGE) and offers the opportunity to visualize the topography and dynamics of sialylated glycans in vitro, ex vivo, and in vivo (bioorthogonal MGE). [ABSTRACT FROM AUTHOR]
- Published
- 2016
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16. Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C−N Bond Activation.
- Author
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Hu, Jiefeng, Zhao, Yue, Liu, Jingjing, Zhang, Yemin, and Shi, Zhuangzhi
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NICKEL catalysts , *CARBENE synthesis , *AMIDES , *BORYLATION , *ACYL group - Abstract
A nickel/N-heterocyclic carbene catalytic system has been established for decarbonylative borylation of amides with B2nep2 by C−N bond activation. This transformation shows good functional-group compatibility and can serve as a powerful synthetic tool for late-stage borylation of amide groups in complex compounds. More importantly, as a key intermediate, the structure of an acyl nickel complex was first confirmed by X-ray analysis. Furthermore, the decarbonylative process was also observed. These findings confirm the key mechanistic features of the acyl C−N bond activation process. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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17. Total Synthesis and Biological Evaluation of Siladenoserinol A and its Analogues
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Masahito Yoshida, Takayuki Doi, Koya Saito, Sachiko Tsukamoto, and Hikaru Kato
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010402 general chemistry ,01 natural sciences ,Catalysis ,Propanolamines ,Structure-Activity Relationship ,chemistry.chemical_compound ,Humans ,Moiety ,Hydroalkoxylation ,Dose-Response Relationship, Drug ,Molecular Structure ,010405 organic chemistry ,Regioselectivity ,Total synthesis ,Proto-Oncogene Proteins c-mdm2 ,Biological activity ,General Medicine ,General Chemistry ,Glycerylphosphorylcholine ,Combinatorial chemistry ,Gold Compounds ,0104 chemical sciences ,chemistry ,Propylene Glycols ,Yield (chemistry) ,Tumor Suppressor Protein p53 ,Acyl group ,Derivative (chemistry) - Abstract
The total synthesis of siladenoserinol A, an inhibitor of the p53-Hdm2 interaction, has been achieved. AuCl3 -catalyzed hydroalkoxylation of an alkynoate derivative smoothly and regioselectively proceeded to afford a bicycloketal in excellent yield. A glycerophosphocholine moiety was successfully introduced through the Horner-Wadsworth-Emmons reaction using an originally developed phosphonoacetate derivative. Finally, removal of the acid-labile protecting groups, followed by regioselective sulfamate formation of the serinol moiety afforded the desired siladenoserinol A, and benzoyl and desulfamated analogues were also successfully synthesized. Biological evaluation showed that the sulfamate is essential for biological activity, and modification of the acyl group on the bicycloketal can improve the inhibitory activity against the p53-Hdm2 interaction.
- Published
- 2018
18. A Reaction of Triazoles with Thioesters to Produce β‐Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur–Carbonyl Bond
- Author
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Yuuta Funakoshi, Masahiro Murakami, Yoshikazu Fujimoto, and Tomoya Miura
- Subjects
chemistry.chemical_classification ,Nucleophilic addition ,General Medicine ,General Chemistry ,Thioester ,Medicinal chemistry ,Catalysis ,Enamine ,chemistry.chemical_compound ,chemistry ,Sulfanyl ,Organic chemistry ,Moiety ,Carbene ,Carbenoid ,Acyl group - Abstract
N-Sulfonyl-1,2,3-triazoles react with thioesters in the presence of a rhodium(II) catalyst to produce β-sulfanyl enamides in a stereoselective manner. The reaction proceeds through generation of an α-imino rhodium carbene complex, nucleophilic addition of the sulfur atom of a thioester onto the carbenoid carbon atom, and subsequent intramolecular migration of the acyl group from the sulfur atom to the imino nitrogen atom. The method is successfully applied to a ring-expansion reaction of thiolactones, thus leading to the formation of sulfur-containing lactams.
- Published
- 2015
19. Anti-MRSA Agent Discovery Using Diversity-Oriented Synthesis
- Author
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Freija G. Glansdorp, Derek F. J. Brown, Mark Ladlow, Gemma L. Thomas, Joshua D. Cockfield, Jodi A. Lindsay, Helene Rudyk, Martin Welch, David R. Spring, Olivier Loiseleur, Andreas Bender, Richard J. Spandl, and Clare E. Bryant
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chemistry.chemical_classification ,Staphylococcus aureus ,Molecular Structure ,Imidazolidinone ,Stereochemistry ,Drug Evaluation, Preclinical ,Enantioselective synthesis ,General Chemistry ,Aldehyde ,Combinatorial chemistry ,Phosphonate ,Catalysis ,Cycloaddition ,Anti-Bacterial Agents ,chemistry.chemical_compound ,chemistry ,Dihydroxylation ,Methicillin Resistance ,Linker ,Acyl group - Abstract
Antibacterial drugs have played an essential role in the global increase in quality of life and life expectancy. However, these gains are at serious risk owing to bacterial drug resistance by so-called “superbugs”, such as methicillin-resistant Staphylococcus aureus (MRSA). The discovery of new antibiotics with novel modes of action is vital to tackle the threat of multidrug-resistant bacteria. Traditionally, antibiotics have been discovered from natural sources; however, there are many disadvantages to using extracts (e.g. limited availability, bioactive constituent identification, and complex analogue synthesis). These problems have led to a complementary approach of synthesizing structurally diverse, natural-product-like small molecules directly and efficiently, an approach known as diversity-oriented synthesis (DOS). Whereas compound collections of a common scaffold decorated with diverse building blocks have been synthesized efficiently, there are limited examples of the synthesis of small molecules with a high degree of skeletal diversity (usually by a build–couple–pair strategy). Previously, we have used a diazoacetate starting unit to mimic nature8s divergent synthetic strategy with acetyl CoA (by a pluripotent functional-group strategy) to synthesize compounds with natural-product scaffolds (e.g. cocaine and warfarin). Herein, we report the use of a solid-supported phosphonate unit to synthesize 242 drug-like compounds based on 18 natural-product-like scaffolds in two to five steps and their use in discovering a new structural class of antibiotic with anti-MRSA activity. The solid-supported phosphonate 1 (Scheme 1) was identified as an attractive DOS starting unit for three key reasons. First, the reactive phosphonate functionality permits the stereoselective formation of a,b-unsaturated acyl imidazolidinones (2) that could be used to generate enantioselectively a wide range of scaffolds that can be diversified further. Second, the imidazolidinone linker not only enables twopoint binding of chiral catalysts but also permits divergent cleavage of the exocyclic acyl group (hydrolysis, reduction, esterification, and amide formation). Thirdly, immobilization of 1 on a silyl polystyrene support simplified reaction optimization and work-up procedures in the multistep parallel synthesis (total of over 1000 individual steps), thereby allowing the efficient production of milligram quantities of 242 compounds without the requirement for automation equipment. In the first step of the diversity-oriented synthesis, 1 was treated with aldehyde building blocks (aryl, heteroaryl, and alkyl; see the Supporting Information) to deliver twelve a,bunsaturated acyl imidazolidinones (2). The second steps of the solid-supported synthesis exploited three catalytic, enantioselective, divergent reaction pathways (Scheme 1): 1) [2+3] cycloaddition (reaction b, ee 60–65%, de 7899%), 2) dihydroxylation (reaction c, ee 88–91%), and 3) [4+2] cycloaddition (reaction d, ee 89–98%, de 74– 74%). Similar selectivities were observed when repeating the reactions in solution with a triisopropylsilyl-protected linker (as opposed to the diisopropylpolystyrene group; see the Supporting Information). The reactions were also conducted with achiral catalysts to give racemic products, which were used for the later steps of the synthesis. This procedure enabled the diversity-oriented synthesis to be streamlined to half the size, yet permitted the enantioselective synthesis of hits during the structure–activity relationship stages of this [*] Dr. G. L. Thomas, R. J. Spandl, F. G. Glansdorp, Dr. M. Ladlow, Dr. D. R. Spring Department of Chemistry, University of Cambridge Lensfield Road, Cambridge, CB2 1EW (UK) Fax: (+44) 1223-336362 E-mail: drspring@ch.cam.ac.uk Homepage: http://www-spring.ch.cam.ac.uk/
- Published
- 2008
20. Protecting Groups: Strategies and Applications in Carbohydrate Chemistry. Edited by Sébastien Vidal.
- Author
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Bertozzi, Carolyn R.
- Subjects
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CARBOHYDRATES , *CHEMISTRY , *ACYL group , *OLIGOSACCHARIDE synthesis , *SPATIAL arrangement , *MONOSACCHARIDES - Published
- 2019
- Full Text
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21. Corrigendum: Visible-Light-Mediated 1,2-Acyl Migration: The Reaction of Secondary Enamino Ketones with Singlet Oxygen.
- Author
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Fan, Weigang and Li, Pixu
- Subjects
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MIGRATION reactions (Chemistry) , *ACYL group , *ENAMINES - Abstract
A correction to the article "Visible-Light-Mediated 1,2-Acyl Migration: The Reaction of Secondary Enamino Ketones with Singlet Oxygen" that was published in the 2014 issue is presented.
- Published
- 2015
- Full Text
- View/download PDF
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