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1. High-Pressure Synthesis of Crystalline Carbon Nitride Imide, C2N2(NH)

2. Spinel Sialons We gratefully acknowledge the synthesis of β-sialon starting material by M. Zenotchkine and the fruitful conversation with James W. McCauley concerning the existence of γ-Al3O3N. The department of high-pressure/mineral physics, Max-Planck-Institut für Chemie, Mainz, is acknowledged for providing technical support. We are further grateful for the financial support of this work provided by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. E.K. thanks the Alexander von Humboldt Foundation for granting a Lynen fellowship

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