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Start Over Author "Jacques Pécaut" Journal angewandte chemie international edition
8 results on '"Jacques Pécaut"'

2. A Fully Delocalized Mixed-Valence Bis-μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center

Author

Carole Duboc, Serena DeBeer, Frank Neese, Marie-Noëlle Collomb, Marcello Gennari, Jacques Pécaut, Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (DCM - CIRE), Département de Chimie Moléculaire (DCM), Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Reconnaissance Ionique et Chimie de Coordination (RICC), SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé (SYMMES), Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Cornell University [New York], Max-Planck-Institut für Chemische Energiekonversion (MPI-CEC), Max-Planck-Gesellschaft, Département de Chimie Moléculaire - Chimie Inorganique Redox (DCM - CIRE), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)

Subjects
Models, Molecular, Valence (chemistry), 010405 organic chemistry, Chemistry, Stereochemistry, Molecular Conformation, Electrochemical Techniques, General Medicine, General Chemistry, Crystallography, X-Ray, 010402 general chemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, Electron Transport Complex IV, Crystallography, Delocalized electron, Coordination Complexes, [CHIM]Chemical Sciences, Copper, ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2011
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3. H2O2-Dependent Fe-Catalyzed Oxidations: Control of the Active Species

Author

Colette Lebrun, Stéphane Ménage, Jacques Pécaut, Marc Fontecave, Yasmina Mekmouche, Carole Toia-Duboc, and Jean-Baptiste Galey

Subjects
Reaction mechanism, Coordination sphere, Homogeneous catalysis, General Medicine, General Chemistry, Photochemistry, Catalysis, Ion, Hydroxylation, chemistry.chemical_compound, chemistry, Fenton chemistry, Hydrogen peroxide
Abstract

Manipulation of the coordination sphere of an FeII ion can be used to tune the balance between different catalytic pathways for oxidation (OH. versus iron-based oxidant; see scheme). This reinvestigation of Fenton chemistry uses the iron complex shown as a mechanistic probe.

Published
2001
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4. Inside Back Cover: Self-Assembly of a 3d-5f Trinuclear Single-Molecule Magnet from a Pentavalent Uranyl Complex (Angew. Chem. Int. Ed. 49/2014)

Author

James P. S. Walsh, Floriana Tuna, Marinella Mazzanti, Jacques Pécaut, and Lucile Chatelain

Subjects
chemistry.chemical_compound, Crystallography, chemistry, Magnetism, Inorganic chemistry, chemistry.chemical_element, Cover (algebra), Single-molecule magnet, General Chemistry, Self-assembly, Uranium, Uranyl, Catalysis
Published
2014
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6. Inside Cover: Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation-Cation Interactions (Angew. Chem. Int. Ed. 45/2009)

Author

Paweł Horeglad, Jacques Pécaut, Grégory Nocton, Marinella Mazzanti, and Victor Mougel

Subjects
chemistry.chemical_compound, Mixed valent, chemistry, INT, Inorganic chemistry, chemistry.chemical_element, Cover (algebra), General Chemistry, Self-assembly, Actinide, Uranium, Uranyl, Catalysis
Published
2009
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8. An Efficient Design for the Rigid Assembly of Four Bidentate Chromophores in Water-Stable Highly Luminescent Lanthanide ComplexesWe thank Pierre Alain Bayle for help with NMR spectroscopic measurements and Emilie Robert for her contribution to the ligand synthesis. We are grateful to Daniel Imbert and Jean-Claude Bünzli for their suggestions and help with the photophysical measurements.

Author

Nicholas Chatterton, Yann Bretonnière, Jacques Pécaut, and Marinella Mazzanti

Published
2005
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