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Start Over Author "Mo, Xueling" Journal angewandte chemie international edition
3 results on '"Mo, Xueling"'

3. Light‐Promoted Copper‐Catalyzed Enantioselective Alkylation of Azoles.

Author

Li, Chen, Chen, Bin, Ma, Xiaodong, Mo, Xueling, and Zhang, Guozhu

Subjects
CARBAZOLE, ALKYLATION, AZOLES, LOW temperatures, ALKYL bromides, PHOTOEXCITATION, STEREOSELECTIVE reactions
Abstract

A catalytic asymmetric alkylation of azoles with secondary 1‐arylalkyl bromides through direct C−H functionalization is reported. Under blue‐light photoexcitation, a copper(I)/carbazole‐based bisoxazoline (CbzBox) catalytic system exhibits good reactivity and high stereoselectivity, thus offering an efficient strategy for the construction of chiral alkyl azoles. These reactions proceed at low temperature and are compatible with a wide range of azoles. [ABSTRACT FROM AUTHOR]

Published
2021
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