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Start Over Author "Robinson, Gregory" Journal angewandte chemie international edition
7 results on '"Robinson, Gregory"'

3. Carbene‐Stabilized Dithiolene (L0) Zwitterions.

Author

Wang, Yuzhong, Tran, Phuong M., Xie, Yaoming, Wei, Pingrong, Glushka, John N., Schaefer, Henry F., and Robinson, Gregory H.

Subjects
LEWIS bases, ZWITTERIONS, SPIRO compounds, DITHIOLENES, SILYLENES
Abstract

A series of reactions between Lewis bases and an imidazole‐based dithione dimer (1) has been investigated. Both cyclic(alkyl)(amino)carbene (CAAC) (2) and N‐heterocyclic carbene (NHC) (4), in addition to N‐heterocyclic silylene (NHSi) (6), demonstrate the capability to cleave the sulphur–sulphur bonds in 1, giving carbene‐stabilized dithiolene (L0) zwitterions (3 and 5) and a spirocyclic silicon–dithiolene compound (7), respectively. The bonding nature of 3, 5, and 7 are probed by both experimental and theoretical methods. [ABSTRACT FROM AUTHOR]

Published
2021
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4. Stable Boron Dithiolene Radicals

Author

Wang, Yuzhong, primary, Xie, Yaoming, additional, Wei, Pingrong, additional, Blair, Soshawn A., additional, Cui, Dongtao, additional, Johnson, Michael K., additional, Schaefer, Henry F., additional, and Robinson, Gregory H., additional

Published
2018
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